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11.
鲁北新生代隐伏火山岩及其石油地质意义 总被引:1,自引:0,他引:1
鲁北新生代隐伏火山岩可划分为3个喷发期6个亚期,9种火山岩岩石类型和同期侵入的辉绿岩。它们形成在近大陆边缘的板内裂谷型盆地,对于富有机质生油岩的沉积、各种储集体的形成、多种含油圈闭类型的形成以及有机质成熟向烃类转化都是非常有利的。作为储集岩主要有玄武安山岩、辉绿岩和湖底玄武质凝灰岩。储油空间主要为次生孔隙和裂缝。火山岩及其有关岩石在本区不仅形成了特殊的油气藏,而且还可作为盖层、封堵层、披复构造的基岩,因此对石油地质勘探有重要意义。 相似文献
12.
13.
Aggregates composed of olivine and magnesiowüstite have been deformed to large strains at high pressure and temperature to investigate stress and strain partitioning, phase segregation and possible localization of deformation in a polyphase material. Samples with 20 vol.% of natural olivine and 80 vol.% of (Mg0.7Fe0.3)O were synthesized and deformed in a gas-medium torsion apparatus at temperatures of 1127 °C and 1250 °C, a confining pressure of 300 MPa and constant angular displacement rates equivalent to constant shear strain rates of 1–3.3 × 10− 4 s− 1. The samples deformed homogeneously to total shear strains of up to γ 15. During constant strain rate measurements the flow stress remained approximately stable at 1250 °C while it progressively decreased after the initial yield stress at the lower temperature. Mechanical data, microstructures and textures indicate that both phases were deforming in the dislocation creep regime. The weaker component, magnesiowüstite, controlled the rheological behavior of the bulk material and accommodated most of the strain. Deformation and dynamic recrystallization lead to grain refinement and to textures that were not previously observed in pure magnesiowüstite and may have developed due to the presence of the second phase. At 1127 °C, olivine grains behaved as semi-rigid inclusions rotating in a viscous matrix. At 1250 °C, some olivine grains remained largely undeformed while deformation and recrystallization of other grains oriented for a-slip on (010) resulted in a weak foliation and a texture typical for pure dry olivine aggregates. Both a-slip and c-slip on (010) were activated in olivine even though the nominal stresses were up to 2 orders of magnitude lower than those needed to activate these slip systems in pure olivine at the same conditions. 相似文献
14.
《Chemie der Erde / Geochemistry》2019,79(4):125524
Due to their common occurrence in various types of chondrites, igneous rims formed on pre-existing chondrules throughout chondrule-forming regions of the solar nebula. Although the peak temperatures are thought to reach similar values to those achieved during chondrule formation events, the heating duration in chondrule rim formation has not been well defined. We determined the two-dimensional chemical and oxygen isotopic distributions in an igneous rim of a chondrule within the Northwest Africa 3118 CV3oxA chondrite with sub-micrometer resolution using secondary ion mass spectrometry and scanning electron microscopy. The igneous rim experienced aqueous alteration on the CV parent body. The aqueous alteration resulted in precipitation of the secondary FeO-rich olivine (Fa40–49) and slightly disturbed the Fe-Mg distribution in the MgO-rich olivine phenocrysts (Fa11–22) at about a 1 μm scale. However, no oxygen isotopic disturbances were observed at a scale greater than 100 nm. The MgO-rich olivine, a primary phase of igneous rim formation, has δ17O = −6 ± 3‰ and δ18O = −1 ± 4‰, and some grains contain extreme 16O-rich areas (δ17O, δ18O = ∼−30‰) nearly 10 μm across. We detected oxygen isotopic migration of approximately 1 μm at the boundaries of the extreme 16O-rich areas. Using oxygen self-diffusivity in olivine, the heating time of the igneous rim formation could have continued from several hours to several days at near liquidus temperatures (∼2000 K) in the solar nebula suggesting that the rim formed by a similar flash heating event that formed the chondrules. 相似文献
15.
Structural parameters and cation ordering are determined for four compositions in the synthetic MgGa2O4-Mg2GeO4 spinel solid solution (0, 8, 15 and 23 mol% Mg2GeO4; 1400 °C, 1 bar) and for spinelloid β-Mg3Ga2GeO8 (1350 °C, 1 bar), by Rietveld refinement of room-temperature neutron diffraction data. Sample chemistry is determined by
XRF and EPMA. Addition of Mg2GeO4 causes the cation distribution of the MgGa2O4 component to change from a disordered inverse distribution in end member MgGa2O4, [4]Ga = x = 0.88(3), through the random distribution, toward a normal cation distribution, x = 0.37(3), at 23 mol% Mg2GeO4. An increase in ao with increasing Mg2GeO4 component is correlated with an increase in the amount of Mg on the tetrahedral site, through substitution of 2 Ga3+⇄ Mg2++Ge4+. The spinel exhibits high configurational entropy, reaching 20.2 J mol−1 (four oxygen basis) near the compositional upper limit of the solid solution. This stabilizes the spinel in spite of positive
enthalpy of disordering over the solid solution, where ΔH
D
= αx + βx
2, α = 22(3), β = −21(3) kJ mol−1. This model for the cation distribution across the join suggests that the empirically determined limit of the spinel solid
solution is correlated with the limit of tetrahedral ordering of Mg, after which local charge-balanced substitution is no
longer maintained.
Spinelloid β-Mg3Ga2GeO8 has cation distribution M1[Mg0.50(2)Ga0.50(2)] M2[Mg0.96(2)Ga0.04(2)] M3[Mg0.77(2) Ga0.23(2)]2 (Ge0.5Ga0.5)2O8 (tetrahedral site occupancies are assumed). Octahedral site size is correlated to Mg distribution, where site volume, site
distortion, and Mg content follow the relation M1<M3<M2. The disordered cation distribution provides local electrical neutrality
in the structure, and stabilization through increased configurational entropy (27.6 J mol−1; eight oxygen basis). Comparison of the crystal structures of Mg1+
N
Ga2−2
N
Ge
N
O4 spinel, β-Mg3Ga2GeO8, and Mg2GeO4 olivine reveals β-Mg3Ga2GeO8 to be a true structural intermediate. Phase transitions across the pseudobinary are necessary to accommodate an increasing
divergence of cation size and valence, with addition of Mg2GeO4 component. Octahedral volume increases while tetrahedral volume decreases from spinel to β-Mg3Ga2GeO8 to olivine, with addition of Mg and Ge, respectively. Furthermore, M-M distances increase regularly across the join, suggesting
that changes in topology reduce cation-cation repulsion.
Received: 9 November 1998 / Revised, accepted: 3 August 1999 相似文献
16.
R. Rinaldi G. Artioli C. C. Wilson G. McIntyre 《Physics and Chemistry of Minerals》2000,27(9):623-629
Crystallographic determinations on natural olivine single crystals of mantle composition and origin, carried out by in situ neutron diffraction at high temperature, show that the octahedrally co-ordinated Fe2+ and Mg cations undergo two successive trends of cation ordering with increasing temperature. An initial slight preference of Fe2+ for site M1, up to a temperature of about 850?°C, is followed by a reverse-ordering reaction with a site preference exchange between the two cations. The cross-over between the two regimes of ordering, corresponding to a situation of complete disorder, occurs at about 900?°C. Above this temperature Fe2+ progressively and strongly segregates into site M2 up to 1300?°C, the practical limit of the experimental setup utilized in the experiments. Care was taken to ensure that no chemical changes occurred in the crystals (i.e. oxidation), as testified by Mössbauer spectroscopy determinations carried out before and after the heat treatment. The cation-ordering behaviour is reflected in temperature-dependent changes of geometrical and atomic displacement parameters occurring in the octahedral sites M1 and M2. A thermodynamical explanation of this behaviour is proposed in terms of a prevailing vibrational contribution to entropy. 相似文献
17.
岩石圈流变实验研究的进展 总被引:2,自引:2,他引:0
岩石高温高压变形实验是了解地球内部物质流动特性的最直接的手段 .本文概述了近年来岩石流变实验研究的一些成果 ,重点总结了水和部分熔融对上地幔顶部橄榄石流变行为的影响 ,以及地壳多相岩石流变实验研究的一些成果 . 相似文献
18.
19.
Shear deformation of hot pressed plagioclase–olivine aggregates was studied in the presence and absence of mineral reaction. Experiments were performed at 900 °C, 1500 MPa, and a constant shear strain rate of 5×10−5 s−1 in a solid medium apparatus. Whether the mineral reaction between plagioclase and olivine takes place or not is controlled by choosing the appropriate plagioclase composition; labradorite (An60) does not react, anorthite (An92) does. Labradorite–olivine aggregates deformed without reaction are very strong and show strain hardening throughout the experiment. Syndeformational reaction between olivine and anorthite causes a pronounced strain weakening. The reaction produces fine-grained opx–cpx–spinel aggregates, which accommodate a large fraction of the finite strain. Deformation and reaction are localised within a 0.5-mm-wide sample. Three representative samples were analysed for their fabric anisotropy R* and shape-preferred orientation α* (fabric angle with the shear plane) using the autocorrelation function (ACF). Fabric anisotropy can be calibrated to quantify strain variations across the sheared samples. In the deformed and reacted anorthite–olivine aggregate, there is a strong correlation between reaction progress and strain; regions of large shear strain correspond to regions of maximum reaction progress. Within the sample, the derived strain rate variations range up to almost one order of magnitude. 相似文献
20.
Effects of dynamic recrystallization on lattice preferred orientation (LPO) in olivine were investigated through the combination of two SEM-based techniques, electron backscattered diffraction (EBSD) technique for crystallographic orientation measurement and backscattered electron imaging (BEI) for dislocation observation. Samples are experimentally deformed olivine aggregates in simple shear geometry. In the sample deformed at T=1473 K and high stresses (480 MPa), only incipient dynamic recrystallization is observed along grain-boundaries. Orientations of these small recrystallized grains are more random than that of relict grains, suggesting an important role of grain-boundary sliding at this stage of recrystallization. In the sample deformed at T=1573 K and low stress (160 MPa), dynamic recrystallization is nearly complete and the LPO is characterized by two [100] peaks. One peak is located at the orientation subparallel to the shear direction and is dominated by grains with high Schmid factor. The other occurs at high angles to the shear direction and is due to the contribution from grains with low Schmid factor. Grains with high Schmid factor tend to have higher dislocation densities than those with low Schmid factor. Based on these observations, we identify two mechanisms by which dynamic recrystallization affects LPO: (1) enhancement of grain-boundary sliding due to grain-size reduction, leading to the modification of LPO caused by the relaxation of constraint for deformation; (2) grain-boundary migration by which grains with lower dislocation densities grow at the expense of grains with higher dislocation densities. Based on the deformation mechanism maps and stress versus recrystallized grain-size relation, we suggest that the first mechanism always plays an important role whereas the second mechanism has an important effect only under limited conditions. 相似文献