Geochemistry, Geochronology and Isotopic Evolution of the Chewore-Rufunsa Terrane, Southern Irumide Belt: a Mesoproterozoic Continental Margin Arc

The southern Irumide Belt (SIB) is an ENE–WSW-trending,late Mesoproterozoic orogenic belt located between the Congo–Tanzania–Bangweulu(CTB) and Kalahari cratons in central southern Africa. It isseparated from the late Mesoproterozoic Irumide Belt (IB) tothe north by Permo-Triassic graben, raising the possibilitythat the younger rifts reactivated a suture between the twobelts that has been rendered cryptic as a result of youngerKaroo cover. Both belts are dominated by calc-alkaline gneisses,but in addition the SIB contains abundant metavolcanic and metasedimentaryrocks. In this study we present detailed geochemical, isotopicand geochronological data for volcanic and plutonic lithologiesfrom the southernmost part of the SIB, the Chewore–RufunsaTerrane. This terrane comprises a wide variety of supracrustalto mid-crustal rocks that have major- and trace-element compositionssimilar to magmas formed in present-day subduction zones. Chondrite-normalizedrare earth element (REE) profiles and whole-rock Sm–Ndisotope compositions indicate that the parental supra-subductionmelts interacted with, and were contaminated by sialic continentalcrust, implying a continental-margin-arc setting. Secondaryionization mass spectrometry dating of magmatic zircon has yieldedcrystallization ages between c. 1095 and 1040 Ma, similar toelsewhere in the SIB. U–Pb dating and in situ Lu–Hfisotopic analyses of abundant xenocrystic zircon extracted fromthe late Mesoproterozoic granitoids indicate that the contaminantcontinental basement was principally Palaeoproterozoic in ageand had a juvenile isotopic signature at the time of its formation.These data are in contrast to those for the IB, which is characterizedby younger, c. 1020 Ma, calc-alkaline gneisses that formed bythe direct recycling of Archaean crust without significant additionof any juvenile material. We suggest that the SIB developedby the subduction of oceanic crust under the margin of an unnamedcontinental mass until ocean closure at c. 1040 Ma. Subsequentcollision between the SIB and the CTB margin led to the cessationof magmatism in the SIB and the initiation of compression andcrustal melting in the IB. KEY WORDS: geochemistry; Mesoproterozoic; SHRIMP zircon U–Pb dating; Sm–Nd isotopes; Southern Irumide Belt     

Archaean high-K granitoids produced by remelting of earlier Tonalite–Trondhjemite–Granodiorite (TTG) in the Sangmelima region of the Ntem complex of the Congo craton,southern Cameroon

We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.     

Triassic alkaline intrusives in the Yanliao-Yinshan area: their chronology, Sr, Nd and Pb isotopic characteristics and their implication

Dated isotopic ages for 15 alkaline intrusives in the Yanliao-Yinshan area, ranging from 268 to 190 Ma, ten of which are from 250 to 208 Ma, indicate that most of them were formed in the Triassic Epoch. All the E_Nd(t) ratios from - 17.19 to -3.21 averaging -7.09, the E_Sr(t) ratios fmm 11.7 to71.5 averaging 36.63, and the I_sr(t) ratios from 0.705 0 to 0.709 3 averaging 0.706 8, show their characteristics of enrichment. On the E_Nd (t) virus E_Sr(t) correlation diagram, the samples from these intmsives were plotted within the enriched mantle trend lines and just outside, demonstrating their close connection to materials from the enriched mantle reservoir, taking into account the same Pb isotopic composition as that of the mantle.     

延边地区中生代火山岩的岩浆源区:来自Sr-Nd同位素和深源捕虏体(晶)的证据

延边地区中侏罗世和早白垩世火山岩中包含有较多的辉石岩捕虏体和角闪石捕虏晶,前者为普通辉石变种,其化学成分类似于中国东部新生代玄武岩中单斜辉石巨晶的成分,具有岩浆堆积成因特征;后者为韭闪石和镁质绿钠闪石变种,其成分类似于中生代晚期玄武岩中角闪二辉石岩包体里的角闪石和新生代玄武岩中的角闪石巨晶.矿物温压计算结果显示,它们形成深度介于25～37km.延边地区中生代火山岩的(87Sr/86Sr)i值介于0.704 3～0.705 0,εNd(t)值介于2.33～4.71,表明岩浆源区应是一套具有亏损性质的新增生的地幔物质.综合上述结果,可以判定延边地区中生代火山岩的原始岩浆应来源于新增生的壳幔过渡带物质的部分熔融,地壳增生事件的时间为新元古代.     

北山南部二叠纪海相玄武岩地球化学特征及其构造意义

基于北山南部晚古生代构造演化争议较大,本文对该区4条下—中二叠统代表剖面中的玄武岩进行了岩相学、元素地球化学、及全岩Sr- Nd同位素等研究;并对地层中的中酸性火山岩进行了锆石U- Pb定年。获得英安岩与安山岩的锆石U- Pb年龄分别为289. 5±2. 3Ma和267. 8±3. 1Ma,结合已发表年龄数据及古生物资料,明确了火山岩的喷发时代介于早二叠世亚丁斯克期—中二叠世沃德期。该套玄武岩产于海相地层中,主体为拉斑玄武岩系列;氧化物含量变化较大,TiO 2 含量中等(0. 9%~2. 53%);轻重稀土分馏不明显［(La/Yb) N=1. 6~6. 2］,且无显著Eu异常( δ Eu为0. 79~1. 19);不同程度亏损Nb、Ta、Ti、P等元素,富集La、Ce、Nd、Zr等元素;ε Nd ( t ) 值介于1. 4~10. 9,( 87 Sr/ 86 Sr) i 值为0. 703365~0. 707285。玄武岩源区为受俯冲物质改造的软流圈地幔,经不同程度熔融所形成;既与岛弧或陆缘弧所产生的火山岩有所差别,又不同于地幔柱或热点所产生的玄武岩,在各判别图解中,大多投入板内玄武岩(WPB)或洋脊玄武岩(MORB)。结合该区域其他地质资料,推测该套玄武岩的产生与北山南部加厚岩石圈的拆沉作用有关。     

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.     

Petrogenesis of the Xihuashan Granite in Southern Jiangxi Province,South China: Constraints from Zircon U-Pb Geochronology,Geochemistry and Nd Isotopes

Mesozoic granitic intrusions are widely distributed in the Nanling region,South China.Yanshanian granites are closely connected with the formation of tungsten deposits.The Xihuashan granite is a typica...     

Petrology, geochemistry and isotopic ages of eclogites from the Dulan UHPM Terrane, the North Qaidam, NW China

The Dulan eclogite–gneiss region is located in the eastern part of the North Qaidam eclogite belt, NW China. Widespread evidence demonstrates that this region is a typical ultrahigh-pressure (UHP) metamorphic terrane. Eclogites occur as lenses or layers in both granitic and pelitic gneisses. Two distinguished sub-belts can be recognized and differ in mineralogy, petrology and geochemistry. The North Dulan Belt (NDB) has tholeiitic protoliths with high TiO₂ and lower Al₂O₃ and MgO contents. REE patterns and trace element contents resemble those of N-type and E-type MORB. In contrast, eclogites in the South Dulan Belt (SDB) are of island arc protoliths with low TiO₂, high Al₂O₃ and show LREE-enriched and HFSE-depleted patterns. Sm–Nd isotope analyses give isochron ages of 458–497 Ma for eclogite-facies metamorphism for the two sub-belts. The ages are similar to those of Yuka and Altun eclogites in the western extension of the North Qaidam-Altun eclogite belt. The Dulan UHP metamorphic terrane, together with several other recently recognized eclogite-bearing terrenes within the North Qaidam-Altun HP-UHP belt, constitute the key to the understanding of the tectonic evolution of the northern Tibetan Plateau. The entire UHP belt extends for more than 1000 km from the Dulan UHP terrane in the southeast to the Altun eclogite–gneiss terrane in the west. This super-belt marks an early Paleozoic continental collision zone between the Qaidam Massif and the Qilian Massif.     

内蒙古白银都西群变质火山岩的钕、锶同位素研究

白银都西群主要由斜长角闪岩、变粒岩、长英片岩和条带状混合岩组成,是白银都西-白乃庙地体的重要组成部分,主要分布在内蒙古白乃庙铜(金)矿床东北白银都西一带。长期以来,由于缺乏可信的同位素年龄数据,该套岩层的归属,构造性质和形成机理尚不清楚。笔者首次对白银都西群斜长角闪岩的Nd和Sr同位素组成进行了测定,所获Sm-Nd同位素等时年龄为1394±46Ma(23),Nd初始比值为0.511 243±8(23)和εNd(T)=+7.9±2.1(23)。~(87)Sr/~(86)Sr和~(87)Rb/~(86)Sr比值分别为0.705 79—0.709 12和0.17—0.34,两者之间不存在任何相关关系。结合野外地质证据和岩相学特征,我们认为:白银都西群基性火山活动发生在中元古代,成岩物质来自亏损地幔源,成岩以后构造变动和变质热液活动致使Rb-Sr同位素体系受到严重干扰破坏。     

河北平山小觉地区阜平岩群浅粒岩深熔作用的地球化学研究

新太古代阜平岩群浅粒岩遭受深熔作用改造形成一些不同规模和形状的浅色体。与溶融母岩相比，其稀土元素和高场强元素含量相对较低，但大多数情况下具有相似的元素分布模式。然而，深熔作用刚开始时形成的浅色体，其元素含量、分布模式与熔融母岩完全不同，Nd同位素组成存在较大差别。随着深熔作用的进行，两者Nd同位素组成的差异越来越小，最后几乎完全消失。残余相副矿物，特别是锆石和磷灰石，对深熔浅色体的元素、Nd同位素组成的变化起了重要的作用。