不同方案求解非线性化学动力学方程组的比较

在一个简化的气相化学模式的基础上，比较了Ｈｙｂｒｉｄ、ＱＳＳＡ、Ｓｋｌａｒｅｗ三种计算方案求解非线性化学动力学方程组的差异，并引入误差分配和线性组合两种质量守恒技术，分析它们对模拟结果的影响．研究结果表明：不同方案对有机烃类浓度的计算几乎没有影响，但对其它气态物浓度有一定的影响．用ＱＳＳＡ和Ｓｌａｒｅｗ方案预测的结果更为相近，而采用Ｈｙｂｒｉｄ方案得到的气态物浓度的平衡时间略为提前．从计算效率来看，ＱＳＳＡ方案优于其它两种方案，两种质量守恒技术均能改善模拟结果．     

Differential diatom dissolution in Late Quaternary sediments from Lake Manyara,Tanzania: an experimental approach

Diatom dissolution in saline lakes represents an important obstacle to the quantitative reconstruction of water chemistry and climate from lake sediment archives. This problem is here approached experimentally by artificially dissolving diatom-bearing core sediment from Lake Manyara, Tanzania. Manyara holds one of the longest continuous palaeolimnological records from tropical Africa although its interpretation is based on a fragmentary diatom record due to frustule dissolution. These experiments have revealed clear changes in assemblage composition as dissolution operated differentially with respect to diatom taxa. Differential dissolution has considerable impact on the water chemistry estimates derived from transfer functions. Taphonomy, rather than environmental change, may have been responsible for minor fluctuations in the diatom assemblages from Manyara, although major palaeohydrological changes during the Late Pleistocene and Early Holocene can be identified. Particularly well represented by MANE-87 is a period of intermediate lake level between 27 500 and 23 000 ¹⁴C yr BP which has regional palaeohydrological significance.     

The CNSDTF topological vector model and structure

Geo-Spatial Data Transfer Standard is an important part of "National Spatial Data Infrastructure(NSDI)" ,as well as a necessary means for data sharing. "Chinese National Geo-Spatial Data Transfer Format (CNSDTF)" was approved by National Quality Technology Supervise Bureau in 1999 with the standard serial number of 17798-1999. It is designed to support vector and raster spatial data. This paper describes the vector part of CNSDTF, including design ideas, main characters, conceptual model, definition of spatial object, and file structure.     

A two-stage time series model for monthly hydrological projections under climate change in the Lim River basin (southeast Europe)

ABSTRACT

Climate change projections of precipitation and temperature suggest that Serbia could be one of the most affected regions in southeastern Europe. To prepare adaptation measures, the impact of climate changes on water resources needs to be assessed. Pilot research is carried out for the Lim River basin, in southeastern Europe, to predict monthly flows under different climate scenarios. For estimation of future water availability, an alternative approach of developing a deterministic-stochastic time series model is chosen. The proposed two-stage time series model consists of several components: trend, long-term periodicity, seasonality and the stochastic component. The latter is based on a transfer function model with two input variables, precipitation and temperature, as climatic drivers. The Nash-Sutcliffe model efficiency for the observed period 1950–2012 is 0.829. The model is applied for the long-term hydrological prediction under the representative concentration pathway (RCP) emissions scenarios for the future time frame 2013–2070.     

CT-1地震计传递函数测试仪的设计

将计算机控制技术应用到甚宽频带地震计的传递函数测试中。讨论了基本的测试方法和原理，阐述了传递函数测试系统的软、硬件设计，给出了测试系统的应用实例。该测试系统具有正弦波自动扫频、阶跃信号法和脉冲信号法等标定方法，满足了甚宽频带地震计的传递函数测试在观测频带、动态范围和测试精度等方面的要求。     

The transformation and export of phosphorus from Wetlands

There is widespread acceptance of the phosphorus retention capability of wetlands even though research findings are often inconclusive and contradictory. The results of a one year phosphorus budget study indicate that internal wetland processes may transform sediment bound phosphorus to plant available orthophosphorus. While total phosphorus imports were nearly double the total phosphorus exports for the study wetland, orthophosphorus exports were 22 per cent greater than imports. This study supports the recent finding that wetlands have limited capability to retain orthophosphorus and indicates that wetlands may even increase the export of orthophosphorus. The generally accepted nutrient retention function of wetlands and their possible role in eutrophication is thus questionable.     

Effects of high velocities on photoionization lines

We have treated formation of spectral lines in a commoving frame where photoionization is predominant over collisional processes. We have assumed that the radiation field for causing photoionization is a function of Planck function. We have also considered the situation in which the continuum contributes to the radiation in the line. In all the models the quantityB/A (ratio of outer to inner radii) is kept equal to 10 and the total optical depth is taken to be 10³. The velocity is assumed to be varying according to the lawdV/dτ ∼ < 1/τ whereτ is the optical depth (τ > 0) in the given shell. The velocities at the innermost radius (r =A) are set equal to 0 and at the outermost radius (r =B), the maximum velocities are taken to be 0, 1, 3 and 10 Doppler units. The calculated line profiles are those seen by an observer at infinity.P Cygni-type profiles are observed in the case of a medium with no continuum absorption. For a medium with continuum absorption double peaked asymmetric profiles are noticed when the velocities are small; the two emission peaks merge into a single asymmetric peak for larger velocities.     

Parameterization of the non-local thermodynamic equilibrium source function with chemical production by an equivalent two-level model

The classic two-level or equivalent two-level model that includes only the statistical equilibriumof radiative and thermal processes of excitation and quenching between two vibrational energy levelsis extended by adding chemical production to the rate equations. The modifications to the non-localthermodynamic equilibrium source function and cooling rate are parameterized by φc, which characterizesthe ratio of chemical production to collisional quenching. For applications of broadband emission of O3 at9.6 μm, the non-LTE effect of chemical production on the cooling rate and limb emission is proportionalto the ratio of O to O3. For a typical [O]/[O3], the maximum enhancements of limb radiance and coolingrate are about 15%-30% and 0.03-0.05 K day-1, respectively, both occurring near the mesopause regions.This suggests that the broadband limb radiance above ～80 km is sensitive to O3 density but not sensitiveto the direct cooling rate along the line-of-sight, which makes O3 retrieval feasible but the direct coolingrate retrieval difficult by using the O3 9.6 μm band limb emission.     

Meso-scale testing and development of test procedures to maintain mass balance

The Conrad Blucher Institute for Surveying and Science (Texas A&M University––Corpus Christi) has conducted numerous petroleum experiments at the Shoreline Environmental Research Facility (Corpus Christi, Texas, USA). The meso-scale facility has multiple wave tanks, permitting some control in experimental design of the investigations, but allowing for real-world conditions. This paper outlines the evolution of a materials balance approach in conducting petroleum experiments at the facility. The first attempt at a materials balance was during a 1998 study on the fate/effects of dispersant use on crude oil. Both water column and beach sediment samples were collected. For the materials balance, the defined environmental compartments for oil accumulation were sediments, water column, and the water surface, while the discharge from the tanks was presumed to be the primary sink. The “lessons learned” included a need to quantify oil adhesion to the tank surfaces. This was resolved by adhering strips of the polymer tank lining to the tank sides that could be later removed and extracted for oil. Also, a protocol was needed to quantify any floating oil on the water surface. A water surface (oil slick) quantification protocol was developed, involving the use of solid-phase extraction disks. This protocol was first tested during a shoreline cleaner experiment, and later refined in subsequent dispersant effectiveness studies. The effectiveness tests were designed to simulate shallow embayments which created the need for additional adjustments in the tanks. Since dispersant efficacy is largely affected by hydrodynamics, it was necessary to scale the hydrodynamic conditions of the tanks to those expected in our prototype system (Corpus Christi Bay, Texas). The use of a scaled model permits the experiment to be reproduced and/or evaluated under different conditions. To minimize wave reflection in the tank, a parabolic wave dissipater was built. In terms of materials balance, this design reduced available surface area as a sink for oil adsorption.     

The hydrogen emission spectrum of a shock wave in a stellar atmosphere

Based on a self-consistent solution of the equations of gas dynamics, kinetics of hydrogen atomic level populations, and radiative transfer, we analyze the structure of a shock wave that propagates in a partially ionized hydrogen gas. We consider the radiative transfer at the frequencies of spectral lines by taking into account the effects of a moving medium in the observer's frame of reference. The flux in Balmer lines is shown to be formed behind the shock discontinuity at the initial hydrogen recombination stage. The Doppler shift of the emission-line profile is approximately one and a half times smaller than the gas flow velocity in the Balmer emission region, because the radiation field of the shock wave is anisotropic. At Mach numbers M₁?10 and unperturbed gas densities σ₁=10^?10 g cm^?3, the Doppler shift is approximately one third of the shock velocity U₁. The FWHM of the emission-line profile δ _? is related to the shock velocity by δ _? ≈ k _? U₁, where k _? = 1, 0.6, and 0.65 for the Hα, Hβ, and Hγ lines, respectively.