Assessment of the effects of hydrocarbon contamination on the sedimentary bacterial communities and determination of the polar lipid fraction purity: Relevance of intact phospholipid analysis

This in situ study reports on the relevance of intact phospholipids as new biomarkers and highlights the limits of the classical fatty acid analysis after the hydrolysis of the polar lipid fraction. The analysis of polar lipid fractions revealed significant contributions of marine macrophytes with either non-phospholipid compounds (sulfoquinovosyl diacylglycerol) or with both non-bacterial phospholipid classes (phosphatidylcholine) and non-bacterial phospholipid molecular species (some molecular species of phosphatidylglycerol). The analysis of intact phospholipids showed also the predominance of gram-negative bacteria in sediments whereas the analysis of fatty acids alone cannot confirm such information. Lastly, as regard to the effects of petroleum hydrocarbons on the sedimentary bacterial communities, we observed a higher degree of saturation of the fatty acyl chains of the phospholipids extracted from sediment exposed to a massive and chronic crude oil contamination. Such a result was interpreted as an adaptive response resulting in higher membrane rigidity of the bacterial communities.     

烟威及石岛近海春季水团分析

本文使用1960—1980年春季的水文资料,以温度和盐度作为主要指标,根据聚类分析逼近温盐图解,结合对该海域地理环境特征的分析,对烟台、威海及石岛近海春季的水团结构演变及其和渔场、渔期的关系进行综合分析。结果表明,北黄海及青岛外海的冷水团,以及黄海暖水团的强度与位置的变动,对春季渔期的早迟以及渔场位置的变动,都有很大的影响。     

Micro-fracture instabilities in granular solids

We study the aspect of unstable behavior (like strain localization bands) in elastic solids as a consequence of micro-fracturing. A two-scale approach of computational homogenization is considered. The macroscopic behavior is investigated by finite element computations on a unit cell. At the micro-level, we consider a granular structure with elastic grains. The inter-granular boundaries are modeled with cohesive laws, friction and unilateral contact. We show that decohesion between grains gives rise to macro-instabilities, indicated by the loss of ellipticity, typical for deformation localization bands. The relation between the microscopic softening on inter-granular boundaries and the onset of macro-instabilities is studied through numerical examples. The influence of the cohesive law and friction parameters is analyzed. For periodic distributions of granular structures, we prove the loss of periodicity by failure and the corresponding size dependence effect in the homogenized response. We present numerical examples of bifurcation of solutions for granular cell structures and of particular solutions specific to elementary volumes with periodic cell distribution. Size dependence appears in the unstable regime and is strongly influenced by cohesion and friction parameters.     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

Sources of Sediment in Lake Pepin on the Upper Mississippi River in Response to Holocene Climatic Changes

Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 ¹⁴C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation, snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America.     

三维遥感影像数据库系统的研究与实现

介绍了以3S技术为手段，采用目前较为先进的三层结构体系，使用Dephi开发工具，结合数据库技术、遥感技术，尝试以数据库SQL Server组织、存储、管理海量的中巴资源卫星遥感影像数据和新疆1：10万地形矢量数据，应用OpenGL技术实现海量三维遥感影像数据的三维立体显示浏览，进而完成全疆三维遥感影像库建库和三维显示及漫游．     

Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

应用RMi法估算岩体变形模量

RMR法与Q法是国内外八、九十年代岩体质量和参数估算的常用方法,然而RMR法和Q法对质量较差的岩体不太实用,而RMi法是一种既适用于软岩又适用于硬岩的岩体质量评价和参数估算方法。本文在介绍RMi法基本原理的基础上,对贵州省鱼简河水库坝基岩体变形模量进行确定。