Meso-scale testing and development of test procedures to maintain mass balance

The Conrad Blucher Institute for Surveying and Science (Texas A&M University––Corpus Christi) has conducted numerous petroleum experiments at the Shoreline Environmental Research Facility (Corpus Christi, Texas, USA). The meso-scale facility has multiple wave tanks, permitting some control in experimental design of the investigations, but allowing for real-world conditions. This paper outlines the evolution of a materials balance approach in conducting petroleum experiments at the facility. The first attempt at a materials balance was during a 1998 study on the fate/effects of dispersant use on crude oil. Both water column and beach sediment samples were collected. For the materials balance, the defined environmental compartments for oil accumulation were sediments, water column, and the water surface, while the discharge from the tanks was presumed to be the primary sink. The “lessons learned” included a need to quantify oil adhesion to the tank surfaces. This was resolved by adhering strips of the polymer tank lining to the tank sides that could be later removed and extracted for oil. Also, a protocol was needed to quantify any floating oil on the water surface. A water surface (oil slick) quantification protocol was developed, involving the use of solid-phase extraction disks. This protocol was first tested during a shoreline cleaner experiment, and later refined in subsequent dispersant effectiveness studies. The effectiveness tests were designed to simulate shallow embayments which created the need for additional adjustments in the tanks. Since dispersant efficacy is largely affected by hydrodynamics, it was necessary to scale the hydrodynamic conditions of the tanks to those expected in our prototype system (Corpus Christi Bay, Texas). The use of a scaled model permits the experiment to be reproduced and/or evaluated under different conditions. To minimize wave reflection in the tank, a parabolic wave dissipater was built. In terms of materials balance, this design reduced available surface area as a sink for oil adsorption.     

Characteristics and formation causes of Qingdao Cold Water Mass

In this work,the main characteristics of the Qingdao Cold Water Mass were studied by using“the comparison analysis method”based on 1980 temperature,salinity and dissolved oxygen data on the western South Yellow Sea.The formation cause of the water mass was analyzed based on February of 1959 temperature and salinity data for this area and on some other authors’studies.The results showed that the Qingdao Cold Water Mass has growing and vanishing processes：appears in the last ten days of March;has stable pattern in April;is biggest in its area in May;becomes small in its area in June;vanishes in July.It comes from the northem Shandong Coastal Water and is characterized by low temperature and salinity and high disolved oxygen.The mass is formed under the joint effects of anticyclonic circulation and solar radiation.     

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.     

Quasi-stationary flow structure in turbidity currents

A turbidity current is a particle-laden current driven by density differences due to suspended sediment particles. Turbidity currents can transport large amounts of sediment down slopes over great distances, and play a significant role in fluvial, lake and submarine systems. To better understand the sediment transport process, the flow system of an experimentally produced turbidity current in an inclined flume was investigated using video processing. We observed that the current progresses with constant frontal velocity and maintains an unchanged global interface geometry. In addition, the spatio-temporal profiles of the inner mean and turbulence velocity obtained by ultrasound velocity profiler (UVP) showed that similar distributions were maintained, with low dissipation. The results indicate that the turbidity current progressed in a quasi-stationary state, which enabled long-distance sediment transport. To understand the mechanisms behind the quasi-stationary flow, we analyzed the forces acting on the turbidity current. We found that under particular densities of suspended particles, the gravitational force is balanced by the viscous forces along the slope direction. We conclude that this specific force balance induces the quasi-stationary flow structure, enabling the long-distance transport of a substantial amount of sediment downstream with low dissipation.     

Mass flows and river response in rapid uplifting regions – A case of lower Yarlung Tsangpo basin,southeast Tibet,China

The fluvial geomorphology in tectonically active (particularly rapid uplift) regions often undergoes continuous change. The rapid uplift is coincident with high erosion rates; consequently, incised valleys are formed. Mass flows (for example, avalanches, landslides, and debris flows) in incised valleys can markedly influence fluvial processes and even reshape valley geomorphology. However, these processes and long-term evolution corresponding to mass flows require further clarification. Field campaigns were carried out in the region near the Yigong Tsangpo and Palong Tsangpo Rivers (hereafter the Yigong and Palong Rivers), the two largest tributaries of the lower Yarlung Tsangpo River, to examine the feedback between fluvial processes and mass flows. Remote sensing images from recent decades were used to compare the channel morphology before and after typical mass flows (particularly catastrophic ones). The morphology of the lower Yigong River has evidently been impacted by landslides, while that of the Palong River has mainly been shaped by glacial processes and debris flows. At present, the morphology of the latter consists of alternating sections of gorges and wide valleys, with a staircase-like longitudinal profile. The gorge sections exhibit single and deeply incised channels with a high-gradient channel bed and terraces. In contrast, the wide valley sections consist of lakes, braided or anabranching channels, gentle bed gradients, and thick alluvial deposits. Debris flows occur more frequently in gullies in the reaches of the gorge sections and rarely in gullies along the wide valley sections. The occurrence of mass flow events has resulted in an imbalance of the previous (quasi-)equilibrium in the river morphology; however, this has triggered negative feedback that is driving the transient river morphology to a new state of (quasi-)equilibrium.     

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.     

Erosion and deposition by debris flows at Mt Thomas,North Canterbury,New Zealand

The grass-covered slopes on the southern flank of Mt Thomas, an upfaulted block of highly sheared sandstone and argillite 40 km NW of Christchurch, New Zealand, are presently undergoing severe erosion by a combination of mass-wasting processes. Gully erosion, soil slips, and debris flows have carved out a number of steep, deeply incised ravines, from which coarse debris is transported (primarily by debris flows) to alluvial fans below. Geologic and historical evidence indicates that debris flows have been episodically active here for at least the last 20,000 years and have been the dominant process in fan building. This demonstrates that catastrophic geomorphic processes, rather than processes acting at relatively uniform rates, can be dominant in humid-temperate areas as well as in arid and semi-arid regions. In April 1978, debris flows were triggered in one of two unstable ravines in the Bullock Creek catchment by a moderate intensity, long duration rainstorm with a return period in excess of 20 years. Surges of fluid debris, moving at velocities up to 5 m/s, transported a dense slurry of gravel, sand, and mud up to 3·5 km over a vertical fall of 600 m. Deposition on the alluvial fan occurred when the flows left the confines of an entrenched fan-head channel and spread out as a 0·16 km² sheet averaging 1·2 m thick. In all, 195,000 m³ were deposited, roughly a third of that being reworked sediments from the head of the fan. Sediment yield from this one event would be equivalent to several thousand years worth of erosion at average sediment discharge rates for small South Island mountain catchments. Samples of viscous fluid debris during surges contained up to 84 per cent solids, composed of 70 per cent gravel, 20 per cent silt, and 4 per cent clay. Fluid density of the material ranged between 1·95 and 2·13 g/cm³, and it was extremely poorly sorted. Between surges the fluid was less viscous, less dense, and unable to carry gravel in suspension. Severe fan-head entrenchment of the stream channel (approximately 10 m in less than 24 hours) was accomplished by the erosive action of the surges. Tectonic uplift of the Mt Thomas block and the weak, crushed condition of the bedrock appear to be ultimately responsible for the catastropic erosion of slopes in the Bullock Creek catchment. However, forest clearing within the last few centuries appears to have greatly increased the rate of mass wasting and gully erosion on these slopes.     

Analysis of Astex-Stratocumulus Observational Data Using a Mass-Flux Approach

A mass-flux approach is applied to observational data obtained in a convective boundary layer topped with stratocumulus clouds. The observational data were obtained from aircraft measurements during the Atlantic Stratocumulus Transition Experiment (ASTEX). A conditional sampling method is used to calculate average updraft and downdraft values. The vertical fluxes calculated with the mass-flux approach are found to be proportional to the real (measured) fluxes, with a proportionality factor being about 0.6. This value is predicted by theory for two variables having a joint Gaussian distribution function; proportionality factor = 2^-1 0.637. The horizontal fractional entrainment and detrainment rates calculated from the data ( 1–2 × 10^-2 m^-1) are an order of magnitude higher than the rates obtained by large eddy simulations for cumulus convection ( 2–3 × 10^-3 m^-1) and two orders of magnitude higher than those used in modelling cumulus convection with a mass-flux scheme in an operational weather forecast model ( 3 × 10^-4 m^-1). A numerical mass-flux model for the thermodynamics was developed and showed that results are in good agreement when compared with measured profiles of the liquid water content.     

A mass balance approach to estimate the dilution and removal of the pollutants in stream water polluted by acid mine drainage

 A few simple mass balance equations were developed to simultaneously estimate how much the pollutants from acid mine drainage (AMD) in stream water are diluted and removed during their migration. The application of the equations requires knowledge of the variations in the concentrations of the dissolved pollutants and the stoichiometry of the precipitation reaction of the pollutants when none of the pollutant shows a conservative behavior along the stream path. The calculation should be restricted to the pollutants showing much higher concentrations in the polluted main stream water than in the combining or diluting water of the same target area. The mass balance equations were applied to estimate the dilution factor and precipitation fractions of pollutants in Imgok Creek such as Fe, SO₄ and Al from the AMD of Yeongdong mine. The results show that the estimation, especially for SO₄ and Al, significantly depends on the kinds of the precipitates. When FeOHSO₄ and AlOHSO₄ are assumed to precipitate, the maximum removal fractions of SO₄ and Al by precipitation are respectively 34% and 46% of the original input, which is much higher than the values estimated when SO₄ is considered to be perfectly conservative. It indicates that the stoichiometry of precipitation reaction is very important in the interpretation of the pollutant dilution and migration and assessment of environmental impacts of AMD. The applicability of the mass balance equations may still need to be verified. However, examining the calculated dilution factor and precipitation fractions with the equations can provide invaluable information on not only the behavior but also unexpected input of the pollutants in the stream water polluted by AMD and other point sources. Received: 12 November 1997 · Accepted: 30 March 1998     

New INTEGRAL sources and TeV emission

INTEGRAL is operational since more than three years and producing high quality data that allows to detect fainter new hard X-ray sources. The new sources, identified until now, are mostly active galactic nuclei and absorbed or transient high mass X-ray binaries. TeV emission could be expected from the new high mass X-ray binaries accreting dense clumps of stellar wind. INTEGRAL sources with TeV counterparts are discussed. Based on observations with INTEGRAL, an ESA project with instruments and science data centre funded by ESA member states (especially the PI countries: Denmark, France, Germany, Italy, Switzerland, Spain), Czech Republic and Poland, and with the participation of Russia and the USA.