变质玄武岩体系相平衡及矿物 熔体微量元素分配：限定TTG/埃达克岩形成条件和大陆壳生长模型

埃达克质岩石是高Na、Al和Sr、低Y和HREE以及Nb、Ta亏损的钠质花岗质岩石,奥长花岗岩-英云闪长岩-花岗闪长岩(TTG)是早期(太古宙)大陆壳主要组分,成分与埃达克质岩石相似,这些成分独特的岩石总体上认为是俯冲洋壳、下地壳和拆沉的下地壳中变质玄武岩部分熔融的产物。文中综述我们近年来在变质玄武岩体系相平衡和矿物-熔体微量元素分配实验研究成果:相平衡实验和熔体微量元素特征研究表明,变质玄武岩部分熔融过程中金红石是导致TTG/埃达克岩浆Nb、Ta亏损的必要残留矿物,从而否定了前人“TTG由无金红石的角闪岩熔融产生”的观点;证实金红石仅仅在压力1.5GPa以上才能稳定存在,从而限定TTG/埃达克岩熔体必定产生在大约50km以上,表明TTG/埃达克岩是在相对较深的含金红石榴辉岩相条件下熔融产生的。矿物(石榴子石、角闪石,单斜辉石和金红石)-熔体微量元素分配系数测定和部分熔融模拟结果进一步限定俯冲洋壳和下地壳起源的TTG/埃达克岩浆由含金红石角闪榴辉岩熔融产生,而拆沉下地壳起源的埃达克岩浆的产生要求软流圈地幔高温,由无水或含有少量含水矿物的榴辉岩熔融产生。     

A new solution for a partially penetrating constant‐rate pumping well with a finite‐thickness skin

A mathematical model describing the constant pumping is developed for a partially penetrating well in a heterogeneous aquifer system. The Laplace‐domain solution for the model is derived by applying the Laplace transforms with respect to time and the finite Fourier cosine transforms with respect to vertical co‐ordinates. This solution is used to produce the curves of dimensionless drawdown versus dimensionless time to investigate the influences of the patch zone and well partial penetration on the drawdown distributions. The results show that the dimensionless drawdown depends on the hydraulic properties of the patch and formation zones. The effect of a partially penetrating well on the drawdown with a negative patch zone is larger than that with a positive patch zone. For a single‐zone aquifer case, neglecting the effect of a well radius will give significant error in estimating dimensionless drawdown, especially when dimensionless distance is small. The dimensionless drawdown curves for cases with and without considering the well radius approach the Hantush equation (Advances in Hydroscience. Academic Press: New York, 1964) at large time and/or large distance away from a test well. Copyright © 2007 John Wiley & Sons, Ltd.     

VTI介质多波速度与各向异性系数求取及应用

针对具有垂直对称轴的横向各向同性(VTI)介质,研究了多波速度与地层各向异性系数之间的关系。采用适应大偏移距以及强各向异性介质的双平方根方程,进行速度和各向异性系数分析,并将批量计算与交互解释相结合,实现了高精度各向异性介质多波速度与各向异性系数提取,并形成了一套利用多波地震资料求取地震波纵、横波速度及各向异性系数的方法和软件。所求取的参数可用于多波地震资料处理,提高多波资料的成像质量,也可为地层地质解释提供参考。实际资料的应用效果证明了该方法和软件的正确性及有效性。     

GPS载波相位三差观测方程的改化

本文根据相关测量平差原理推导出改化ＧＰＳ载波相位三差观测方程的算法，使改化后的协因数呈分块对角体。这种改化算法不但顾及观测值的相关性，而且节省大量的存储单元。使采用严密平差法平差三差观测值成为一种最简单的数据处理方法之一。     

基于岭估计的有理多项式参数求解方法

在使用最小二乘法解算卫星遥感影像的RPC参数时,如果控制点非均匀分布或模型过度参数化,其法方程系数矩阵很容易产生病态,获得的解将偏离真值,甚至得到错误的解。使用岭估计可改善法方程的状态,保证解稳定。采用岭估计方法,通过所获取的不同岭参数对SPOT和QuickBird影像进行实验,证实L曲线法是一种稳定的、有效的岭参数确定方法,可显著提高RPC参数的解算精度。     

A SEARCH TECHNIQUE FOR CHOOSING OPTIMUM PARAMETERS IN NUMERICAL WEATHER PREDICTION

The steepest descent(or ascent)search is employed for finding optimum diffusion coefficients in T42L9Gmodel,with a view to improving the model's computational stability or prediction accuracy.The method of thesteepest descent search is first described,in which the golden section search is chosen as the fundamental one-dimensional search used in the multi-dimentional steepest descent search,and then the optimization of the dif-fusion coefficients is described.     

Reconstructed light extinction coefficients using chemical compositions of PM<Subscript>2.5</Subscript> in winter in Urban Guangzhou,China

The objective of this study was to reconstruct light extinction coefficients (b ext ) according to chemical composition components of particulate matter up to 2.5 μm in size (PM 2.5 ). PM 2.5 samples were collected at the monitoring station of the South China of Institute of Environmental Science (SCIES, Guangzhou, China) during January 2010, and the online absorbing and scattering coefficients were obtained using an aethalometer and a nephelometer. The measured values of light absorption coefficient by particle (b ap ) and light scattering coefficient by particle (b sp ) significantly correlated (R 2 > 0.95) with values of b ap and b sp that were reconstructed using the Interagency Monitoring of Protected Visual Environments (IMPROVE) formula when RH was <70%. The measured b ext had a good correlation (R 2 > 0.83) with the calculated b ext under ambient RH conditions. The result of source apportionment of b ext showed that ammonium sulfate [(NH 4 ) 2 SO 4 ] was the largest contributor (35.0%) to b ext , followed by ammonium nitrate (NH 4 NO 3 , 22.9%), organic matter (16.1%), elemental carbon (11.8%), sea salt (4.7%), and nitrogen dioxide (NO 2 , 9.6%). To improve visibility in Guangzhou, the effective control of secondary particles like sulfates, nitrates, and ammonia should be given more attention in urban environmental management.     

Use of Nash's IUH and DEMs to identify the parameters of an unequal‐reservoir cascade IUH model

Under the assumption that hydrograph generation was affected by n linear reservoirs with the same value of storage coefficient k, Nash proposed the formulation of the Instantaneous Unit Hydrograph (IUH), which has been widely used in rainfall–runoff simulation and flood forecasting. However, the assumption of the parameter k having the same value in all reservoirs is obviously unphysical as it results in the estimated value of n not being integral. In this study, for parameter n integral, the different k value for each reservoir was derived using the Laplace transform and developing a general rule for the equation of the IUH of any order. The relationship between parameter k and the slope of the river channel estimated using digital elevation model (DEM) data is established, the parameter estimation procedures are given. As in most unit hydrograph studies, only isolated storm events are considered here. Seventeen flood events in three catchments were selected for the case studies. Application results show that the proposed method is slightly better than Nash's IUH with higher model efficiency and smaller absolute relative errors. This work provides a new methodology for the formulation of the IUH. Copyright © 2008 John Wiley & Sons, Ltd.     

Chemical and physical properties affecting strontium distribution coefficients of surficial-sediment samples at the Idaho National Engineering and Environmental Laboratory, Idaho

 The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study to determine strontium distribution coefficients (K_ds) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using synthesized aqueous solutions were used to determine K_ds, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from the INEEL. The K_ds for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations, and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium K_ds of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations with strontium K_ds were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and –0.6518, respectively. Sediment properties with the strongest correlations with strontium K_ds were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022, and –0.6660, respectively. Effects of solution properties on strontium K_ds were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption sites; effects of sediment properties on strontium K_ds were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted in r² values of 0.8071 when all five properties were used and 0.8043 when three properties, equilibrium pH, MnO, and BET surface area, were used. Received: 30 November 1998 · Accepted: 16 February 1999     

The use of remotely sensed land cover to derive floodplain friction coefficients for flood inundation modelling

Remotely sensed land cover was used to generate spatially‐distributed friction coefficients for use in a two‐dimensional model of flood inundation. Such models are at the forefront of research into the prediction of river flooding. Standard practice, however, is to use single (static) friction coefficients on both the channel and floodplain, which are varied in a calibration procedure to provide a “best fit” to a known inundation extent. Spatially‐distributed friction provides a physically grounded estimate of friction that does not require fitting to a known inundation extent, but which can be fitted if desired. Remote sensing offers the opportunity to map these friction coefficients relatively straightforwardly and for low cost. Inundation was predicted using the LISFLOOD‐FP model for a reach on the River Nene, UK. Friction coefficients were produced from land cover predicted from Landsat TM imagery using both ML and fuzzy c‐means classifiction. The elevetion data used were from combined contour and differential global positioning system (GPS) elevation data. Predicted inundation using spatially‐distributed and static friction were compared. Spatially‐distributed friction had the greatest effect on the timing of flood inundation, but a small effect on predicted inundation extent. The results indicate that spatially‐distributed friction should be considered where the timing of initial flooding (e.g. for early warning) is important. Copyright © 2007 John Wiley & Sons, Ltd.