A Multi‐Element Ion‐Pair Extraction for Trace Metals Determination in Environmental Samples

A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L^?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples.     

察尔汗盐湖别勒滩区段晶间卤水的主要离子分布特征

通过野外采集样品、室内实验分析,研究了察尔汗盐湖别勒滩区段晶间卤水的主要离子分布特征。采集了53个晶间卤水样品,通过分析,发现K+浓度一般随着深度的增加而减小,Li+浓度一般随着深度的增加而增加,Mg2+浓度随着深度增加浓度也在增加,但异常情况同样存在。Li+,B2O3在空间分布上有一个富集区域,越是远离这一区域离子含量就越低;K+含量则存在两个临界点,在临界点附近相关离子浓度和矿化度会变化。     

复杂构造三维地震观测系统设计的共聚焦分辨率分析

三维地震观测系统共聚焦分辨率特性分析突破传统以点论证为基础的观测系统分辨率分析方法,面向地质目标定量预测三维观测系统地震成像的空间分辨率和振幅精度.基于Fourier有限差分（FFD）大步长波场延拓和Born-Kirchhoff小步长波场插值递推方法,本文介绍了一种复杂介质条件下三维地震观测系统共聚焦分辨率特性快速分析方法.对给定的速度模型,该方法能够分析拟采用的三维地震观测系统设计方案对复杂构造的成像分辨率与AVP属性,从而为进一步的偏移成像与储层分析提供保证.最后本文以SEG/EAGE三维盐丘模型为例设计满覆盖为16次的三维地震观测系统,并实施三维共聚焦分辨率特性分析.     

西藏改则6.9级地震前的电离层电磁扰动

2008年1月9日西藏改则县发生6.9级地震, 震前2天法国DEMETER卫星飞过震中上空时记录到离子温度(Ti)和超低频电场异常。 文中通过震前10天内多条轨道的数据对比和分析处理, 对空间异常的识别和判定给出了两种有效的方法, 同时也积累了空间地震电磁前兆震例和异常信号判别的经验。     

Diachronous evolution of volcano-sedimentary basins north of the Congo craton: Insights from U–Pb ion microprobe dating of zircons from the Poli, Lom and Yaoundé Groups (Cameroon)

Ion microprobe U–Pb dating of zircons from Neoproterozoic volcano-sedimentary sequences in Cameroon north of the Congo craton is presented. For the Poli basin, the depositional age is constrained between 700–665 Ma; detrital sources comprise ca. 920, 830, 780 and 736 Ma magmatic zircons. In the Lom basin, the depositional age is constrained between 613 and 600 Ma, and detrital sources include Archaean to Palaeoproterozoic, late Mesoproterozoic to early Neoproterozoic (1100–950 Ma), and Neoproterozoic (735, 644 and 613 Ma) zircons. The Yaoundé Group is probably younger than 625 Ma, and detrital sources include Palaeoproterozoic and Neoproterozoic zircons. The depositional age of the Mahan metavolcano-sedimentary sequence is post-820 Ma, and detrital sources include late Mesoproterozoic (1070 Ma) and early Neoproterozoic volcanic rocks (824 Ma). The following conclusions can be made from these data. (1) The three basins evolved during the Pan-African event but are significantly different in age and tectonic setting; the Poli is a pre- to syn-collisional basin developed upon, or in the vicinity of young magmatic arcs; the Lom basin is post-collisional and intracontinental and developed on old crust; the tectono-metamorphic evolution of the Yaoundé Group resulted from rapid tectonic burial and subsequent collision between the Congo craton and the Adamawa–Yade block. (2) Late Mesoproterozoic to early Neoproterozoic inheritance reflects the presence of magmatic event(s) of this age in west–central Africa.     

拉果错盐湖卤水蒸发过程中Li+富集行为的分子动力学模拟(英文)

采用分子动力学模拟,研究了西藏拉果错盐湖卤水中阴、阳离子以及水分子间的相互作用行为。以盐湖卤水等温蒸发过程中粒子浓度变化的四个阶段为研究对象,分别计算了不同体系的扩散系数、配位数、均方位移和径向分布函数。计算结果表明,液相浓度越低时,H₂O分子对各离子之间的相互作用有抑制作用,液相中离子浓度越高时,SO₄^2-易与CO₃^2-竞争Li⁺形成离子对,从而影响盐湖卤水中Li⁺的富集。本文研究结果对盐湖卤水中Li⁺的迁移行为作出了机理解释,为盐湖卤水提锂的发展奠定了理论基础。     

汉诺坝幔源单斜辉石巨晶氢同位素组成的离子探针分析：微尺度不均一性

运用离子探针技术测定了河北汉诺坝新生代玄武岩中3个单斜辉石巨晶的氢同位素组成，结果显示同一颗粒内部表现出微尺度的不均一性，2mm范围内δD的变化达到60‰。δD和氢含量之间不存在同步的变化，巨晶内部的化学成分均一，因此我们认为巨晶的氢同位素不均一性继续自母岩浆。母岩浆的氢同位素变化可能是去气过程中气相与熔体之间的分馏引起的。单斜辉石巨晶形成后很短的时间内即被寄主岩浆带至地表并经历了快速淬火。     

离子色谱法测定水样中S~(2-)、SO_3~(2-)、SO_4~(2-)、S_2O_3~(2-)

该种方法利用离子色谱仪的电导检测器与电化学检测器串联 ,十几分钟即可连续完成水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3 的测定 ,方法具有快速、高效、方便、灵敏、选择性好等特点。方法的检出限分别为 :S2 - 12 5 μg/L ;SO2 - 3 2 2 4 μg/L ;SO2 - 45 0 μg/L ;S2 O2 - 35 0 μg/L。相对标准偏差在 1 5 %～ 6 9%之间 ,能够满足水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3四种阴离子分析测试的需要。     

云、雨水酸度和离子浓度与其微物理参数的关系

本文1987年5-6月和1989年5-6月庐山地区的实测资料,分析了云、雨水酸度和离子浓度与其微物理量间的关系。结果表明,云、雨滴大小、含水量、谱宽等微物理量的演变直接影响着其酸度和离子浓度。     

柴达木盆地昆特依盐湖大盐滩矿区卤水地球化学特征分析

大盐滩作为柴达木盆地重要的液体钾盐赋存地之一,开展卤水水文地球化学研究能够有效指导钾矿的合理、长期开采。利用改进的Collins图、相关性系数、变异系数及离子等值线图等地球化学分析手段,探讨了该地区卤水水化学变化特征及影响因素。结果显示,目前该地区的卤水类型均为Cl-Na型;研究区内主要卤水化学成分变异程度不大,Na~+及Cl~-在空间上呈东北高、西南低的分布特征,其余离子均表现出反向的分布规律;研究区内地球化学特征变化除了受到溶滤作用影响外,还在很大程度上受到卤水开采及淡水补给的影响;卤水开采及淡水补给从某种程度上改变了沉积层的物理结构,使地层渗透系数的不均匀性增强;人工淡水补给能够渗入到卤水潜水层中,从而增加可开采卤水量,但对卤水矿化度的影响情况尚不明确。