注水煤体应力能 V-f 转化与释放机理研究

文章分析了在煤层注水湿润后煤体弹性能的转化与消耗过程，给出在湿润状态下能量由体变弹性能向形变弹性能转化进而自耗释放的理论模型。指出在坚硬干燥煤体中，注水后在水压力和毛细力的切割作用下，裂隙大量扩展，丰富了自由裂隙，产生更多的裂隙启发(裂隙切口)，使原来近似的刚性煤体变成由裂隙分割的块体组成的组合体或半组合体。裂隙中水的粘滞作用及水分子吸附力使块体问粘性结合、刚度降低、形变增大。煤体形变弹性能自身消耗释放的形式有3种：产生剪应力导致自由裂隙问错动摩擦；强度降低，使裂隙启发被劈裂成自由裂隙；湿润煤体蠕变性增强，产生整体性移动作功。初步给出能量消耗的量化表达式。通过这一理论，能建立煤层注水湿润度与冲击地压灾害发生的更直接的关系，使进一步量化该关系成为可能。从更深层次解释煤层注水防治冲击地压的机理。     

温度变化对夏季降温耗能的影响

该文采用降温度日数作为评估夏季降温耗能的指标 ,分析了我国夏季降温度日分布和长期变化特征。温度与降温耗能相关分析表明 ,两者相关密切 ,相关程度随气温升高而增加 ;降温耗能的 1℃效应量 ,北方大于南方。文章最后 ,利用气温距平与降温度日变率建立了夏季降温耗能评估模型。     

波包传播诊断的理论基础和计算方法

文中提出了一种新的利用实际观测资料研究波包传播的诊断方法 (WPD) ,并通过理想资料和实际资料的计算证明了该方法的可用性和广泛性     

土壤热异常对地表能量平衡影响初探

将来自土壤深部的热通量引入off line的陆面过程模式 (NCAR—LSM ) ,通过长达 2a的数值试验对比分析了它对各层次土壤温度和地表能量平衡的影响。　　在土壤底部引入 5W /m2 的热通量使底层土壤显著升温 ,但升温随着接近表层而迅速衰减。积分 3个月后 ,由地下进入地表的热流量增幅可达 1W/m2 以上 ,并持续增大到 5W /m2 ,地表最大升温约 0 .5K ,同时地表感热、蒸发潜热及长波辐射通量均有 1W /m2 左右的正异常 ;若将土壤热传导系数放大一个量级以加速热量交换 ,则地表升温提高到 1K以上 ,长波辐射增加 3W /m2 以上 ,超过了气溶胶全球平均的辐射效应。结果表明 :一定量值的土壤热异常对地表能量平衡和短期气候变化 (10 -1～ 10 1a)有着不可忽略的影响。同时 ,深入的资料分析、完善的陆面过程模式以及它与大气模式的耦合试验也是亟待进行的相关工作。     

土壤热异常影响地表能量平衡的个例分析和数值模拟

The statistical relationship between soil thermal anomaly and short-term climate change is presented based on a typical case study. Furthermore, possible physical mechanisms behind the relationship are revealed through using an off-line land surface model with a reasonable soil thermal forcing at the bottom of the soil layer.In the first experiment, the given heat flux is 5 W m-2 at the bottom of the soil layer (in depth of 6.3 m)for 3 months, while only a positive ground temperature anomaly of 0.06℃ can be found compared to the control run. The anomaly, however, could reach 0.65℃ if the soil thermal conductivity was one order of magnitude larger. It could be even as large as 0.81℃ assuming the heat flux at bottom is 10 W m-2. Meanwhile, an increase of about 10 W m-2 was detected both for heat flux in soil and sensible heat on land surface, which is not neglectable to the short-term climate change. The results show that considerable response in land surface energy budget could be expected when the soil thermal forcing reaches a certain spatial-tem poral scale. Therefore, land surface models should not ignore the upward heat flux from the bottom of the soil layer. Moreover, integration for a longer period of time and coupled land-atmosphere model are also necessary for the better understanding of this issue.     

Electrical aerosol spectrometer of Tartu University

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.     

Optimal design of passive energy dissipation systems based on H∞ and H2 performances

Passive energy dissipation devices (EDDs), such as viscous dampers, viscoelastic dampers, etc., have been used to effectively reduce the dynamic response of civil infrastructures, such as buildings and bridges, subject to earthquakes and strong winds. The design of these passive energy dissipation devices (EDDs) involves the determination of the optimal locations and the corresponding capacities. In this paper, we present two optimal design methodologies for passive EDDs based on active control theories, including H_∞ and H₂ performances, respectively. The optimal design methodologies presented are capable of determining the optimal locations and the corresponding capacities of EDDs. Emphasis is placed on the application of linear matrix inequality (LMI) for the effective design of passive EDDs using the popular MATLAB toolboxes. One important advantage of the proposed approaches is that the computation of the structural response is not needed in the design process. The proposed optimal design methodologies have been applied to: (i) a 10‐storey building and a 24‐storey building both subject to earthquake excitations, and (ii) a 76‐storey wind‐excited benchmark building, to demonstrate the advantages of the proposed design methodologies over the conventional equal capacity design. Copyright © 2002 John Wiley & Sons, Ltd.     

Damaging properties of ground motions and prediction of maximum response of structures based on momentary energy response

Dynamic damaging potential of ground motions must be evaluated by the response behaviour of structures, and it is necessary to indicate what properties of ground motions are most appropriate for evaluation. For that purpose, the behaviour of energy input process and hysteretic energy dissipation are investigated in this study. It is found that the momentary input energy that is an index for the intensity of input energy is related to the characteristics of earthquakes such as cyclic or impulsive, and to the response displacement of structures immediately. On the basis of these results, a procedure is proposed to predict inelastic response displacement of structures by corresponding earthquake input energy to structural dissipated damping and hysteretic energy. In this procedure the earthquake response of structures is recognized as an input and dissipation process of energy, and therefore structural properties and damaging properties of ground motions can be taken into account more generally. Lastly, the studies of the pseudodynamic loading test of reinforced concrete structure specimens subjected to ground motions with different time duration are shown. The purpose of this test is to estimate the damaging properties of ground motions and the accuracy of the proposed prediction procedure. Copyright © 2002 John Wiley & Sons, Ltd.     

25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Spectroscopic evidence for pressure-induced phase transitions in diopside

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002