High-pressure experimental growth of diamond using C–K2CO3–KCl as an analogue for Cl-bearing carbonate fluid

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.     

Three-dimensional forward and backward modelling of diapirism: numerical approach and its applicability to the evolution of salt structures in the Pricaspian basin

Numerical studies of ductile deformations induced by salt movements have, until now, been restricted to two-dimensional (2D) modelling of diapirism. This paper suggests a numerical approach to model the evolution of three-dimensional (3D) salt structures toward increasing maturity. This approach is also used here to restore the evolution of salt structures through successive earlier stages. The numerical methodology is applied to study several model examples. We analyse a model of salt diapirs that develop from an initial random perturbation of the interface between salt and its overburden and restore the evolved salt diapirs to their initial stages. We show that the average restoration errors are less than 1%. An evolutionary model of a 2D salt wall loaded by a 2D pile of sediments predicts a decomposition of the salt wall into 3D diapiric structures when the overburden of salt is supplied by 3D synkinematic wedge of sediments. We model salt extrusion feeding a gravity current over the depositional surface and estimate an average rate of extrusion and horizontal velocity of salt spreading. Faulting of the overburden to salt overhangs initiates new secondary diapirs, and we analyse the growth of these secondary diapirs. We also study how lateral flow effects the evolution of salt diapirs. The shape of a salt diapir can be very different if the rate of horizontal flow is much greater than the initial rate of diapiric growth solely due to gravity. We discuss the applicability of the results of the models to the evolution of Late Permian salt structures in the Pricaspian basin (Russia and Kazakhstan). These structures are distinguishable into a variety of styles representing different stages of growth: salt pillows, diapirs, giant salt massifs, 2D diapiric walls and 3D stocks complicated by large overhangs. The different sizes, shapes and maturities of salt structures in different parts of the Pricaspian basin reflect areal differences in salt thickness and loading history. Our results suggest that the numerical methodology can be employed to analyse the evolution of all salt structures that have upbuilt through younger ductile overburdens.     

基于不同退耕模式的黄土丘陵区生态环境建设地域分异特征

退耕是目前国家关于黄土丘陵区生态环境建设的主体措施。在总结"赈济退耕25"、"赈济退耕15"和"梯田退耕"各模式基本特点的基础上,根据土地利用、耕地坡度分级数据、农业人口数据和不同模式生态环境建设标准,分别计算了黄土丘陵区各县(市、区)退耕25°和15°以上坡耕地、新建园地、新修梯田、林草植被恢复的面积以及相应的投资需求额度。在构建并采用生态环境建设指数、政策性补贴资金密度指数和投资需求密度指数等指标,对55个县(市、区)进行类型划分的基础上,分析了黄土丘陵区不同退耕模式下的生态环境建设规模及投资需求地域分异特征。     

Relationship between solar radiation and the development and morphology of small cirque glaciers (Maladeta Mountain massif, Central Pyrenees, Spain)

Abstract Spatial and temporal variations in radiative fluxes influence glacier mass‐balance in mountain areas. The primary goal of this study was to assess differences in solar radiation on three glacial cirques located in the Maladeta Mountain massif (Central Spanish Pyrenees), and analyse their implications on glacier development and morphology. A quantitative approach is adopted to obtain the values of solar radiation (direct, diffuse and global radiation), combining several field data parameters (measured at 55 control‐points) with the solar radiation modelling package Ecosim. The data obtained confirm that the morphologies of the glacial bodies developed in the three cirques have a good correlation with the spatial variation on solar radiation inputs, favouring also the conservation (Aneto and Coronas cirques) or total vanishing (Llosás cirque) of the glacial remnants analysed here. The study shows how strongly in this Alpine‐Mediterranean context solar radiation — firstly as a function of latitude and time of year, and locally as a function of topographic slope, aspect and shadowing — controls the mass‐balance and the spatial distribution of melting in small glaciers, having an effect on the development of their morphologies.     

利用现有重力场模型求定CHAMP卫星加速度计修正参数

CHAMP卫星加速度计数据的标定是通过确定其尺度因子和偏差参数来完成的.本文基于能量守恒方程,给出利用现有重力场模型标定CHAMP卫星加速度数据的基本原理和数学模型;提出相邻历元间差分算法,大大简化了观测方程,同时避免积分常量的计算.该算法既能同时解算尺度因子和偏差参数,也可任意求解其中之一.基于实测的CHAMP卫星加速度数据,利用EGM96模型和最新公布的EIGEN-2模型进行计算与比较,验证该方法的有效性.     

Testing links between river patterns and in-channel characteristics using MRPP and ANOVA

This study tests the assumption that the characteristics of channels within multiple channel rivers are different from those of single channel rivers. Some river restoration approaches propose radical transformation of river patterns, from multiple to single channels, based on the link between river patterns and their in-channel characteristics. Determining the links between river patterns and their in-channel characteristics is complicated by differences in geology, history, climate and discharge among rivers. Furthermore, multiple channel rivers are composed of a mosaic of channel types with a range of in-channel characteristics. This study minimizes these problems by analysing a single river containing neighbouring single and multiple channel patterns with little change in discharge downstream, and by analysing all channel types. The study addressed two objectives: to determine the hydraulic geometry, energy, and sediment mobility characteristics of neighbouring single and multiple channel river patterns, and to test for statistical differences in these characteristics between patterns. The Renous River shows a wandering pattern for 11.5 km, with multiple channels around semipermanent islands and abandoned channels in the flood plain. The river displays a single channel river pattern where channels are confined by their valley walls, upstream and downstream of wandering. The analysis was conducted at three scales. First, the confined single channel and wandering multiple channel patterns were compared (pattern scale). Second, the confined channel pattern was compared to single and multiple channel sections within the wandering pattern (section scale). Third, all channel types were compared (channel type scale). Multi response permutation procedure (MRPP) and analysis of variance (ANOVA) were used to analyze differences between channels. Difference tests found no simple discrimination between the single and multiple channel river patterns of the Renous River. Tests between the single confined and multiple wandering channel patterns found few differences in the in-channel variables. The tests did find differences between multiple channel sections within the wandering pattern and confined single channels; however, a greater number of differences were found between multiple channel and single channel sections within the wandering pattern, highlighting the variability within the wandering pattern. Two groups emerged when all channel types were tested for differences: perennial main-channels containing the thalweg, and ephemeral side-channels. Therefore, side-channels define the in-channel characteristics of wandering rivers because few differences were found among main-channels in either pattern. This analysis suggests that all channel types, not just main-channels, should be investigated to obtain a complete picture of a river pattern prior to any restoration efforts. Engineers must exercise caution when applying the link between river patterns and in-channel characteristics to river restoration efforts.     

Channel Bed Mobility Downstream from the Elwha Dams,Washington*

Dams are a major source of fragmentation and degradation of rivers. Although substantial research has been conducted on the environmental impacts of large structures in the United States, smaller dams have received less attention. This study evaluated the impact of two dams of moderate size, the Elwha Dams, on the downstream channel system using field data collection at river cross‐sections. The relationship of average boundary shear stress (τ_o) to critical shear stress (τ_cr) served as the basis for determining channel bed material mobility under the two‐year and ten‐year flood events. The channel had the greatest channel bed mobility at the natural cross‐section upstream from the dams, low bed mobility between the structures, and an increase in channel bed mobility in the low gradient river segment near the mouth of the river. Low bed mobility tended to be associated with a lack of channel system complexity, including reduction or loss of bars and low alluvial terraces and their associated young riparian communities. Although these run‐of‐the‐river dams do not modify streamflow greatly, the loss of sediment from the channel system has had a substantial impact on bed mobility and geomorphic and biotic complexity of the Elwha River.     

The reflection of plane waves in a poroelastic half-space saturated with inviscid fluid

This paper discusses surface displacements, surface strain, rocking, and energy partitioning during reflection-of-plane waves in a fluid-saturated poroelastic half-space. The medium is modeled by Biot's theory, and is assumed to be saturated with inviscid fluid. A linear porosity-modulus relation based on experimental data on sandstones is used to determine the material parameters for Biot's model. Numerical results in terms of angle of incident waves and Poisson's ratio are illustrated for various porosities and degrees of solid frame stiffness. The results show that the amount of solid frame stiffness controls the response of a fluid-saturated porous system. A poroelastic medium with essentially dry-frame stiffness behaves like an elastic medium, and the influence of pore fluid increases as dry-frame stiffness is reduced. The effects of a second P-wave become noticeable in poroelastic media with low dry-frame stiffness.     

Experimental and theoretical study of stability of dense hydrous magnesium silicates in the deep upper mantle

Fluid-undersaturated experiments were conducted to determine the phase relations in the simplified peridotite system MgO-SiO₂-H₂O (MSH) at 11.0-14.5 GPa and 800-1400 °C. Stability relations of dense hydrous magnesium silicates (DHMSs) under fluid-undersaturated conditions were experimentally examined. From the fluid-absent experimental results, we retrieved thermodynamic data for clinohumite, phase A, phase E, and hydrous wadsleyite, consistent with the published data set for dry mantle minerals. With this new data set, we have calculated phase equilibria in the MSH system including dehydration reactions. The dehydration reactions calculated with lower water activities of 0.68-0.60 match the fluid-present experiments of this study above 11.0 GPa and 1000 °C, indicating that considerable amounts of silicate component were dissolved into the fluid phase. The calculated phase equilibria illustrate the stability of the post-antigorite phase A-bearing assemblages. In the cold subducting slab peridotite, phase A + enstatite assemblage survives into the transition zone, whereas phase A + forsterite + enstatite assemblage forms hydrous wadsleyite at a much shallower depth of about 360-km. The slab is subducted with no dehydration reactions occurring when entering the transition zone. The phase equilibria also show the high temperature stability of phase E. Phase E is stable up to 1200 °C at 13.5 GPa, a plausible condition in the mantle of relatively low temperature, i.e., beneath subduction zones. Phase E is a possible water reservoir in the mantle as well as wadsleyite and ringwoodite.