The effect of anatase, rutile and sodium titanate on the dissolution of boehmite and gibbsite at 90 °C

Industrial plants that refine bauxite to alumina using the high temperature process have always held the belief that anatase was detrimental to the extraction of boehmite while rutile was not. This study shows that this effect is real and that it is observable at temperatures as low as 90 °C. The extraction of gibbsite is shown to be unaffected which leads us to believe that the kinetics of both the Ti-bearing mineral and the Al-bearing mineral is important in this phenomenon. In addition, it is shown that not only is the presence of anatase an issue in boehmite extraction but so too is the presence of sodium titanate. Rutile was found to have the least impact of the three mineral phases.     

Intrusion and its implication for subsidence: A case from the Baiyun Sag, on the northern margin of the South China Sea

We develop a series of simple numerical models to explain the anomalous subsidence and deposition phenomena on the northern continental margin of the South China Sea, in particular in the Baiyun Sag. The results suggest that a short-period high rate deposition of around 17 Ma is related to a rapid subsidence event, which may be due to episodic emplacement of a dense intrusion. Necking and gravity models indicate that in the basement of the Baiyun Sag, there is a dense zone that is 100–200 kg/m³ more dense than the surrounding country rock. Considering its high magnetic intensity and regional igneous activity, the dense zone is thought to be related to a phase of basalt intrusion that may have taken place around 17 Ma. Thermal and subsidence models indicate that a hot denser intrusion can cause significant subsidence immediately after the intrusion. The subsidence rate then slows down with cooling, thus becoming consistent with the observed subsidence curves at around 17 Ma. The results also indicate that the lithospheric strength under the Baiyun Sag is negligible, and that the high-velocity layer in the lowermost crust may be not an original part of the pre-rift crust. Instead, it is thought to be underplated intrusion emplaced at around 30 Ma when the continental margin broke up.     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

RegCM3对山东夏季气候高分辨率模拟

利用区域气候模式RegCM3及NCEP/DOE再分析资料,对山东地区1985-2000年夏季区域气候变化进行了高分辨率(20 km)的数值模拟试验.通过对模拟结果和山东地区较密集的观测资料的比较分析,检验了模式在该地区的模拟能力.结果表明:(1)区域气候模式RegCM3能够合理地模拟出山东区域中高层的主要环流特征;(2)数值模拟能够合理再现山东地区16 a夏季平均降水南高北低和地面气温西高东低的主要分布特征.同时也能够合理地模拟出1990和1998年山东地区夏季强降水的主要特征,以及1992和1999年的干旱;(3) 模式结果较好地反映了1985-2000年16 a夏季山东地区降水和地面气温变率的主要特征.     

深圳市高影响天气的风廓线雷达特征

利用深圳多年风廓线雷达观测资料,分析了灰霾、大雾、高温、雷暴、台风、冷空气等高影响天气过程中的风廓线特征。结果表明风廓线雷达作为一种新型的探测工具,能够在垂直方向获取较高时间、空间分辨率的实时资料,为分析、预报预警高影响天气提供了新的资料和观测事实。不同的高影响天气风廓线特征各不相同。灰霾和高温以上空出现东北风为特征:大雾的水平、垂直方向分布与信噪比有关;雷暴等强对流天气具有明显的风垂直切变;热带气旋、西风槽和锋面等移动性天气系统,其风向、风速的垂直分布随时间有明显变化。     

海冰非均匀条件下大气环流模式和海洋环流模式耦合的实现

通过采用一种较好地考虑了海气通量交换对下垫面特征非线性依赖的通量计算方案,利用较成熟的逐日通量距平耦合方案实现了次网格尺度海冰非均匀条件下一个全球大气环流模式和一个全球海洋环流模式在高纬地区的耦合,并完成了一个50年的长期积分。模拟结果表明,通量计算方案中水道的作用是合理的,耦合模式能较好地模拟出北半球高纬海冰的主要地理分布特征,但夏季北冰洋内部靠近欧亚大陆部分边缘海区海冰密集度偏大。     

中尼公路多年冻土工程地质性质分析及整治设计

通过对中尼公路嘉措拉山多年冻土工程地质性质的分析,确定其为高温多年冻土,热稳定性属不稳定型;并对此多年冻土的整治原则、路基合理高度、路基路面综合设计进行了探讨。     

四川九寨黄龙机场高填方地基变形三维动力分析

四川九寨黄龙机场具有高填方、高地震烈度、高海拔等三高的特点,高填方体地基在地震作用下的动力稳定与变形问题成为该机场需着重考虑的主要工程地质问题之一。在对目前各种动力分析方法研究的基础上,选用快速拉格郎日差分分析(FLAC)程序,对该机场元山子沟段高填方地基在地震作用下的变形规律进行了系统地研究,获得了一些有实际意义的认识。     

北斗卫星导航系统双差动力法精密定轨及其精度分析

针对GEO卫星切向轨道分量与双差模糊度强相关的问题,对经典双差动力法进行了改进,提出联合使用载波相位和相位平滑伪距实现北斗系统精密定轨,并从理论上分析了以上处理策略的可行性及对模糊度固定的影响,然后结合北斗系统精密定轨特点,推导给出了利用QIF方法实现北斗卫星双差模糊度固定的基本原理,实测数据分析表明:联合载波相位和相位平滑伪距,既可降低相关性,又可兼顾精度,定轨效果优于经典双差动力法;利用QIF方法能够取得一定的模糊度固定效果,但受观测条件限制,北斗卫星双差模糊度固定成功率整体不高,双差模糊度固定之后对轨道的改进作用有限。     

A Study of the Extended-range Forecast for the Low Frequency Temperature and High Temperature Weather over the Lower Reaches of Yangtze River Valley in Summer

Based on the observational data, the variations of Intraseasonal Oscillation (ISO) of the daily temperatures and its relationships to the high temperature in summer over the lower reaches of the Yangtze River Valley (LYRV) were studied for the period of 1979-2011. It is found that the daily temperatures over LYRV in May-August was mainly of periodic oscillations of 1525, 3060 and 6070 days, and the interannual variation of the intensity of its 3060-day oscillation had a strongly positive correlation with the number of days with daily highest temperature over 35 ℃ in July-August. Low frequency components of daily temperature in the LYRV, and the principal components of the Eastern Asian 850 hPa low frequency temperature, over a time period ranging from 1979 to 2000, were used to establish the Extended Complex Autoregressive model (ECAR) on an extended-range forecast of the 3060-day low frequency temperature over the LYRV. A 11-year independent real-time extended-range forecast was conducted on the extended-range forecast of low frequency component of the temperature over the LYRV in May-August, for the period ranging from 2001 to 2011. These experimental results show that this ECAR model, which is based on a data-driven model, has a good forecast skill at the lead time of approximately 23 days, with a forecast ability superior to the traditional autoregressive (AR) model. Hence, the development and variation of the leading 3060-day modes for the Eastern Asian 850 hPa low frequency temperatures and temporal evolutions of their relationships to low frequency components of the temperature over the LYRV in summer are very helpful in predicting the persistent high temperature over the LYRV at a 20 to 25 days lead.