Response of a tunnel deeply embedded in a viscoelastic medium

This paper presents a three‐dimensional energy‐based solution for the time‐dependent response of a deeply embedded and unsupported semi‐infinite tunnel of circular cross‐section. The tunnel is taken to be excavated quasi‐instantaneously from an infinite rock body that initially exhibits an isotropic stress state and that is made up of a homogeneous, isotropic and viscoelastic material. The viscoelastic behaviour is modelled by means of Burger's model, and the rock is taken to behave volumetrically linear elastic and to exhibit exclusively deviatoric creep. This viscoelastic problem is transformed into the Laplace domain, where it represents a quasi‐elastic problem. The displacement fields in the new solution are taken to be the products of independent functions that vary in the radial and longitudinal directions. The differential equations governing the displacements of the system and appropriate boundary conditions are obtained using the principle of minimum potential energy. The solutions for these governing equations in the Laplace domain are then obtained analytically and numerically using a one‐dimensional finite difference technique. The results are then transformed back into the time domain using an efficient numerical scheme. The accuracy of the new solution is comparable with that of a finite element analysis but requires much less computation effort. Copyright © 2011 John Wiley & Sons, Ltd.     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

Compression mechanisms of coesite

 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s₂₃ and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.     

几种电法仪器在地质勘查中的应用

文章介绍了几类物探电法仪器的工作原理、技术特点和适用范围,强调了物探资料的合理解释必须与地质认识相结合的重要性,物探工作要做实做细,对物探原始资料要选择合理的方法与参量进行计算处理,结合一些具体的勘测实例,说明各种方法的有效性及其实际应用效果.     

溶洞对路基稳定性影响分析——以常张高速公路K122+200路基为例

利用弹塑性理论和有限差分方法,对常张高速公路下伏溶洞处理前后对路基变形和稳定性影响进行了计算分析和评价。计算结果表明,在汽车动载作用下,常张高速公路K122+ 200路基和溶洞上部土层产生较大的塑性变形, 整个路基处于不稳定状态。进一步分析表明,溶洞的顶板厚度是影响路基稳定性的主导因素,随着顶板厚度的增加,路基地面变形迅速减小。K122+ 200路基下伏溶洞采用回注水泥粘土浆液加固处理后,路基变形和溶洞上部土体的塑性变形明显减小,可见回注水泥粘土浆液加固溶洞效果明显,能满足工程建设的要求。      

Characterization of high molecular weight biomarkers in crude oils

High-temperature gas chromatography (HTGC) has enhanced our ability to characterize hydrocarbons extending to C₁₂₀ in crude oils. As a result, hydrocarbons in waxes (> C₂₀) have been observed to vary significantly between crude oils, even those presumed to originate from the same source. Prior to this development, microcrystalline waxes containing hydrocarbons above C₄₀ were not characterized on a molecular level due to the analytical limitations of conventional gas chromatography. Routine screenings of high pour-point crude oils by high-temperature gas chromatography has revealed that high molecular weight hydrocarbons (> C₄₀) are very common in most oils and may represent 2% of the crude oil. Precise structures, origins, and significance of these high molecular weight compounds remain elusive. As a preliminary step to expand our knowledge of these compounds their general molecular structures and formulas have been investigated in this study. Initial results suggest that the major high molecular weight compounds include a homologous series of n-alkanes, methylbranched alkanes, alkylcyclopentanes, alkylcyclohexanes, alkylbenzenes and alkylcycloalkanes.     

Comparative Study of the Carbon Emission Situation and Goals between China and India

As the two large developing and populous countries, China and India face the dual challenges of economic development and climate change. Both of them are active in carbon emissions reduction, while India also bears the pressure of being “benchmarked” against China. With taking China and India as the sample of a comparative analysis, and the statistical value of a long sequence as the basic analysis data, based on the detailed analysis and comparison of carbon emissions history, the carbon emissions situation of the two countries from various dimensions including economic development, energy reserves and consumption, etc. were comparatively analyzed. The carbon intensity and energy structure after achieving the objectives were measured and compared by focusing on the carbon emissions reduction targets in China and India. The comparative results show that: China’s total carbon emissions are greater than India’s, but the growth rate of emissions, per capita emissions are significantly lower than India’s, while the carbon intensity decreases significantly faster than that of India. China has taken more efforts to make commitments to carbon reduction than India. With India’s energy structure adjustment, the situation will be gradually better than that in China.     

滇东北渔户村组内的富铅锌矿床成矿地质特征及成因

渔户村组为滇东北富铅锌矿床的重要产出层位。通过茂粗、金沙厂、五星、乐红、大海等矿床，总结了滇东北渔户村组内的富铅锌矿床的地质特征及成因，认为其与喷流沉积成矿作用和后期改造作用有关，为海底火山喷流沉积－改造成因。     

Electrical Resistivity Imaging technique to delineate coal seam barrier thickness and demarcate water filled voids

Exploration and exploitation of coal seams is one of the major resources for the energy sector in any country but at the same time water filled voids/water logged areas in the old workings of these seams are very critical problems for the coal mining industry. In such situations, disasters like inundation, landslides, collapsing of the old seams may occur. In this regard, it is necessary to find out the water saturated/water filled voids and zones in the mining areas. Since no established technique is available to find such zones, an experimental study using Electrical Resistivity Imaging (ERI) has been carried out in one of the coal mining areas near Dhanbad, to find out the feasibility of finding the barrier thickness and the water logged area in underground coal mines. The area under study forms part of Jharia coalfield in Dhanbad district, Jharkhand state. The coal bearing rocks of Barakar Formation of Lower Permian age (Gondwana period) occur in the area under a thin cover (10 m to15 m) of soil and or alluvium. Coal bearing Barakar Formations consist mainly of sandstone of varying grain size, intercalation of shale and sandstone, grey and carbonaceous-shale and coal seams. Since the water saturation reduces the resistivity of a formation to a large extent, water filled voids and old coal workings are expected to have significant resistivity contrast with the surrounding host rock. Hence, ERI technique was applied in such an environment as this technique uses high-density data acquisition both laterally and vertically by using multiple number of electrodes. Along with ERI, mise-à-la-masse (also called charged body) technique was also employed at one of the promising sites to find out the connectivity of water logged areas and also detection of these old workings from the surface measurements was analyzed. The interpreted 2D resistivity sections have clearly indicated the water bearing zone(s) along the profile which was well confirmed with the existing water level in the nearby borewells. On the other hand, this technique did not identify the size of the coal pillar and gallery (air filled voids), which might be due to the small size of the voids (i.e. about 2 m × 2 m) below a depth of 15m and more but have indicated altogether as a high resistive zone ranging from 600–1000 Ohm-m.     

钙质砂在三轴剪切中颗粒破碎评价及其能量公式

钙质砂是一种易破碎粒状材料。本文在分析颗粒破碎机理的基础上,提出了颗粒破碎与剪胀耦合作用的破碎功表示式,并用实验证明了相对破碎Br 与1,Wp,WB 之间的关系,从而建立了钙质砂颗粒破碎的评价指标及其能量公式。