混合表面活性剂存在下镓与O—Cl—PF显色反应的研究

本文研究了在pH 6.5-7.8的(CH_2)_6N_4-HCl缓冲介质中,CDMAA和TritonX-100对Ga与o-Cl-PF和F~-显色反应的增敏作用。结果表明,Ga-o-Cl-PF-F-CDMAA-TritonX-100多元配合物λ_(max)为565nm,表观摩尔吸光系数ε=1.74×10~5L·mol~(-1)·Cm~(-1),Ga含量在0～6.0μg/25ml范围内符合比尔定律,用合成样和标样进行本方法考验,结果满意。     

Calculation of partial melting equilibria in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH)

A thermodynamic model for haplogranitic melts in the system Na₂O–CaO–K₂O–Al₂O₃–SiO₂–H₂O (NCKASH) is extended by the addition of FeO and MgO, with the data for the additional end‐members of the liquid incorporated in the Holland & Powell (1998) internally consistent thermodynamic dataset. The resulting dataset, with the software thermocalc , is then used to calculate melting relationships for metapelitic rock compositions. The main forms for this are P–T and T–X pseudosections calculated for particular rock compositions and composition ranges. The relationships in these full‐system pseudosections are controlled by the low‐variance equilibria in subsystems of NCKFMASH. In particular, the solidus relationships are controlled by the solidus relationships in NKASH, and the ferromagnesian mineral relationships are controlled by those in KFMASH. However, calculations in NCKFMASH allow the relationships between the common metapelitic minerals and silicate melt to be determined. In particular, the production of silicate melt and melt loss from such rocks allow observations to be made about the processes involved in producing granulite facies rocks, particularly relating to open‐system behaviour of rocks under high‐grade conditions.     

The impact of fragment “L” of comet SL-9 on Jupiter

Filtergrams of high spatial and temporal resolution were obtained in the methane band centred at 892 nm during the impact of fragment L of comet Shoemaker-Levy 9 on Jupiter. The light curve shows two maxima of an emission ball observed above the limb shortly after the impact. The second maximum was the brightest and had a short life time of about 90 seconds. During it's life, the apparent height of the emission ball declined towards the surface of Jupiter; the amount of displacement is larger than the expected effect caused by Jupiter's rotation. About half an hour after the impact, a domelike feature became visible when the location of the impact rotated into the illuminated hemisphere of Jupiter.     

Herbig-Haro objects—tracers of the formation of low-mass stars and sub-stellar objects

Herbig-Haro objects (HHOs) are caused by outflows from young objects. Since the outflow relies on mass accretion from a circumstellar disk, it indicates ongoing growth. Recent results of infrared observations yielded evidence for disks around brown dwarfs. This suggests that at least a certain fraction of brown dwarfs forms like stars. Thus, young sub-stellar objects might cause HHOs as well. We present selected results of a general survey for HHOs based on DSS-II plates and CCD images taken with the Tautenburg Schmidt telescope. Numerous young objects could be identified due to their association with newly detected HHOs. In some cases the luminosity is consistent with very low-mass stars or close to sub-stellar values. This holds for L1415-IRS and a few infrared sources embedded in other dark clouds (e.g., GF9, BHR111). The question on the minimum mass for outflow activity is addressed.     

An integrated linear/non-linear flow model for the conduit-fissure-pore media in the karst triple void aquifer system

Most karstic aquifer media may be characterized as the triple-void media with highly-varied hydraulic properties, including matrix pore, fissure and conduit, in which liner flow may co-exist with non-linear flow. In this paper, an attempt is made to couple linear flow with non-linear flow in a single unified flow governing equations by introducing the concept of equivalent hydraulic conductivity (EHC) and deriving a general Darcys law for various flow. The expression of EHC in the karst conduit and fissure are also derived. The procedures of numerical implementation are demonstrated via an ideal model and a case study of karst aquifer system in the Beishan Ore Formation area, Guangxi Autonomous Region, China.     

Stochastic Hill's equations for the study of errant rocket burns in orbit

The problem of errant rocket burns in low Earth orbit is of growing interest, especially in the area of safety analysis of nuclear powered spacecraft. The development of stochastic Hill's equations provides a rigorous mathematical tool for the study of such errant rocket maneuvers. These equations are analyzed within the context of a theory of linear dynamical systems driven by a random white noise. It is established that the trajectories of an errant rocket are realizations of a Gauss-Markov process, whose mean vector is given by the solution of a deterministic rocket problem. The time-dependent covariance matrix of the process is derived in an explicit form.     

新型人工引雷专用火箭及其首次引雷实验结果

成功研制了一种新型的人工引雷专用火箭, 火箭箭体结构采用了新型复合材料, 质量轻, 并具有空中抛伞和放线功能。利用新型火箭和全新的雷电流及同步电磁场测量技术, 在2009年的山东人工引雷实验 (SHATLE2009) 中成功引发负极性云对地放电过程3次, 共包括6次大电流回击过程, 采用0.5 mΩ的大功率同轴分流器和宽带光纤传输技术测量到了0.1 μs时间分辨率的雷电流波形、以及距雷电通道30 m、60 m和480 m处的电磁场和6000 f/s的高速摄像观测资料。6次回击的电流峰值分布范围为11.2～16.3 kA, 几何平均值12.8 kA; 半峰值宽度为7.4～34.9 μs, 几何平均值21.6 μs; 10%～90%峰值的上升时间为0.5～1.4 μs, 几何平均值1.0 μs。成功的人工引发雷电实验证明新型引雷火箭安全性能好、可靠性高, 其成功研制为雷电物理过程和效应的研究, 以及雷电流波形资料的积累提供了重要的技术手段, 对制定具有我国自主知识产权的雷电防护标准等具有重要的应用价值。     

Recent sediment transport and accumulation on the NW Iberian margin

Five transects across the NW Iberian margin were studied in the framework of the EU-funded Ocean Margin EXchange II (OMEX II) project, to determine and establish recent sediment and organic carbon transport and accumulation processes and fluxes.On the Galician shelf and shelf edge, resuspension of sediments resulting in well-developed bottom nepheloid layers was observed at all stations, but transport of suspended sediment appears largely confined to the shelf. On the continental slope, only very dilute bottom nepheloid layers were present, and intermediate nepheloid layers were only occasionally seen. This suggests that cross-slope transfer of particles is limited by the prevailing northerly directed shelf and slope currents.Optical backscatter and ADCP current measurements by the BOBO lander, deployed at 2152 m depth on the Galician slope, indicated that particles in the bottom boundary layer were kept in suspension by tidal currents with highest speeds between 15–25 cm s⁻¹. Net currents during the recording period August 6th–September 10th 1998, were initially directed along-slope toward the NNW, but later turned off-slope toward the SW.The separation of the water masses on the slope from the sediment-laden shelf water by the along-slope current regime is reflected in the recent sedimentary deposits of the Galician shelf and slope. Apart from compositional differences, shelf deposits differ from those on the slope by their higher flux of excess ²¹⁰Pb (0.57–5.37 dpm cm⁻²y⁻¹ versus 0.11–3.00 dpm cm⁻²y⁻¹), a much higher sediment accumulation rate (315.6–2295.9 g m⁻²y⁻¹ versus 10.9–124.7 g m⁻²y⁻¹) and organic carbon burial rate (1.01–34.30 g m⁻²y⁻¹ versus 0.01–0.69 g m⁻²y⁻¹).In contrast to the observations on the Galician margin, pronounced nepheloid layers occurred in the Nazaré Canyon, which extended to considerably greater water depths. This indicates that significantly greater transport of fine-grained particles in both the INL and the BNL was occurring within the canyon, as reflected in the exceptionally high ²¹⁰Pb excess flux (up to 34.09 dpm cm⁻²y⁻¹), mass accumulation rates (maximum 9623.1 g m⁻²y⁻¹) and carbon burial fluxes (up to 180.91 g m⁻²y⁻¹) in the sediment. However, radioisotope fluxes in the lower canyon were only slightly higher than at comparable depths on the Galician margin. This suggests that transport and rapid accumulation is focused on the upper and middle part of the canyon, from where it is episodically released to the deep sea. Compared to the Galician margin, the Nazaré Canyon may be considered as an important organic carbon depocenter on short time-scales, and a major conduit for particulate matter transport to the deep sea on >100 y time-scales.     

复杂区域对象拓扑关系分解与计算

本文提出了基于9交矩阵的拓扑关系计算方法,将复杂区域分解有限个简单区域,采用正则表达式描述其多部分和洞构成,通过定义两个9交关系矩阵操作算子,利用分解区域间的拓扑关系直接计算复杂区域间的9交关系矩阵。详细证明和分析了两个操作算子的不成立条件以及消除不成立条件的方法。结合关系矩阵表法拓扑关系的推导和推理过程,操作算子可用于推导已知结构复杂区域间的所有可能9交拓扑关系。同时,9交关系矩阵操作算子依赖复杂区域的定义,不适用于所有区域对象。