海底热流探测技术综述

热流探测是一项重要的基础地球物理调查项目,使用探针式热流计测量海底热流是常用的方法.自二十世纪中期以来,先后出现的三种主要的热流计:Bullard型、Ewing型和Lister型,使热流探测的精度和效率有了很大的提高.文中比较详细地介绍了这三种热流计的主要技术特点,分析了我国海底热流探测的现状与不足,并对热流探测技术未来的发展进行了展望.     

Hydrogen Isotopic Compositions of Pyroxenes in Nushan Peridotite Xenoliths,SE China

Hydrogen isotopic compositions of pyroxenes in peridotite xenohths from the Nushan volcano, Anhui Province, SE China have been obtained using an ion probe (Cameca 1270). D/H ratios are constant within a single grain and among the different grains from the same sample. The lack of correlation between the D/H ratios and the hydrogen contents indicates that the hydrogen isotopic compositions are inherited from their mantle source. Combining with the δD values of coexisting amphiboles, it is inferred that the Nushan mantle experienced at least a two-stage metasomatic event.One was responsible for formation of amphiboles with extremely variable δD values, and the other was probably responsible for the high δD values (up to -20‰) of some clinopyroxenes from peridotites, clinopyroxene and mica megacrysts. High δD values point to a subduction-related fluid being involved in one metasomatic event. The primary δD values (-90‰ to -140‰) of the Nushan pyroxenes, together with data gleaned from the literature, suggest that the D/H ratios of the nominally anhydrous mineral reservoir might have differed from that of the other mantle hydrogen in being relatively depleted in D.     

电子探针分析技术进展及面临的挑战

电子探针是研究地球与行星物质组成最基础的微束分析技术。近年来,固体地球科学和行星科学的不断发展,促使电子探针分析技术取得了一系列进展:矿物微量元素分析、稀土矿物测试方法完善、副矿物定年、富Fe矿物/熔体Fe~(3+)含量测定、场发射电子探针及软X射线分析谱仪的开发及应用等。同时,电子探针分析技术也面临着诸多挑战:微量元素测试在降低检测限的同时,还需要提高分析的准确度和精确度;降低二次荧光效应的影响;场发射电子探针在低电压下需要建立全新的分析条件和校正方式。基于这些挑战,电子探针未来在微量元素监测标样开发、二次荧光效应校正、场发射电子探针及软X射线分析谱仪应用、波谱仪完善和微区多种分析技术集成等方面具有发展潜力,以便为地学样品的研究提供更丰富、更准确的微米尺度成分信息。     

祁漫塔格成矿带磁铁矿Fe2+/Fe3+比值测定方法对比研究

为了厘清磁铁矿成分测试过程中Fe²⁺/Fe³⁺比值分析各种方法的准确性及适用范围;采用直接测氧法、Lβ/Lα强度比值法、电价差值法、剩余氧法和穆斯堡尔谱法,对祁漫塔格成矿带中典型矿床中磁铁矿的Fe²⁺/Fe³⁺比值进行了研究,结果表明电价差值法、剩余氧法和穆斯堡尔谱法是相对比较准确的测试方法,但穆斯堡尔谱法不是原位分析方法,存在适用范围的缺陷。     

Overcoming Challenges Associated with the Analysis of Nacre by Atom Probe Tomography

In this study atom probe tomography was used to study nacre, an important biocomposite material that is challenging to prepare and analyse by atom probe and, when successful, yields data that is challenging to interpret. It was found that these challenges mainly arise from the insulating and heterogeneous nano‐scale properties of nacre. We outline our current best practice for preparing and running atom probe tips, such as using a low acceleration voltage (< 3 kV) and current (≤ 50 pA) to avoid damage to the microstructure, and using transmission electron microscopy to confirm that the region of interest is located close to the apex of the atom probe tip. Optimisation of the preparation parameters led to several successful atom probe experiments, with one of the data sets containing part of an organic membrane and others showing organic inclusions within the reconstruction.     

New Olivine Reference Material for In Situ Microanalysis

A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.     

白榆、新疆杨液流动态比较研究

运用Granier热扩散式探针(TDP)法对宁夏河东沙地主要乔木树种白榆（Ulmus pumila）和新疆杨（Populus alba）夏初边材液流变化规律进行连续观测。利用自动气象站对周围气象因子如太阳辐射（Rs）、空气温度（Ta）、空气相对湿度（RH）和风速（Ws）进行同步观测,并对气象因子与白榆、新疆杨边材液流通量(Fs)的相关性进行分析。结果表明：①白榆、新疆杨边材液流速率（Vs）变化规律存在显著差异,白榆Vs主体表现为窄小双峰型,新疆杨Vs主体表现为宽峰波动型;白榆日间液流启动时间较新疆杨提前0.0~0.8 h,峰值出现时间推迟0.0~2.0 h,峰值持续时间较新疆杨缩短2.5~6.7 h,液流消退时间提前0.0~2.5 h。②白榆边材液流通量(Fs)仅为0.50 kg·h-1,而新疆杨高达1.25 kg·h-1,为白榆的2.5倍;白榆日耗水量（W）在8.81~17.73 kg·d-1之间,而新疆杨W在22.82~34.06 kg·d-1之间。③白榆、新疆杨在夜间保持一定的液流量以补充白天所耗水分,夜间水分补充量对各自日耗水量的贡献相近,为8%左右。④白榆、新疆杨Fs与气象因子关系密切,但气象因子的作用过程表现复杂。复相关分析表明：白榆、新疆杨Fs与Rs、Ta、Ws之间呈极显著正相关,与相对湿度RH呈极显著负相关,按相关程度排序为：Rs>RH>Ta>Ws。     

探针原子化石墨炉原子吸收法测定高纯金属镁中痕量铝

采用探针恒温原子化技术的石墨炉原子吸收 ,测定高纯金属镁中的痕量铝 ,利用样品中的基体镁转化成硝酸镁成为一种有效基体改进剂 ,进一步改善了铝的分析性能。实验优化了仪器条件和分析方法。结果表明 ,在有Mg(NO3) 2 存在时 ,可显著提高探针原子化测铝的灰化温度 ,降低原子化温度 ,并且使铝的灵敏度提高了 50 %。方法的检出限为 2 .2× 1 0 - 1 1 gAl,测定 50 μg/LAl标准溶液的相对标准偏差 (n =1 2 )为 3.1 %。用该法测定了 4个金属镁内部管理样品中Al的含量 ,结果与推荐值相符合 ,其RSD(n =6)为 3.4%～ 1 1 .0 %。     

NMOHEMS探头外形对其下沉运动的影响分析

NMOHEMS 探头是一种由无人机运载的小型投掷式探头,采用混合网格技术结合湍流模型,建立了探头下沉运动的数值计算方法,分析了导流腔、收缩段及尾翼对探头下沉运动的影响;通过6种外形探头在不同雷诺数下的阻力系数和相同质量下的极限速度对比,发现探头外形对其下沉运动数值计算的结果影响较大;其中导流腔和收缩段均具有明显的减阻作用,且收缩段的影响更大,而尾翼具有一定的增阻作用;lgRe 在2.3~3.8时,6种外形探头的阻力系数差别较大,随着雷诺数的增加,阻力系数均迅速减小;lgRe 在3.8~5.1时,6者的阻力系数比较接近,虽仍然保持减小趋势,但变化趋于缓慢.NMOHEMS 探头的体型较小,下沉速度较慢,对其下沉运动进行数值计算时,必须考虑外形对数值计算结果的影响.     

Huygens probe entry dynamic model and accelerometer data analysis

During the first phase of Huygens arrival into Titan's atmosphere the probe is subjected to gravitational and aerodynamic forces in aerodynamic hypersonic regime. Atmospheric drag exerts a strong deceleration on the capsule measured by Huygens atmospheric structure instrument (HASI) servo accelerometer. A 6 DOF (Degree of Freedom) model of the Huygens probe entry dynamics has been developed and used for data analysis. The accelerometer data are analysed and the model allows the retrieval of dynamics information of Huygens probe from 1545 km altitude down to end of the entry phase. Probe's initial conditions (velocity and position) were refined to match the measured deceleration profile resulting in a different altitude at interface epoch with respect to those of the Cassini Navigation Team. Velocity and position of probe at interface epoch are compatible with those used by Descent Trajectory Working Group (DTWG).Measurements acquired before atmosphere detection are used to estimate probe's angular rate, bound attitude and characterise the angle of attack profile which results to be lower than 4^° during the whole entry. Probe's spin calculated (6.98 RPM) is slightly different with respect to DTWG of 7.28 RPM but considering a 2% error in the Inertia matrix these results are inside the 1-σ error band.