金属成矿学研究的若干进展

主要讨论近１０年来国内外在金属矿床地质研究中的若干进展，内容包括：成矿地质环境和深部背景；矿床、成矿带和全球的成矿作用演化；成矿系统和成矿动力学；地质流体与成矿作用以及超大型矿床的形成条件等。在这５个重点研究领域中，分别介绍了对它们的研究和已取得的一些进展，又展望了其在今后的研究前景。认为上述５个方面的系统深入研究，将构成２１世纪上半世纪新的成矿理论基础，并将对金属矿产勘查工作有重大影响。     

乌鲁木齐河源1号冰川积累区透底冰芯地层及冰结构分析

对乌鲁木齐河源１号冰川积累区一支深达９１．６４ｍ的透底冰芯进行了详细的层位及冰结构分析，结果表明，在２０ｍ深度以内，很好地保存了原始沉积的特征，但在７０￣８０ｍ深处还发现小密度的乳白色冰占优势的冰层，可能形成于小冰期，中层具有动力变质及再结晶作用共存及反复消长的结构特征（冰晶尺寸、气泡），未见单极大型组构，但出现弱竖环形组构，底层出现弱宝石状的多极大组构。     

淮南谢—矿煤的组成对甲烷吸附性的影响

从淮南谢—矿五层煤（Ｃ＿（１３）、Ｂ＿（１１ｂ）、Ｂ＿（１０）、Ｂ＿（４ｂ）和Ａ＿３）中精选出镜煤、壳质暗煤、惰性暗煤及构造煤，采用重量法，分别测定它们的甲烷吸附量，从而研究不同成分组成的煤其甲烷吸附性能。     

从天山乌鲁木齐河源1号冰川变化估计近百年来该地区夏季升温

通过冰川波动历史来揭示气候变化是一种重要的方法。然而，以往有关这一方面的研究大都是一些定性的。文章试图依据冰种变化来定量的研究气候变化，并且通过近百年来天山乌鲁木齐河源１号冰川的变化，揭示出本世纪以来该河源地区夏季气温上升约０．２３￣０．２５℃，同时，对于该冰川不同长度规模时的气候敏感性也进行了讨论。     

金矿脉分形特征及找矿意义研究

各种类型的金矿脉常呈不规则的几何形状产出,对它们用欧几里德方法进行描述和分析,不仅难以精确地说明其几何形态特征,有时甚至无法作出实际测量,因此也就很难掌握其产状变化的准确趋势,给金矿床的定量定位预测造成了困难.分形理论为获得有关隐伏矿床(脉)分布的更为准确的信息提供了有利工具.通过对招远灵山和河东两个典型金矿床矿脉分维数、几何丰度和有效紧密度等研究,讨论了分形理论在紧密结合地质特征条件下,客观准确揭示不规则矿脉变化规律及在找矿预测等方面的应用前景.     

Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.     

Environmental Properties of Minerals and Contaminants Purified by the Mineralogical Method

The investigation of the environmental properties of minerals, i.e., environmental mineralogy, is a branch of science dealing with interactions between natural minerals and spheres of the Earth surface as well as a reflection of global change, prevention of ecological destruction, participation in biomineralogy, and remediation of environmental pollution. Pollutant treatment by natural minerals is based on the natural law and reflects natural self-purification functions in the inorganic world, similar to that of the organic world - a biological treatment. A series of case studies related to natural self-purification, which were mostly completed by our group, are discussed in this paper. In natural cryptomelane there is a larger pseudotetragonal tunnel than that formed by [MnO6] octahedral double chains, with an aperture of 0.462-0.466 nm2, filled with K cations. Cryptomelane might be a real naturally-occurring mineral of the active octahedral molecular sieve (OMS-2). CrⅥ-bearing wastewater can be treate     

Optimizing a layered and laterally constrained 2D inversion of resistivity data using Broyden's update and 1D derivatives

Dense profile-oriented resistivity data allows for 2D and 3D inversions. However, huge amounts of data make it practically impossible to do full 2D or 3D inversions on a routine basis. Therefore, a number of approximations have been suggested over the years to speed up computations. We suggest using a combination of Broyden's update on the Jacobian matrix with derivatives calculated using a 1D formulation on a parameterized 2D model of locally 1D layered models. The approximations bring down the effective number of 2D forward responses to a minimum, which again gives us the ability to invert very large sections. Broyden's update is not as useful with a parameterized problem as is the case with a smooth minimum structure problem that has been the usual application. 1D derivatives, however, seem to be very effective when initiating a full 2D solution with Broyden's update. We compare the different methods using two different kinds of data on two synthetic models and on two field examples. The most effective and reliable optimization combines 1D derivatives with a full 2D solution and Broyden's update. When using Broyden's update the Jacobian matrix needs to be reset every once in a while. We do this whenever the difference in data residual from the previous iteration is less than 5%. This combined inversion method reduces the computation time approximately a factor of 3 without losing model resolution.     

CAPPS1和CAPPS2数值预报模式对比分析

对CAPPS1模式和CAPPS2模式预报广西污染物进行了对比分析。主要对比了其污染扩散原理、气象预报模式、操作系统、运行时间、预报时效及预报效果。分析表明：CAPPS1和CAPPS2模式对各种污染物预报的相关系数均在0．44以上，两种模式预报广西空气污染都是可行的；两种模式均对SO2的预报效果最好，NO2次之，PM10相对最差；CAPPS2模式对各种污染物的预报值与实测值相关系数均比CAPPS1高，其中NO2的相关系数提高幅度最大；CAPPS2模式对NO2和PM10的预报准确率比CAPPS1偏高，而对SO2的预报准确率比CAPPS1偏低；CAPPS2预报首要污染物正确率比CAPPS1高出11个百分点，而预报首要污染物等级正确率则高出9个百分点。     

赣南中侏罗世流纹岩地球化学及成因研究：上地壳成因的的微量元素和Pb-Nd-Sr同位素地球化学制约

江西南部龙南-寻邬地区余田群菖蒲组的流纹岩形成于中侏罗世(164．8．1Ma～174．9Ma)，为双峰式火山岩组合的酸性端元，属弱过铝质(ACNK平均为1．04)钙碱性系列(σ平均为1．90)。稀土元素含量高(平均为278．9μg/g)，轻稀土富集(IMH平均为7．94)，Eu亏损中等(δEu平均为0．41)。微量元素以富集Rb，Ba，Th，U，Zr，Y，Pb，而亏损Sr，Nb为特征。Pb，Nd，Sr同位素组成为：(^206Pb/^204Pb)t=17．89～18．58，(^207Pb/^204Pb)t=15．58～15．70，(^208Pb/^204Pb)t=37．94～38．82；εNd(t)=-7．44～-11．9；ISr=0．71126～0．71228。对赣南流纹岩微量元素采用蛛网图和模糊聚类分析方法进行对比研究的结果及Pb-Nd-Sr同位素相关特征为其上地壳成因提供了地球化学佐证。赣南流纹岩是由进入上地壳内高位岩浆房的石英拉斑玄武岩浆的底侵作用直接使上地壳部分熔融形成的产物。