Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.     

关于国土资源数据共享分类的思考

数据共享分类是制定数据共享政策和数据资源开发利用规划的一项基础性工作。本文 提出国土资源数据共享分类的意义、原则和方法,探讨建立以数据共享分类为核心的 国土资源数据分类体系,以期为全面开展国土资源数据共享分类提供参考。     

InSAR系列讲座4InSAR数据处理及关键算法

作为InSAR系列讲座的第四篇，本文介绍并讨论InSAR数据处理方法和关键算法，并对主要的数据处理流程以数学模型的形式进行了概括。     

三维遥感影像数据库系统的研究与实现

介绍了以3S技术为手段，采用目前较为先进的三层结构体系，使用Dephi开发工具，结合数据库技术、遥感技术，尝试以数据库SQL Server组织、存储、管理海量的中巴资源卫星遥感影像数据和新疆1：10万地形矢量数据，应用OpenGL技术实现海量三维遥感影像数据的三维立体显示浏览，进而完成全疆三维遥感影像库建库和三维显示及漫游．     

电子地图的数据结构与模型

电子地图是集地图表达、数据处理、地图分析为一体的新型地图产品，其数据组织形式直接关系到电子地图的质量与性能。本文对几种数据结构和模型进行了分析、比较，并探讨了它们在电子地图领域的应用前景。     

利用DXF文件进行测量数据辅助处理

DXF文件是AUTOCAD与高级语言程序设计之间的接口文件,在测量工作中,充分利用DXF文件对测量数据进行辅助处理计算,可以达到事半功倍的效果.     

超级计算机上矩阵乘的并行计算与实现

数值预报系统中经常要用到矩阵乘运算。在分布式超级计算机 (如IBM-SP) 上, 矩阵乘的并行计算需要较多的数据移动, 有效的数据传输对矩阵乘的实现至关重要。该文讨论了两种矩阵乘的并行算法, 一种是基于矩阵的列-行划分方式, 一种是基于矩阵的网格划分方式。在IBM-SP计算机上的实验结果表明, 网格划分的矩阵乘并行算法通讯开销更小, 并行效率更高, 其并行加速比较列-行并行算法改善约10 %。     

Wind and Wave Data Analysis for the Aegean Sea - Preliminary Results

In this paper, a statistical analysis on wind and wave buoy measurements and wind and wave model forecasts obtained during a two-year period (1999-2001) is presented with reference to four characteristic near-shore sites of the Aegean Sea. The measurements are a main product of the "POSEIDON" system aiming at the monitoring and forecasting of the state of the Greek seas, operated by the National Centre for Marine Research (NCMR). Although the two-year period is rather short for a thorough analysis of the local wind and wave climate, yet the obtained results, presented herein for the first time, reveal some interesting features of the corresponding wave and wind characteristics. Comparisons between the measurements and the forecast results are also performed at the locations under consideration. It is found that (i) wind speeds obtained from the POSEIDON weather forecasting system are, in general, in agreement with the measurements, except for high wind speeds which are systematically underestimated, (ii) the WAM model can successfully follow the monthly and over year trend of the evolution of wind and wave characteristics, but face significant problems for efficient sea-state forecasting. Finally, the overall pattern of the wind/wave climate for the entire Aegean Sea as obtained from the models is presented by means of the spatial distribution of the mean annual wind and sea-state intensity.     

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

城市地区抗御地震灾害风险评估项目综述

城市地区抗御地震灾害风险评估项目系联合国在上世纪末为减轻地震灾害所实施的规模宏大，影响甚远的国际性研究项目，其宗旨是为了提高社会公众防灾意识，有效地减轻城市地区的地震灾害。这一历时2年的项目在有限的经费支持下，取得了令人瞩目的成绩。结合自贡市开展这个项目的实践。综合介绍和总结了该项目的情况及经验。