甘肃马坞金矿成矿流体特征及地质意义

位于西秦岭岷(县)—礼(县)成矿带西段的马坞金矿床,是近年发现的一个中型卡林型金矿床。矿体产出受NWW向断裂构造控制,其赋矿围岩为中泥盆统的千枚岩与灰岩。矿床流体包裹体研究表明,脉石矿物中主要发育CO2-H2O型和H2O溶液型包裹体;均一温度为135~389℃,盐度为4.4%~15.9%,为中-低温、中-低盐度流体;流体成矿压力为34.6~219.8 MPa,成矿深度为1.3~8.1 km。流体包裹体气相成分以H2O、N2为主,其次为CO2、O2,并含有少量CH4、CO等还原性气体;液相成分中阳离子以Ca2+、Na+为主,阴离子以Cl-和SO42-占主导地位,成矿流体为N2-H2O-Ca2+-Cl-体系。氢氧同位素测试结果表明,成矿流体的δ18O水为5.3‰~10.5‰,δD为-123‰~-93‰,成矿流体主要为热卤水。从流体性质及其演化来看,构造体制的转换使流体稳定体系发生改变与沸腾作用是造成金富集成矿的主要因素。     

Metasomatism and sulfide mobility in lithospheric mantle beneath eastern Australia: Implications for mantle Re–Os chronology

Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.

Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition.     

Eocene tonalite–granodiorite from the Havza (Samsun) area,northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting

ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO₂ (67–68 wt%) and Al₂O₃ (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and La_N/Yb_N (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and Yb_N (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (La_N/Lu_N = 14.2–21.6) with insignificant negative Eu anomalies (Eu_N/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have ⁸⁷Sr/⁸⁶Sr ratios of 0.704767 to 0.704927, ¹⁴³Nd/¹⁴⁴Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ¹⁸O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.     

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

常用锂同位素地质标准物质的多接收器电感耦合等离子体质谱分析研究

锂同位素研究是非传统稳定同位素地球化学研究的前沿,已广泛应用于从地表到地幔的岩石圈及流体等固体地球科学的研究领域。准确测定锂同位素比值是应用该同位素体系的前提。本文报道了国际上7种常用地质标准物质(BHVO-2、JB-2、BCR-2、AGV-2、NKT-1、L-SVEC、IRMM-016)的锂同位素组成数据。分析中采用硝酸-氢氟酸混合酸消解岩石标准样品,通过3根阳离子交换树脂(AG50W-X8,200~400目)填充的聚丙烯交换柱和石英交换柱对锂进行分离富集,利用Neptune型多接收器电感耦合等离子体质谱(MC-ICPMS)测定锂同位素比值,使用标准-样品交叉法(SSB)校正仪器的质量分馏。实验得到这7种常用地质标准物质的锂同位素组成与测试精度(2SD)分别为:δ7LiBHVO-2—L-SVEC=4.7‰±1.0‰(n=53),δ7LiJB-2—L-SVEC=4.9‰±1.0‰(n=20),δ7LiBCR-2—L-SVEC=4.4‰±0.8‰(n=8),δ7LiAGV-2—L-SVEC=6.1‰±0.4‰(n=14),δ7LiNKT-1—L-SVEC=9.8‰±0.2‰(n=3),δ7LiL-SVEC—L-SVEC=-0.3‰±0.3‰(n=10),δ7LiIRMM-016—L-SVEC=0.0‰±0.5‰(n=10),这些数据在误差范围内与国际上已发表的数据一致。Li同位素分析精度可以达到大约0.5‰,长期的分析精度即外部重现性≤±1.0‰,达到了国际同类实验室水平。7种常用地质标准物质的锂同位素组成数据的发表为锂同位素研究提供了统一的标准,使地质样品的锂同位素数据的质量监控成为可能。在基质效应的研究中,使用不同量的IRMM-016配制的标准溶液过柱,深入探讨了样品量对锂同位素测定值的影响,结果表明,在现有测试精度下,只要分析样品的锂含量达到100μg/L,且不超过树脂的承载量,样品的锂同位素组成在误差范围内与真值吻合,样品量的大小不影响锂同位素测定结果的准确性。     

钾稳定同位素研究综述

钾稳定同位素是重要的非传统稳定同位素体系,也是近年来迅速发展的热门研究课题。对钾同位素研究历史和现状进行综述,具体包括以下内容:(1)总结了钾元素的地球化学和宇宙化学性质,包括钾在主要地质储库(地幔、地壳、海洋)中的丰度及其分配,钾在岩浆演化中的不相容大离子亲石性,常见含钾火成岩/沉积岩矿物以及钾在表生过程中的循环,也包括主要行星物质(球粒陨石、非球粒陨石、火星和灶神星陨石以及月球样品)中钾的含量、赋存状态、主要矿物,钾在太阳星云冷凝、行星积聚以及岩浆海过程中的中等挥发性质;(2)介绍了钾同位素的研究历史,从1922年Dempster利用最早的质谱仪测量钾同位素在自然界的丰度,到Taylor和Urey在1938发表的经典的钾同位素分馏实验,再到Humayun和Clayton在1995年发表的钾同位素领域的经典研究,最后到近几年的进展;(3)介绍了对钾的前处理(离子交换柱法)以及钾同位素的主要测量方法,包括早期热电离质谱仪法(TIMS),二次离子质谱仪法(SIMS)和近十几年以来高速发展的多接收电感耦合等离子体质谱仪法(MC-ICP-MS)及其不同的技术路线;(4)介绍了高精度钾同位素比值在低温地球化学和生物地球化学中的应用,包括钾同位素在地表的风化过程中、海水洋壳的反向风化作用中的分馏及其在示踪全球钾元素循环和洋壳俯冲等过程中的应用;(5)介绍了高精度钾同位素比值在高温地球化学中的应用,包括钾同位素在岩浆分异和矿物结晶过程中的分馏;(6)介绍了高精度钾同位素比值在宇宙化学中的应用,包括在太阳星云冷凝、行星凝聚、月球形成大碰撞、岩浆海、火山喷发去气过程中的分馏作用。     

大兴安岭北部塔河花岗杂岩体的地球化学特征及成因

塔河杂岩体位于塔源-喜桂图缝合带北侧的额尔古纳地块东部,是早古生代侵入的花岗杂岩体。该杂岩体的主要岩石类型为正长花岗岩、二长花岗岩,少量碱长花岗岩和花岗闪长岩,辉长岩以包体存在于花岗岩中。岩石成因类型为典型的Ⅰ型后造山侵入体。岩体在野外地质特征、矿物组合、显微结构、化学成分及锆石Hf同位素特征等方面都表现出岩浆混合成因。在早古生代额尔古纳地块与兴安地块拼合后的后造山伸展拉张背景下,地壳和地幔都发生部分熔融,直接起源于亏损地幔的玄武质岩浆侵入到下地壳熔融的花岗质岩浆房,经结晶分异作用,形成了塔河杂岩体不同的岩石类型。花岗岩的εHf(t)为-0.8~+5.6之间,Hf模式年龄在0.9~1.5Ga之间,反映塔河花岗岩的源岩应该是在中-新元古代时期由亏损地幔起源的新生地壳物质。结合额尔古纳地块早古生代和中生代花岗岩锆石Hf同位素资料,我们认为额尔古纳地块在中-新元古代时曾发生过一次重要的地壳增生事件。     

江南造山带西南段宰便辉绿岩年代学、地球化学及其构造意义SCIEI北大核心CSCD

宰便地区位于江南造山带西南段,发育有一系列新元古代镁铁质-超镁铁质火成岩。然而,其成因与构造背景仍存在广泛争议。因此,本文选择江南造山带西南段宰便辉绿岩为研究对象,系统开展岩石学、地球化学、Nd-Hf同位素和锆石U-Pb年代学研究。研究结果表明,辉绿岩具有高Mg^(#)(50~69)、高Al_(2)O_(3)(13.94%~18.63%)、低钾(0.03%~0.33%)、低磷(0.04%~0.28%)特征,显示为低钾拉斑系列岩石特点。同时,岩石整体相对富集Th、U等大离子亲石元素,亏损Nb和Y等高场强元素,Eu具有微弱负异常特征。辉绿岩的Nb/Ta、Zr/Nb比值揭示了母岩浆在岩浆侵位过程中未发生地壳混染。3件样品的锆石U-Pb年龄分别为820.7±3.0Ma、821.1±9.2Ma和823.1±9.5Ma,表明岩浆侵位时代为新元古代早期。锆石ε_(Hf)(t)值介于-13.6~7.7之间,Hf的t_(DM2)值介于1214~2547Ma之间,结合全岩地球化学特征,揭示其原始岩浆可能源于富集地幔,并伴有一定的亏损地幔参与。综合前人和本次研究的地质、地球化学和年代学数据,本文认为江南造山带西南段宰便地区在新元古代早期处于板内构造环境。     

新疆罗布泊盐湖氢氧锶硫同位素地球化学及钾矿成矿物质来源

罗布泊罗北凹地第四系上部盐层中蕴藏丰富的卤水,卤水中则富含钾（ＫＣｌ平均品位为１．４０％）。文章通过对罗布泊卤水氢、氧、锶及硫同位素等分析及与塔里木盆地（河流）、柴达木盆地等地区对比研究,确定了罗布泊富钾卤水源于地表水,可能主要是塔里木盆地南北缘河流水;卤水中的硫钾等物质组分主要来源于南天山、塔里木盆地西北、西南部中新生代石膏钙芒硝石盐矿床或地层及其古代地层卤水。由于第四纪期间塔里木盆地西部抬升。     

High-frequency climatic oscillations during the last deglaciation as revealed by oxygen-isotope records of benthic organisms (Ammersee,southern Germany)

High-resolution oxygen-isotope records of benthic ostracods and molluscs from Ammersee, southern Germany, show high-frequency climatic changes during the last deglaciation and parallel in great detail published faunal and floral variations reconstructed from Norwegian Sea sediments and isotope variations in Greenland ice cores. The marine and the terrestrial records give evidence of a synchronous late glacial climatic development in Greenland, NW- and Mid-Europe. However,¹⁴C-ages of the supraregional climatic events and of two tephra layers in the marine sediments of the northeastern Atlantic Ocean are significantly older than the¹⁴C-ages of the corresponding horizons on land. These differences strongly suggest that major short-term events have affected the exchangeable carbon on earth during the dramatic environmental changes related to the deglaciation and in particular have affected the CO₂-distribution within the ocean and between ocean and atmosphere. Dating methods independent of climatic variations and of the global carbon budget should be given priority to refine the timescales of the marine and atmospheric processes during the last deglaciation.This is the fourth paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr. A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.