渤南洼陷沙四上段非均质性储层“二步建模”方法及应用

渤南洼陷沙四上段油气储层非均质性明显,砂层薄且与泥质间层分布,储层分布规律和空间叠置关系复杂。储层主要受深水盐湖、扇三角洲、滑塌浊积扇、近岸浊积扇、远岸浊积扇五类沉积相控制。利用先进的GridStrat建模软件,采用特殊的"二步建模"处理方法,根据不同沉积相的储层参数分布规律,进行井间插值或随机模拟,建立了沉积相、岩性、孔隙度、渗透率和产能系数模型。沉积相模型显示出扇三角洲及浊积扇是砂体分布的主体,且分布范围广;岩性模型显示出不同岩类的分布受沉积相带、构造位置及不同物源控制。孔、渗模型显示沉积相带和岩性是决定储层孔隙度与渗透率发育程度的主控因素。孔隙度决定了储油气空间的数量,渗透率决定了储层产能系数的大小。产能系数模型显示出产能潜力区为浊积扇和扇三角洲的叠合分布区。研究结论对油田开发部署起到积极指导作用。     

Kinetics and Equilibrium Sorption Studies of 4-Nitrophenol on pyrolyzed and activated oil shale residue

Sorption of the organic pollutant 4-nitrophenol (4-NP) by pyrolyzed and activated Jordanian oil-shale was studied. Pyrolyzed oil shale was prepared using a fluidized bed reactor at 520 °C in the presence of nitrogen. Physical activation was carried out by treating the pyrolyzed oil shale with CO₂ at 830 °C, while chemical activation was achieved by using KOH and ZnCl₂ as impregnating agents. Batch kinetics and isotherm studies were conducted to evaluate the sorption process. Effects of contact time, initial sorbate concentration, sorbent concentration, temperature, pH and inorganic salts (NaCl and KCl) on the sorption process by the different sorbents were considered. Chemically activated oil shale, pretreated with ZnCl₂, gave the highest uptake of 4-NP. The isotherm experimental data fit reasonably well to Langmuir, Freundlich and Redlich-Paterson models. Three kinetic models, namely the Morris-Weber, Lagergren, and Pseudo-Second-Order model (PSOM), were applied to represent the experimental results for both pyrolyzed and ZnCl₂-oil shale sorbents.     

P-T Paths Derived from Garnet Growth Zoning in Danba Domal Metamorphic Terrain, Sichuan Province, West China

Danba (丹巴) domal metamorphic terrain belongs to Songpan (松潘)-Ganze (甘孜) orogenic belt, where typical Barrovian and Buchan metamorphic zones are preserved. The former included chlorite, biotite, garnet, staurolite, kyanite and sillimanite zones, while the latter only developed silimanite+muscovite and sillimanite+K-feldspar zones. Integrated study has been carried on metamorphic reactions of garnet production and consumption, P-T paths and P-T-X-M phase relation and thermal tectonic model for Danba metamorphic zones. Petrological textures in thin sections show that garnet production and consumption in kyanite-sillimanite zone is mainly attributed to ChI+Ms+PI+Q=Grt+Bt+H2O and kyanite=sillimanite respectively. Based on mineral compositions, the geothermobarometry gives an average P, T condition of (4.9±0.3)×108 Pa, 543±30℃ for the first growth stage of the garnet and (5.8±0.3)±108 Pa, 534±29 ℃ for the second stage of garnet growth respectively. Anti-counter clockwise P-T paths were drawn using Gibbs method by NCMnKFMASH system for sample G98686 in the kyanite zone. The P-T-X-M modeling for the first mineral assemblages shows that the prediction is similar to the measured values in gossular, almandine and spessartine but mole fraction of pyrope and Fe/(Fe+Mg) deviated far from the contours; while that for the second mineral assemblages exhibits that the prediction is consistent with the measured value of pyrope, grossular content and Fe/(Fe+Mg) of garnet. A thermal tectonic model that there are at least three structure levels across the thrnst-decollement zones is presented according to the P-T paths, metamorphic grades and deformation styles for the staurolite-kyanite zone of the Barroviau type metamorphism, which will provide some constraints for the evolution of the nappe complex.     

云南羊拉铜矿三维地质建模及储量计算

以云南羊拉铜矿的断层、地层、岩体、矿体为研究对象,在分析研究建模技术方案的基础上,依据收集到的钻孔柱状图、勘探线剖面图、中段地质图和地形地质图,结合野外踏勘与认识,利用Micromine软件建立了研究区的地形、地层、断层以及矿体的三维实体模型,直观展示了区内地表、断层、地层、岩体以及矿体的空间展布以及相互的空间位置关系。运用克里格法对里农矿段的铜矿体进行品位估值,获得了矿体的储量。     

莲沱砂岩——南华大冰期前气候转冷的沉积记录

湖北宜昌地区出露的莲沱组中上部细屑岩的化学蚀变指数(CLA)介于60～70之间,表明是在寒冷干燥的气候条件下沉积的。比较莲沱组与板溪群中下部沉积岩的主化学成分和 CIA 值表明,板溪群源区遭受过强烈的化学风化,相应的古气候是温暖湿润的,而莲沱组源区化学风化弱,可见两者形成时的古气候环境明显不同。根据 CIA 值推测,地层层序上莲沱组位于板溪群的中上部,莲沱砂岩的 CIA 研究表明南华大冰期前全球气候已经从温暖湿润转变为寒冷干燥,CIA 值继续降低预示着全球性的冰期到表,不久就发生了"雪球地球"事件。     

陕西省潼关县碾头岔含金石墨矿工艺矿物学研究

工艺矿物学系统研究表明：碾头岔含金石墨矿床的矿石中除石墨外,可综合利用的有用元素还有金、铜等。金矿物颗粒较细,主要以独立矿物形式赋存于载体矿物黄铜矿、黄铁矿及石墨中。黄铜矿是主要的铜矿物,其次有蓝辉铜矿。石墨呈独立矿物存在,片大且较平直,属于大鳞片石墨,矿石中总碳仅有６５％左右以石墨碳形态存在。上述３种有用元素均可通过合理磨矿,选择适宜的选矿条件得到金精矿、铜精矿和石墨精矿。然而由于石墨精矿中杂质较多且颗粒细小,主要为极细的片状硅酸盐,要得到高品级石墨,用机械选矿办法是无能为力的,需要对精矿进一步加工处理方可奏效。     

Risk assessment of groundwater pollution using sensitivity analysis and a worst-case scenario analysis

This paper illustrates how sensitivity analysis and a worst-case scenario analysis can be useful tools in risk assessment of groundwater pollution. The approach is applied to a study area in Hungary with several known groundwater pollution sources and nearby drinking water production wells. The main concern is whether the contamination sources threaten the drinking water wells of the area. A groundwater flow and transport model is set up to answer this question. Due to limited data availability, the results of this model are associated with large uncertainty. Sensitivity analysis and a worst-case scenario analysis are applied to estimate this uncertainty and build confidence in the model results.     

塔里木盆地西北缘露头区奥陶系古溶洞地质建模

塔里木盆地西北缘奥陶系大型古溶洞广泛出露,为古溶洞露头地质建模提供了优越的条件。综合野外资料和Google Earth影像分析,将大型古溶洞以形态结构特征为依据划分成管道—厅堂连通型溶洞、单一管道孤立型溶洞、流线型溶洞3种类型;以存在形式划分成单一溶洞和溶洞群。其中,管道—厅堂连通型溶洞以潜流带型为主,在平面上沿主方位通过岩溶管道连接厅堂分布,厅堂大小不等,在50～50000m³之间变化;单一管道孤立型溶洞以渗流带型为主,平面上呈现单一管道线条状;流线型溶洞分布在潜流带中,从剖面上看呈近圆形、椭圆形和豆荚状等多种形状,包括顺层和斜交地层2种类型。结合各露头剖面中构造、地层条件及发育溶洞类型,明确管道—厅堂联通型溶洞受不整合面控制,分布在三间房、五道班和西克尔剖面中;单一管道孤立型溶洞受断裂系统控制,分布在一间房和硫磺沟剖面中;流线型溶洞主要分布在西克尔剖面,沿溶蚀沟道两侧分布;多种不同因素的耦合控制了溶洞群的分布。以此建立了综合大型古溶洞特征及其控制因素的古溶洞发育概念地质模型,以溶洞群为主要体积计算单元,通过与塔北奥陶系串珠进行体积对比,明确了地质模型的油气勘探意义。     

流变学:构造地质学和地球动力学的支柱学科

地球是一动态系统,其各层圈的构造运动归根到底就是多矿物复合岩石在各种物理条件(例如,温度、围压、差应力、应变速率、应变方式等)下和化学环境(例如,氧逸度和水含量)中的形变。流变学作为研究岩石力学性质和变形行为的科学,现已成为地球动力学和构造地质学的支柱学科。本文对国际上近年来岩石流变学的最新进展做些扼要的介绍,呼吁中国固体地学界加强流变学的研究,做出经得起时间淘洗、实践检验的原创性成果来,使中国的构造地质学研究迈进国际先进的行列。     

基于Biot-Gassmann 方程的流体替换技术在番禺天然气区PY 气田的应用

珠江口盆地番禺天然气区PY 气田位于坡折带上,特殊的沉积环境导致该气田已钻探的各井 T50 储层泊松比关系异常,含油气性特征非常复杂。为更好的判断储层的含油气性,利用Biot-Gassmann 方程对坡折带储层的流体性质进行了替换,考查不同流体性质下储层的含油气响应特征。研究结果表明: Biot-Gassmann 方程能有效的用于坡折带储层的流体替换研究; 坡折带T50 储层含水和含气时的AVO 响应特征相近,但两者响应的幅值不同,含水砂岩的幅值更小。