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11.
Victor L. Vinograd Bjoern Winkler Daniel J. Wilson Andrew Putnis Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544
Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca3Fe2Ge3O12 and Ca4Ge4O12. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca2+ and Ge4+ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite. 相似文献
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We investigated the upper mantle anelastic structure beneath the northern Philippine Sea region, including the Izu-Bonin subduction zone and the Shikoku Basin. We used regional waveform data from 69 events in the Pacific and the Philippine Sea slabs, recorded on F-net and J-array network broadband stations in western Japan. Using the S–P phase pair method, we obtained differential attenuation factors, δt*, which represent the relative whole path Q. We conducted a tomographic inversion using 978 δt* values to invert for a fine-scale (50–100 km) three-dimensional anelastic structure.
The results shows two high-Q regions (QP>1000) which are consistent with the locations of the Pacific and the Philippine Sea slabs. Also there is a low-Q (QP110) area extending to the deeper parts (350–400 km) of the model just beneath the old spreading center and the Kinan Seamount Chain in the Shikoku Basin. A small depth dependence of the laterally averaged QP was found, with values of 266 (0–250 km), 301 (250–400 km), and 413 (400–500 km). 相似文献
15.
Practical VTI approximations: a systematic anatomy 总被引:3,自引:0,他引:3
Transverse isotropy (TI) with a vertical symmetry axis (VTI) often provides an appropriate earth model for prestack imaging of steep-dip reflection seismic data. Exact P-wave and SV-wave phase velocities in VTI media are described by complicated equations requiring four independent parameters. Estimating appropriate multiparameter earth models can be difficult and time-consuming, so it is often useful to replace the exact VTI equations with simpler approximations requiring fewer parameters. The accuracy limits of different previously published VTI approximations are not always clear, nor is it always obvious how these different approximations relate to each other. Here I present a systematic framework for deriving a variety of useful VTI approximations. I develop first a sequence of well-defined approximations to the exact P-wave and SV-wave phase velocities. In doing so, I show how the useful but physically questionable heuristic of setting shear velocities identically to zero can be replaced with a more precise and quantifiable approximation. The key here to deriving accurate approximations is to replace the stiffness a13 with an appropriate factorization in terms of velocity parameters. Two different specific parameter choices lead to the P-wave approximations of Alkhalifah (Geophysics 63 (1998) 623) and Schoenberg and de Hoop (Geophysics 65 (2000) 919), but there are actually an infinite number of reasonable parametrizations possible. Further approximations then lead to a variety of other useful phase velocity expressions, including those of Thomsen (Geophysics 51 (1986) 1954), Dellinger et al. (Journal of Seismic Exploration 2 (1993) 23), Harlan (Stanford Exploration Project Report 89 (1995) 145), and Stopin (Stopin, A., 2001. Comparison of v(θ) equations in TI medium. 9th International Workshop on Seismic Anisotropy). Each P-wave phase velocity approximation derived this way can be paired naturally with a corresponding SV-wave approximation. Each P-wave or SV-wave phase velocity approximation can then be converted into an equivalent dispersion relation in terms of horizontal and vertical slownesses. A simple heuristic substitution also allows each phase velocity approximation to be converted into an explicit group velocity approximation. From these, in turn, travel time or moveout approximations can also be derived. The group velocity and travel time approximations derived this way include ones previously used by Byun et al. (Geophysics 54 (1989) 1564), Dellinger et al. (Journal of Seismic Exploration 2 (1993) 23), Tsvankin and Thomsen (Geophysics 59 (1994) 1290), Harlan (89 (1995) 145), and Zhang and Uren (Zhang, F. and Uren, N., 2001. Approximate explicit ray velocity functions and travel times for P-waves in TI media. 71st Annual International Meeting, Society of Exploration Geophysicists, Expanded Abstracts, 106–109). 相似文献
16.
E. J. Palin M. T. Dove S. A. T. Redfern C. I. Saniz-Díaz W. T. Lee 《Physics and Chemistry of Minerals》2003,30(5):293-304
As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques
have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K2
[6](Al3Mg)[4](Si7Al)O20(OH)4. Values of the atomic exchange interaction parameters J
n
used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied
and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral
sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst
we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets
alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the
T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range
order was observed.
Received: 8 August 2002 / Accepted: 14 February 2003
Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed
on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility. 相似文献
17.
Philippe Machetel 《Comptes Rendus Geoscience》2003,335(1):91-97
The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone. 相似文献
18.
从系统辨识的原理出发,给出了确定精密重力仪相位滞后的一种方法,即记录精密重力仪在阶跃信号作用下的输出数据,利用这些数据对仪器的传递函数进行辨识,从而确定重力仪对各潮汐波产生的相位滞后角度.用这种方法对ET-21地潮重力仪进行了相位滞后的确定,并给出这台仪器对15个主要潮汐波的相位滞后角度. 相似文献
19.
X. Lee H.H. Neumann G. Hartog R.E. Mickle J.D. Fuentes T.A. Black P.C. Yang P.D. Blanken 《Boundary-Layer Meteorology》1997,84(3):383-398
In this paper we report the results of the analysis of two 60-min wave events that occurred in a boreal aspen forest during the 1994 BOREAS (Boreal Ecosystems-Atmosphere Study) field experiment. High frequency wind and temperature data were provided by three 3-D sonic anemometer/thermometers and fourteen fine-wire thermocouples positioned within and above the forest. Wave phase speeds, estimated from information revealed by spectral analysis and linear plane wave equations, are 2.2 and 1.3 m s-1 for the two events. The wavelengths are 130 m and 65 m respectively and are much larger than the vertical wave displacements. There is strong evidence from the present analysis and from the literature supporting our postulate that these waves are generated by shear instability. We propose that wind shear near the top of the stand is often large enough to reduce the gradient Richardson number below the critical value of 0.25 and thus is able to trigger the instability. When external conditions are favorable, the instability will grow into waves. 相似文献
20.