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101.
102.
S. Madronich D. R. Hastie B. A. Ridley H. I. Schiff 《Journal of Atmospheric Chemistry》1984,1(2):151-157
The photodissociation coefficient, J
NO2 of NO2 in the atmosphere was calculated at 235 and 298 K using the measured temperature dependences of the absorption cross-sections and quantum yields. These calculations gave a ratio J
NO2(298 K)/J
NO2(235 K)=1.155±0.010 which is only weakly dependent on altitude, surface albedo and solar zenith angle. 相似文献
103.
The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause. 相似文献
104.
房山花岗岩岩体氧氢碳的同位素研究 总被引:1,自引:0,他引:1
测定了房山花岗岩侵入体的岩石、共生矿物和气液包体的氧、氢、碳的同位素组成。共生石英-黑云母和石英-全岩的δ~(18)O数据表明,房山花岗岩侵入体保存了氧同位素平衡,氧同位素温度在450—580℃之间。大多数共生黑云母-角闪石δD值的相关性基本上符合Suzuoki-Epstein关系式,可以认为房山侵入体也保存了氢同位素平衡,推算得到的岩浆流体的δD值在-70—-30之间。气液包体中CO_2的δ(13)C为-4—-8,属于一种深源碳,可以利用地下水参加岩浆后期演化的假定来解释黑云母二长闪长岩氢、碳同位素异常 相似文献
105.
Mean growing season soil PCO2 data were obtained for 19 regions of the world in nine countries. Bivariate and multiple linear regression analysis with soil log(PCO2) as the dependent variable and TEMP, PRECIP, log(AET), and log(PET) as the four climatic independent variables demonstrated that AET was the best independent predictor of soil PCO2. An improved soil PCO2-AET model was developed by assuming (1) that as AET approaches zero, soil PCO2 approaches the atmospheric value and (2) that there is an upper limit to soil PCO2 at very high AET. This model has the form log(PCO2) = ?3·47 + 2·09 (1 ?e?0·0172 AET) where AET is in mm. It explains 67 per cent of the initial variation in the soil PCO2 data, predicts a soil log(PCO2) of ? 3·47 at AET = 0, and an upper limit of 3·5 per cent (log(PCO2) = ? 1·45) for mean growing season soil PCO2 at AET values of 2000 mm and above. The results of this study suggest that soil PCO2 levels in tropical areas are, on average, higher than those in temperate, alpine, and arctic regions. 相似文献
106.
Cleaning with hierarchy of CO2‐based solvents is advantageous from an environmental point of view because CO2 is non‐flammable, virtually inert, and abundant. After cleaning, the only waste stuffs generated are the contaminants that are removed from the cleaned parts. The technology is especially well suited for precision cleaning applications in which parts have intricate geometries or for applications in which parts are sensitive to water or high temperature. This review will first introduce aqueous cleaning concepts and mechanism, which is helpful to understand how to design cleaning systems using high pressure CO2. Recent microelectronic processes for cleaning and rising of circuit wafers using CO2‐based solvents are the main focus of the review. Additional cleaning topics include dry cleaning, separation of dyestuffs, and extraction of contaminations from soils and regeneration of catalysts. 相似文献
107.
Accurate modeling of storage of carbon dioxide (CO2) in heterogeneous aquifers requires experiments of the capillary pressure as function of temperature and pressure. We present a method with which static drainage and imbibition capillary pressures can be measured continuously as a function of saturation at various temperature (T) and pressure (P) conditions. The measurements are carried out at (T, P) conditions of practical interest. Static conditions can be assumed as small injection rates are applied. The capillary pressure curves are obtained for the unconsolidated sand–distilled water–CO2 system. The experimental results show a decrease of drainage and imbibition capillary pressure for increasing CO2 pressures and pronounced dissolution rate effects for gaseous CO2. Significant capillary pressure fluctuations and negative values during imbibition are observed at near critical conditions. The measurement procedure is validated by a numerical model that simulates the experiments. 相似文献
108.
西藏地热气体的地球化学特征及其地质意义 总被引:9,自引:3,他引:9
西藏水热活动是青苦恼高原碰撞造山过程的产物,其成因类型、物质来源和时空分布与青藏高原的隆升过程密切相关,地热流体(气、液相)中携带有中上地壳乃至地幔物质的深部信息。西藏地热流体可以区分出CO2型和N2型两类气体,其中绝大多数的地热气体样品属于CO2型气体,而典型的N2型气体则较少。前者具有岩浆热源和深循环两种成因类型,后者都是深循环成因。西藏气体样品中的He含量变化范围非常宽,最高的可达到1.5%。在门士热泉,首次检测到地幔He组分,这说明西藏地壳深处有地幔物质侵位。根据He同位素组成推断,羊八井、谷露等处的地壳熔融体中约有3%的地幔组分。西藏地热气体中的N2和Ar组分主要是大气成因,CO2组分大多以海相碳酸盐岩成因为主,混有少量有机沉积物成因CO2。当Log(H2/Ar)处于-0.8-0.3的区间时,H2/Ar地热温度计可以良好地指示热储层的温度范围。实际调查表明:西藏水热活动区大多分布在斑公错-怒江链合带以南地区,高温水热活动区主要出现在雅鲁藏布缝合带和那曲-羊八井-亚东活动构造带沿线。 相似文献
109.
燃煤烟气中SO2治理方法综述 总被引:2,自引:0,他引:2
对燃煤烟气中SO2的脱除方法进行综述和分析。 相似文献
110.
利用非金属矿制备白炭黑现状及发展前景 总被引:8,自引:0,他引:8
简术了白炭黑的用途和制备方法,综述了利用非金属矿制备白炭黑的方法和技术现状,对充分利用非金属矿制备白炭黑提供思路并展望其发展前景。 相似文献