磁暴对辽宁地区核旋总强度通化值的影响及提高通化精度的方法

通过不同K指数的磁暴对辽宁省磁测点总强度通化值的影响,发现在8个地磁测点,不但干扰幅度不一洋,而且以沈阳台为基准点做的通化值不能完全消除外空场的干扰。磁静日通化值一般不超过1.6nT,而磁暴日通化值可达4.0nT左右。不论磁静日或磁暴日,标准偏差随通化台距离增加而增加,通过加权和五天磁静日方法可提高通化值的精度。     

Secular evolution of the vertical column abundances of CHCIF2 (HCFC-22) in the Earth's atmosphere inferred from ground-based IR solar observations at the Jungfraujoch and at Kitt Peak,and comparison with model calculations

Series of high-resolution infrared solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, between 06/1986 and 11/1992, and at Kitt Peak National Observatory, Tucson, Arizona (U.S.A.), from 12/1980 to 04/1992, have been analyzed to provide a comprehensive ensemble of vertical column abundances of CHCIF₂ (HCFC-22; Freon-22) above the European and the North American continents. The columns were derived from nonlinear least-squares curve fittings between synthetic spectra and the observations containing the unresolved 2v ₆ Q-branch absorption of CHCIF₂ at 829.05 cm^–1. The changes versus time observed in these columns were modeled assuming both an exponential and a linear increase with time. The exponential rates of increase at one-sigma uncertainties were found equal to (7.0±0.35)%/yr for the Junfraujoch data and (7.0±0.23)%/yr for the Kitt Peak data. The exponential trend of 7.0%/yr found at both stations widely separated in location can be considered as representative of the global increase of the CHCIF₂ burden in the Earth's atmosphere during the period 1980 to 1992. When assuming two realistic vertical volume mixing ratio profiles for CHCIF₂ in the troposphere, one quasi constant and the other decreasing by about 13% from the ground to the tropopause, the concentrations for mid-1990 were found to lie between 97 and 111 pptv (parts per trillion by volume) at the 3.58 km altitude of the Jungfraujoch and between 97 and 103 pptv at Kitt Peak, 2.09 km above sea level. Corresponding values derived from calculations using a high vertical resolution-2D model and recently compiled HCFC-22 releases to the atmosphere, were equal to 107 and 105 pptv, respectively, in excellent agreement with the measurements. The model calculated lifetime of CHCIF₂ was found equal to 15.6 years. The present results are compared critically with similar data found in the literature. On average, the concentrations found here are lower by 15–20% than those derived from in situ investigations; this difference cannot be explained by the absolute uncertainty of ±11% assigned presently to the infrared remote measurements.     

黄河矿晶体结构的重新测定及空间群对称的讨论

黄河矿 BaCe(CO₃)₂F(a=0.5072(1)nm,c=3.846(1)nm;V=856.8×10^-3nm³;Z=6)晶体结构的重新测定,采用中心对称空间群 R3m-D_3d⁵,基于337个可观察的单晶 X 射线数据(I>2σ₁)和30个可变参数,R=0.031。原子坐标和均方根振幅(据各向异性位移参数计算,O.013-0.025nm)表明,没有必要降低对称性,即没有必要采用相应的非中心对称空间群或其它次群。黄河矿的结构中,原子形成似层状排列,且垂直于 c 轴;碳酸根通过 Ba 与 Ce 的联结形成三维结构。C(1)O₃,和 C(2)O₃,中的 C 原子偏离三个氧组成的平面,其偏离的距离分别为0.0066(15)nm 和 0.0029(15)nm。     

Grain boundary migration of water and carbon dioxide during uplift of garnet-zone Alpine Schist, New Zealand

Abstract Deformed quartz veins in garnet-zone schist adjacent to the active Alpine Fault, New Zealand, have fluid inclusions trapped along quartz grain boundaries. Textures suggest that the inclusions formed in their present shapes during annealing of the deformed veins. Many of the inclusions are empty, but some contain carbon dioxide with densities that range from 0.16 to 0.80 g cm⁻³. No water, nitrogen or methane was detected. The inclusions are considerably more CO₂-rich than either the primary metamorphic fluid (<5% CO₂) or fluids trapped in fracture-related situations in the same, or related, rocks (<50% CO₂). Enrichment of CO₂ is inferred to have resulted from selective migration (wicking) of saline water from the inclusions along water-wet grain boundaries after cooling-induced immiscibility of a water-CO₂ mixture. Inclusion volumes changed after loss of water. Non-wetting CO₂ remained trapped in the inclusions until further percolation progressively removed CO₂ in solution. This mechanism of fluid migration dominated in ductile quartz-rich rocks near, but below, the brittle-ductile transition. At deeper levels, hydraulic fracturing is also an important mechanism for fluid migration, whereas at shallower levels advection through open fractures dominates the fluid flow regime.     

Atmospheric electrode effect: Approximate theory and wintertime observations

Summary The steady-state equations of the atmospheric electrode effect, i.e. the depletion of negative ions near the ground, are solved analytically in an approximate way. The presence of monodisperse aerosol is included. The method is based on the assumption that the positive ion density remains nearly, although not strictly, constant with height. The results show explicitly the effect of various parameters on the electrode layer. In particular, the height is directly proportional to the current density, and it depends on aerosol density only through the influence of the aerosol on the current density. The results are used to give a tentative explanation, in terms of the electrode effect, to an observed wintertime difference of the two polar conductivities.     

陆面微波比辐射率的卫星观测研究进展

复杂多变的陆地表微波比辐射率,造成陆面上星载微波观测反演大气参数较为困难,也使得许多卫星微波资料不易同化应用到数值模式,因此迫切需要提供准确可靠的陆面微波地表比辐射率信息.随着卫星观测技术的迅速发展,利用丰富的星载被动微波观测直接反演陆面微波比辐射率成为一种主要手段.国外针对星载微波成像仪和微波垂直探测器开展较为系统的陆面微波比辐射率研究,建立不同类型的地表比辐射率反演方法,开发地表比辐射率参数化方法并应用于辐射资料同化.对于卫星观测反演陆面微波比辐射率存在的问题,开展了评估分析和方法订正.国内利用卫星观测也开展了一些陆面微波比辐射率研究工作,尚需要系统、综合的提炼.对于地表特征复杂的中国地区,还需要评估认识不同陆面微波比辐射率反演方法在我国适用情况,需要增强陆面微波比辐射率数据质量的认识以及业务应用.     

Mineralogy of Asteroid 1459 Magnya and implications for its origin

Detailed near-infrared spectral observations of Asteroid 1459 Magnya reveal an asteroid that is primarily composed of pyroxene and plagioclase feldspar, confirming earlier suggestions that Magnya has a basaltic composition. The average Magnya spectrum for March 23, 2002 has a Band I center of 0.926 μm and a Band II center of 1.938 μm. Observations over  hours show little variation in band center positions. The feldspar-to-pyroxene ratio is ∼0.6 on Magnya's surface. Comparing Magnya with the spectral parameters from 4 Vesta shows discordant pyroxene chemistries; Magnya's pyroxenes contain ∼10 mol% less Fs than Vesta's pyroxenes. This suggests that Magnya originated from a parent body other than 4 Vesta and that its progenitor formed in a more chemically reduced region of the solar nebula within the asteroid belt.     

三江平原不同土地利用方式下湿地土壤CO2通量研究

利用暗箱-气相色谱法,同步测量了三江平原几种主要生态类型湿地土壤原始的小叶章草甸白浆土、毛果苔草泥炭沼泽土、已垦旱作草甸白浆土和人工水田草甸白浆土,进行CO2排放通量的对比研究.结果表明不同土地利用方式下,旱作草甸白浆土土壤CO2排放通量最大,平均值为775.38mg/(m2@h);小叶章草甸白浆土土壤次之,平均值为439.02mg/(m2@h);人工水稻田草甸白浆土土壤CO2通量最小,平均值为128.96mg/(m2@h);毛果苔草泥炭沼泽土土壤CO2排放通量介于小叶章草甸白浆土土壤和水稻田草甸白浆土土壤之间,平均值为247.08mg/(m2@h).湿地开垦为旱田,使湿地"碳汇"功能减弱或丧失,变成"碳源";湿地开垦为水田,是比较合理的湿地农业利用方式.     

全国农业气象资料数据模式的研制

在分析我国农业气象观测资料现状与特点的基础上，提出了制定“全国农业气象资料数据模式”必须遵循的基本原则，即以1993年版的《农业气象观测规范》为依据、以现行“农业气象观测记录年报表”的内容为基础、符合气象行业标准编写要求、具有延续性与可扩展性、面向现代化数据管理和应用服务等，对数据模式的结构和主要技术特点也进行了比较详细的论述。数据模式的研制将有助于现存的农业气象报表资料的数字化以及今后农业气象观测数据的采集、传输和处理自动化的实现。