巢湖南淝河口黑水团区流速和溶解氧与Fe2+、S2-浓度的空间关联性

黑臭现象在我国东部地区浅水湖泊频繁发生,已经严重影响环湖地区的社会经济发展.厌氧环境和高浓度Fe~(2+)、S~(2-)是引起黑臭现象的必要条件.本文解析巢湖南淝河口区黑臭水团范围内Fe~(2+)、S~(2-)与DO、流速的分布特性;基于空间计量模型重点探讨了流速、DO和Fe~(2+)、S~(2-)分布的空间关联性.结果发现,水体流动在黑臭水团中主要有两个作用:使Fe~(2+)、S~(2-)和DO彼此产生空间相关性以及通过分散作用改变局部Fe~(2+)、S~(2-)浓度分布;同时流速通过增强复氧间接影响Fe~(2+)及S~(2-)总体浓度的作用较小.流速与Fe~(2+)、S~(2-)之间均满足线性空间滞后模型;而线性回归模型中流速对Fe~(2+)的影响低估了约7%,对S~(2-)的影响则低估了12%.     

湖泛水体沉积物-水界面Fe2+/ΣS2-迁移特征及其意义

湖泊水底Fe~(2+)和ΣS~(2-)浓度的快速增加是湖泛暴发最早发生于沉积物-水界面的主要前提,缺氧环境下水底扩散层附近Fe~(2+)和ΣS~(2-)的迁移是其在沉积物-水界面处稳定积累的重要原因.以蓝藻聚积水体沉积物-水界面为研究对象,应用湖泊过程模拟装置及间隙水被动采样等技术,重点研究了间隙水和底层上覆水中Fe~(2+)和ΣS~(2-)的垂向分布特征,并定量估算了二者的扩散通量及迁移方向.结果表明:湖泛样品水体沉积物-水界面处于典型的还原性环境,表层沉积物间隙水中Fe~(2+)和ΣS~(2-)浓度显著高于对照样品,二者在表层沉积物中积累趋势明显.湖泛水体沉积物-水界面处Fe~(2+)释放通量较高,表现出较强烈的自沉积物向上覆水方向的释放能力;而湖泛样品ΣS~(2-)在沉积物-水界面处释放通量为负,迁移方向为自上覆水向沉积物扩散.Fe~(2+)和ΣS~(2-)在湖泛水体沉积物-水界面处不同的迁移特征证明:缺氧/厌氧条件下,湖泊水体表层沉积物间隙水中高浓度Fe~(2+)向上覆水的扩散为湖泛致黑物质的形成提供了重要的物质基础;底层上覆水及界面水中SO~(2-)4在表层沉积物中被还原,为终端还原产物ΣS~(2-)为湖泛致黑物质的形成提供了另一重要物质来源.     

Component thermalization time-scale estimate for the advection dominated accretion flow around Sgr A

We report here on a calculation of thermalization time-scale of the two temperature advection dominated accretion flow (ADAF) model. It is established that time required to equalize the electron and ion temperatures via electron-ion collisions in the ADAF with plausible physical parameters greatly exceeds the accretion time, which corroborates validity one of the crucial assumptions of the ADAF model, namely the existence of a hot two temperature plasma. This work is motivated by the recent success of the ADAF model [Nature 394 (1998) 651; MNRAS 304 (1999) 501] in explaining the emitted spectrum of Sgr A*, and it is complementary to the similar analysis of Mahadevan and Quataert [ApJ 490 (1997) 605].     

北方黑云杉林冠内空气CO2浓度及其上方通量模拟

考虑植物阴叶和阳叶对环境的反应、植物叶片丛聚特性以及叶片氮素水平的垂直差异,建立了黑云杉林与大气之间物质输送和能量交换的一维完全多层模式.模式中对阳叶和阴叶的叶面积指数借用Chen J M等提出的方法,并经过修改以适用于多层模拟.叶水平的光合作用c运用Farq uhar方程并与CO2传导方程联列获得.模式验证的资料取自BOREAS(Boreal Ecosystem-fAtmosphere Study)研究计划中加拿大Saskatchewan的南试验区,属于温带气候.通过对冠.层上方的显热、感热和CO2通量、以及植物光合作用、蒸腾作用和气孔传导等生理作用t过程的实测值进行了计算结果的验证,结果表明计算的显热通量比实测值偏低,潜热通量则略高于实测值,而CO2通量只有在较高水平时偏高,3个通量的计算值与实测值比较接近,R 2分别为0.71,0.78和0.65,取得了较好的效果.气孔导度、光合作用和蒸腾作用的模拟结果表明,三者的实测与模拟值之间的R 2分别达到0.57,0.69和0.66,均通过0.01显著度检验,且无显著的系统偏差.因此,可以认为在多层模拟中充分考虑叶片不同受光状况,不同氮素水平以及叶片丛聚特性的影响有助于更好地研究植被与大气的交换过程.     

塔里木盆地西北缘下寒武统黑色岩系差异性成岩演化及其影响因素

尽管泥页岩在埋藏过程中经历的复杂成岩改造会显著影响页岩油气储层发育潜力,但对其成岩作用,特别是泥页岩中成岩矿物的类型、成岩演化及其影响因素、成岩矿物元素在低孔低渗孔隙系统中的迁移等问题的认识仍很薄弱,因而制约了对泥页岩储层的深入认识。为此,本文以塔里木盆地西北缘下寒武统玉尔吐斯组发育的两套黑色岩系为例,在沉积环境认识的基础上,通过矿物组分、黏土矿物组合、有机碳含量及有机质成熟度等测定分析,着重研究了黑色岩系自生矿物的分布及在成岩演化阶段的变化特征,阐述了成岩变化的时空分布及其影响因素。研究结果表明：（1）在浅水缓坡台地环境下,玉尔吐斯组受两个较为完整的海进-海退沉积旋回控制而形成的两套黑色岩系主要经历了早成岩阶段和中成岩阶段;（2）受沉积环境和热液作用的影响,这两套黑色岩系在石英、重晶石、碳酸盐胶结物和黏土矿物等自生矿物的组合、分布及形成顺序上存在显著的差异,呈现出差异性成岩演化的特点;（3）伊利石、伊蒙混层、绿泥石、白云石、石英胶结等中成岩阶段成岩产物的广泛分布,反映出在成岩过程中特别是中成岩阶段低孔低渗的泥页岩仍存在一定程度的内部和外部来源的矿物元素迁移。本次研究对深入认识塔里木西北缘下寒武统黑色岩系成岩机制,以及分析页岩储层发育特征提供了重要的依据。     

Offset dependence of overburden time-shifts from ultrasonic data

Depletion or injection into a reservoir implies stress changes and strains in the reservoir and its surroundings. This may lead to measurable time-shifts for seismic waves propagating in the subsurface. To better understand the offset dependence of time-shifts in the overburden, we have systematically quantified the time-shifts of three different overburden shales in controlled laboratory tests. These experiments may be viewed as an analogue to the time-shifts recorded from seismic field surveys. For a range of different stress paths, defined as the ratio between the horizontal and the vertical stress changes, the changes of the P-wave velocities in different directions were measured such that the offset dependence of time-shifts for different stress paths could be studied. The time-shifts are stress path dependent, which is particularly pronounced at large offsets. For all stress paths, the time-shifts exhibit a linearly decreasing trend with increasing offset, that is, a negative offset gradient. At zero offset, for which the ray path is normal to the bedding, the time-shifts are similar for all investigated stress paths. The isotropic stress path is associated with the smallest offset gradient of the time-shifts. In contrast, the constant-mean-stress path shows the largest gradient with a flip in the polarity of the time-shifts for the largest offsets. The separate contributions from the strain and velocity changes to the time-shifts were also quantified. The time-shifts for the isotropic stress path are dominated by the contribution from velocity changes at all offsets. In contrast, the strain contributes significantly to the time-shifts at small offsets for the constant-mean-stress path. This shows that the offset dependence in pre-stack seismic data may be a key to understand the changes of subsurface stresses, pore pressure and strain upon depletion or injection. To utilize this knowledge from laboratory experiments, calibrated rock physics models and correlations are needed to constrain the seismic time-shifts and to obtain an adequately updated geological model reflecting the true anisotropic nature of the subsurface. This may have important implications for improved recovery and safety, particularly in mature fields.     

Some aspects of four-dimensional black hole solutions in gauss-bonnet extended string gravity

An internal singularity of a string four-dimensional black hole with second order curvature corrections is investigated. A restriction to a minimal size of a neutral black hole is obtained in the frame of the model considered. Vacuum polarization of the surrounding space-time caused by this minimal-size black hole is also discussed.     

CME和冕洞边缘结构的可能关系

本文分析了１９８０ 、１９８４ 和１９８９ 年ＳＭＭ 卫星观测到的１４０ 次日冕物质抛射（ＣＭＥ） 事件在时空分布上与“冕洞边缘结构”、耀斑爆发和爆发日珥等事件的相关关系结果表明, ＣＭＥ 事件与日冕边缘结构的关系最密切此外, ＣＭＥ与赤道冕洞具有同步的长期演化关系由此认为, 冕洞边缘结构对ＣＭＥ的可能贡献是不可忽视的     

Sulfur and iron speciation in surface sediments along the northwestern margin of the Black Sea

The speciation of sedimentary sulfur (pyrite, acid volatile sulfides (AVS), S⁰, H₂S, and sulfate) was analyzed in surface sediments recovered at different water depths from the northwestern margin of the Black Sea. Additionally, dissolved and dithionite-extractable iron were quantified, and the sulfur isotope ratios in pyrite were measured. Sulfur and iron cycling in surface sediments of the northwestern part of the Black Sea is largely influenced by (1) organic matter supply to the sediment, (2) availability of reactive iron compounds and (3) oxygen concentrations in the bottom waters. Biologically active, accumulating sediments just in front of the river deltas were characterized by high AVS contents and a fast depletion of sulfate concentration with depth, most likely due to high sulfate reduction rates (SRR). The δ³⁴S values of pyrite in these sediments were relatively heavy (−8‰ to −21‰ vs. V-CDT). On the central shelf, where benthic mineralization rates are lower, re-oxidation processes may become more important and result in pyrite extremely depleted in δ³⁴S (−39‰ to −46‰ vs. V-CDT). A high variability in δ³⁴S values of pyrite in sediments from the shelf-edge (−6‰ to −46‰ vs. V-CDT) reflects characteristic fluctuations in the oxygen concentrations of bottom waters or varying sediment accumulation rates. During periods of oxic conditions or low sediment accumulation rates, re-oxidation processes became important resulting in low AVS concentrations and light δ³⁴S values. Anoxic conditions in the bottom waters overlying shelf-edge sediments or periods of high accumulation rates are reflected in enhanced AVS contents and heavier sulfur isotope values. The sulfur and iron contents and the light and uniform pyrite isotopic composition (−37‰ to −39‰ vs. V-CDT) of sediments in the permanently anoxic deep sea (1494 m water depth) reflect the formation of pyrite in the upper part of the sulfidic water column and the anoxic surface sediment. The present study demonstrates that pyrite, which is extremely depleted in ³⁴S, can be found in the Black Sea surface sediments that are positioned both above and below the chemocline, despite differences in biogeochemical and microbial controlling factors.     

A sulfur budget for the Black Sea anoxic zone

A budget for the sulfur cycle in the Black Sea is proposed which incorporates specific biogeochemical process rates. The average sulfide production in the water column is estimated to be 30–50 Tg yr⁻¹, occurring essentially in the layer between 500 and 2000 m. About 3.2–5.2 Tg sulfide yr⁻¹ form during sulfate reduction in surface sediments of the anoxic zone. Total sulfur burial in anoxic sediments of 1 Tg yr⁻¹ consists of 10–70% (ca. 40–50% is the average) water column formed (syngenetic) component, the rest being diagenetic pyrite. As a maximum, between 3 and 5 Tg yr⁻¹ contribute sulfide to the bottom water or diffuse downward in the sediment. About 20–50 Tg yr⁻¹ sulfide is oxidized mostly at the chemocline and about 10–20% of this amount (4.4–9.2 Tg yr⁻¹) below the chemocline by the oxygen of the Lower Bosphorus Current. A model simulating the vertical distribution of sulfide in the Black Sea water column shows net consumption in the upper layers down to ca. 500 m, essentially due to oxidation at the chemocline, and net production down to the bottom. On the basis of the calculated budget anoxic conditions in the Black Sea are sustained by the balance between sulfide production in the anoxic water column and oxidation at the chemocline. On average the residence time of sulfide in the anoxic zone is about 90–150 yr, comparable to the water exchange time between oxic and anoxic zones. Hydrophysical control on the sulfur cycle appears to be the main factor regulating the extent of anoxic conditions in the Black Sea water column, rather than rates of biogeochemical processes.