Tectonic evolution of the southern margin of Laurasia in the Black Sea region

The Black Sea region comprises Gondwana-derived continental blocks and oceanic subduction complexes accreted to Laurasia. The core of Laurasia is made up of an Archaean–Palaeoproterozoic shield, whereas the Gondwana-derived blocks are characterized by a Neoproterozoic basement. In the early Palaeozoic, a Pontide terrane collided and amalgamated to the core of Laurasia, as part of the Avalonia–Laurasia collision. From the Silurian to Carboniferous, the southern margin of Laurasia was a passive margin. In the late Carboniferous, a magmatic arc, represented by part of the Pontides and the Caucasus, collided with this passive margin with the Carboniferous eclogites marking the zone of collision. This Variscan orogeny was followed by uplift and erosion during the Permian and subsequently by Early Triassic rifting. Northward subduction under Laurussia during the Late Triassic resulted in the accretion of an oceanic plateau, whose remnants are preserved in the Pontides and include Upper Triassic eclogites. The Cimmeride orogeny ended in the Early Jurassic, and in the Middle Jurassic the subduction jumped south of the accreted complexes, and a magmatic arc was established along the southern margin of Laurasia. There is little evidence for subduction during the latest Jurassic–Early Cretaceous in the eastern part of the Black Sea region, which was an area of carbonate sedimentation. In contrast, in the Balkans there was continental collision during this period. Subduction erosion in the Early Cretaceous removed a large crustal slice south of the Jurassic magmatic arc. Subduction in the second half of the Early Cretaceous is evidenced by eclogites and blueschists in the Central Pontides and by a now buried magmatic arc. A continuous extensional arc was established only in the Late Cretaceous, coeval with the opening of the Black Sea as a back-arc basin.     

Geochemistry of trace and rare earth elements during weathering of black shale profiles in Northeast Chongqing,Southwestern China: Their mobilization,redistribution, and fractionation

In this study, the mobilization, redistribution, and fractionation of trace and rare earth elements (REE) during chemical weathering in mid-ridge (A), near mountaintop (B), and valley (C) profiles (weak, weak to moderate, and moderate to intense chemical weathering stage, respectively), are characterized. Among the trace elements, U and V were depleted in the regolith in all three profiles, Sr, Nb, Ta, Zr, and Hf displayed slight gains or losses, and Th, Rb, Cs, and Sc remained immobile. Mn, Ba, Zn, Cu, and Cr were enriched at the regolith in profiles A and B, but depleted in profile C. Mn, Pb, and Co were also depleted in the saprock and fractured shale zones in profiles A and B and enriched in profile C. REEs were enriched in the regolith and depleted at the saprock zone in profiles A and B and depleted along profile C. Mobility of trace and REEs increased with increasing weathering intensity. Normalized REE patterns based on the parent shale revealed light REE (LREE) enrichment, middle REE (MREE), and heavy REE (HREE) depletion patterns. LREEs were less mobile compared with MREEs and HREEs, and this differentiation increased with increasing weathering degree. Positive Ce anomalies were higher in profile C than in profiles A and B. The Ce fractionated from other REE showed that Ce changed from trivalent to tetravalent (as CeO₂) under oxidizing conditions. Minimal REE fractionation was observed in the saprock zone in profiles A and B. In contrast, more intense weathering in profile C resulted in preferential retention of LREE (especially Ce), leading to considerable LREE/MREE and LREE/HREE fractionation. (La/Yb)_N and (La/Sm)_N ratios displayed maximum values in the saprock zone within low pH values. Findings demonstrate that acidic solutions can mobilize REEs and result in leaching of REEs out of the highly acidic portions of the saprock material and transport downward into fractured shale. The overall behavior of elements in the three profiles suggests that solution pH, as well as the presence of primary and secondary minerals, play important roles in the mobilization and redistribution of trace elements and REEs during black shale chemical weathering.     

New optically stimulated luminescence ages provide evidence of MIS3 and MIS2 eolian activity on Black Mesa, northeastern Arizona, USA

Eolian deposition on the semiarid southern Colorado Plateau has been attributed to episodic aridity during the Quaternary Period. However, OSL ages from three topographically controlled (e.g. falling) dunes on Black Mesa in northeastern Arizona indicate that eolian sediments there were deposited in deep tributary valleys as early as 35–30 ka, with most sand deposited before 20 ka. In contrast, the oldest OSL ages for sand sheets fall within the Pleistocene-Holocene climatic transition (~ 12–8 ka). Thus most eolian sediment accumulated on Black Mesa under climatic conditions that were in general cooler, moister, and more variable than today, not more arid, pointing to a considerable increase in sediment supply.     

Microbial water quality of the Georgian coastal zone of the Black Sea

From 2006 to 2008, microbial water quality was monitored along the Georgian coast of the Black Sea. Temperature, pH, salinity, and dissolved oxygen were measured, along with a variety of aquatic microbial parameters, including heterotrophic plate count (HPC), total culturable bacterial count (TCBC), and chlorophyll a (Chl-a) concentration. Total and fecal coliforms and total enterococci counts were recorded as indicators of fecal pollution. Vibrio bacteria, and Escherichia coli- and Vibrio-specific bacteriophages were isolated and enumerated to determine their relationships to standard marine pollution indicators.Persistent microbial pollution was observed, particularly in the summer months, with a higher rate of contamination in estuaries. Microbial indicators generally showed seasonal dependence, suggesting that temperature may influence bacterial dynamics in this environment. No correlation was apparent between fecal pollution indicators and physical-chemical and aquatic microbial parameters, although there were significant relationships amongst the indicators themselves, as well as with the prevalence of Vibrio bacteria and phage.     

贵州-广西地区寒武纪重晶石形成条件探讨

通过分析对比前人在黔桂地区寒武纪重晶石方面的研究资料,结合区域构造运动、沉积展布和演化特征,对寒武纪大型重晶石矿床的形成背景和条件进行了研究,认为寒武纪地层的重晶石矿热液沉积成因和生物沉积成因并不是对立的,海底热液不是由火山喷发而是通过深大断裂连接的岩浆形成海底的局部热点形成的.在谊区构造、火山运动整体较弱的背景下,热...     

Sulfate reduction below the sulfate-methane transition in Black Sea sediments

A sudden increase in salinity about 7000 years ago caused a shift in the deposited sediments of the Black Sea from limnic to brackish-marine. Due to the development of an anoxic deep water basin and a relatively high sulfate concentration, organic matter is mineralized primarily through sulfate reduction in modern Black Sea sediments. Earlier studies showed that sulfate-reducing bacteria are abundant within the limnic sub-surface sediment in spite of extremely low concentrations of sulfate and organic carbon. A main objective of the present study was therefore to understand the depth distribution of sulfate reduction across the different sediment units, even deep below the sulfate-methane transition. Our study combined experimental measurements of sulfate reduction using ³⁵S radiotracer with analyses of sulfur and iron geochemistry in pore water and sediment. Potential sulfate reduction rates were measured with ³⁵S in sediment samples that were amended with sulfate and organic substrates and incubated in time-series up to 48 h. Sulfate reduction could thereby be detected and quantified at depths where concentrations of sulfate were otherwise too low to enable calculation of the rates. The results demonstrate that sulfate-reducing bacteria are active several meters below the sulfate-methane transition in Black Sea sediments. The cryptic sulfate reduction below the sulfate-methane transition may be driven by sulfate produced from re-oxidation of reduced sulfur species with oxidized iron minerals buried in the deep limnic sediment.     

Electromagnetic counterparts from counter-rotating relativistic kicked discs

We show the results of two dimensional general relativistic inviscid and isothermal hydrodynamical simulations comparing the behavior of co-rotating (with respect to the black hole rotation) and counter-rotating circumbinary quasi-Keplerian discs in the post merger phase of a supermassive binary black hole system. While confirming the spiral shock generation within the disc due to the combined effects of mass loss and recoil velocity of the black hole, we find that the maximum luminosity of counter-rotating discs is a factor ∼(2-12) higher than in the co-rotating case, depending on the spin of the black hole. On the other hand, the luminosity peak happens ∼10 days later with respect to the co-rotating case. Although the global dynamics of counter-rotating discs in the post merger phase of a merging event is very similar to that for co-rotating discs, an important difference has been found. In fact, increasing the spin of the central black hole produces more luminous co-rotating discs while less luminous counter-rotating ones.     

Evaluation of atmospheric transport as a nonpoint source of polycyclic aromatic hydrocarbons in marine sediments of the Eastern Mediterranean

Coastal marine sediment, air and seawater samples were collected at six sampling stations in the Eastern Mediterranean Sea distant from pollutant point sources. All sediment samples were analyzed to determine polycyclic aromatic hydrocarbon (PAH), black carbon (BC) and organic carbon (OC) contents. The PAH contents of gaseous and seawater samples of the study were determined in order to evaluate the role of air–sea exchange as PAH nonpoint source to the marine sediments. The average concentration of the total PAHs (∑PAHs) in the sediments varied from 2.2 to 1056.2 ng g⁻¹ dry weight. The average BC and OC contents varied from 0.3 to 5.6 and from 2.9 to 21.4 mg g⁻¹ dry weight, respectively. ∑PAH concentration in the marine atmosphere varied from 20.0 to 83.2 ng m⁻³. Air–water exchange flux (F_A–W) estimation has indicated air transport as a significant source of PAHs to pristine marine sediments of Eastern Mediterranean. In addition, the significant correlation between the PAHs and the organic and soot carbon content further suggests the importance of atmospheric input of PAHs to the sediments.     

西南地区黑色岩系铀成矿作用及成因模式探讨

西南地区广泛分布黑色岩系,主要分布于上震旦统—下寒武统、志留系、二叠系和三叠系,其中以上震旦统—下寒武统为主,次为志留系。西南地区黑色岩系中分布有众多的铀矿床、铀矿点和铀矿化点,但铀矿床相对较少。西南地区黑色岩系中典型的矿床有四川若尔盖铀矿床(510)、贵州白马硐铀矿床(504)和广西大新铀矿床(373)。这3个富大铀矿床具有许多相似的特点,与深大断裂有关,也与岩性有关,同时还与岩浆—流体活动有关。西南地区黑色岩系沉积和成岩期初步富集较高含量的铀,是西南地区黑色岩系铀成矿的前奏。后期改造作用和叠加成矿的方式及规模,是西南地区黑色岩系中铀矿大矿和富矿形成的必要条件。西南地区黑色岩系中形成富大铀矿需要经过"三部曲":①前奏:沉积作用形成铀含量高值区(铀异常),②改造:浅源流体改造形成铀的再富集(出现铀矿点、小型或中型矿床),③叠加:深源流体叠加和改造形成富大矿(大型铀矿床)。