黑色硅钙铀矿的研究

本文描述了产于花岗岩内淋积铀矿床中的黑色硅钙铀矿。文中提供了化学分析、X射线数据和其它矿物学数据。研究结果表明,它和黄色硅钙铀矿的差别是含有U~(4+),但矿物中U~(4+)的存在形式还不清楚。     

The role of dust source area and pedogenesis in three loess-palaeosol sections from North Bulgaria: A mineral magnetic study

Rock magnetic studies of three loess-palaeosol sections from Bulgaria (Harletz and Orsoja in the NW and Durankulak in the NE at the Black Sea coast) have been carried out. Thermomagnetic analyses of magnetic susceptibility point to magnetite as the major ferrimagnetic carrier in the loess and palaeosol units. Maghemite gives a significant contribution to the total magnetic signal in the recent soils (S₀), while in one of the sections-Orsoja-hematite may also be present. The effective magnetic grain sizes deduced from the hysteresis measurements and the ratios M_rs/M_s and B_cr/B_c fall in the pseudo single domain (PSD) range, but the data distributions in a Day diagram for the three different sections are shifted. This is suggested to be caused by different detrital input (e.g. different dust source areas) and varying degrees of pedogenic modification. The calculated background susceptibilities χ_bg differ significantly as well. The lowest value is obtained for the Durankulak section-χ_bg = 9.95 × 10⁻⁸ m³/kg, which is in accordance with the data from other studies of loess-palaeosol profiles from the Black Sea area. The corresponding background susceptibilities for the other two sections studied-Harletz and Orsoja-are significantly higher (33.1 and 17.75 × 10⁻⁸ m³/kg, respectively). Both parent material and pedogenesis are found to be responsible for the observed differences in the magnetic characteristics.     

World's largest known Precambrian fossil black smoker chimneys and associated microbial vent communities, North China: Implications for early life

Black smoker chimneys and biological vent communities have been identified at many sites on the deep seafloor, particularly along oceanic spreading centers. We report the largest and oldest known, microbe-rich sub-meter-sized black smoker chimneys and mounds from a 1.43 billion-year old sulfide deposit in a continental graben in northern China. These chimneys are especially well preserved, with characteristic morphology, internal textures and internal cylindrical mineralogical zonation. Four main types of chimneys are distinguished on textural and mineralogical criteria, exhibiting either Zn–Fe-sulfide or Pb–Zn–Fe-sulfide internal cylindrical mineralogical zones. The chimneys mark vent sites in submarine grabens indicating focused flow-venting processes. The fossil chimneys have mineralogical and geological evolutionary features similar to their counterparts on the modern seafloor and other submarine hydrothermal vents. Black smoker vent fluids and seafloor tectonism played important roles for formation of the massive sulfide deposits in the Mesoproterozoic.We also report the first known, remarkably diverse assemblage of fossil microbialites from around and inside Precambrian vent chimneys, demonstrating that Proterozoic life flourished around submarine hot vents and deep within the chimney vent passages. Filamentous, spherical, rod, and coccus-shaped fossil microbes are preserved preferentially on sulfide precipitates. Based on the depth and setting of the fossil biota, the organisms that produced the microbialites were likely sulfate-reducing chemosynthetic and thermophyllic microbes. Textural and mineralogical evidence shows that biomineralization processes enhanced chimney growth and sulfide precipitation.Close association of microorganisms with sulfide chimneys in modern deep-sea hydrothermal vents and younger ophiolites has sparked speculation about whether life may have originated at similar vents. However, little is known about fossil equivalents of vent microfossils and black smoker chimneys from Earth's early evolution. The fossilized microorganisms from the Gaobanhe black smoker chimney sulfide deposits include thread-like filaments with branching and twisted forms and preserved organic carbon, representing fossilized remnants of microbial mats metabolized at high temperatures characteristic of venting fluids. The preservation of fossil microorganisms provides evidence that microbial populations were closely associated with black smoker chimneys in Earth's early history. The microbial population clearly constitutes the site for mediating mineral formation. These ancient microbial fossils lead to a much better understanding of early life on the deep seafloor. The discovery of the Mesoproterozoic microfossils within black-smoker hydrothermal chimneys indicates that hydrothermal activity around sea-floor vents supported dense microbial communities, and supports speculation that vent sites may have hosted the origin of life.     

绿色勘查技术在广丰许家桥黑滑石矿详查中的应用

在村镇辖区周边矿产勘查中,遇到民居、农田、道路、农业基础设施、山地植被绿化等,为了保护生态环境,满足绿色勘查的要求,提高地质矿产勘查工作质量和效率,在广丰许家桥黑滑石矿详查中,采用无人机航测、便携式全液压岩心钻机等技术设备进行勘查施工.项目通过先进的设备选型、环保的技术工艺、科学的勘查方案及具体的环保措施,取得了缩短勘查周期、提高岩（矿）心采取率、消除传统勘查安全隐患、降低征地搬迁劳动强度与成本及减轻对生态环境的污染与破坏的成效,实现了地质勘查质优高效,经济效益和社会效益双丰收,达到绿色勘察的目标任务。地质矿产勘查工作走绿色勘查之路,不仅保护了绿水青山生态环境,还可通过高标准的绿色勘查技术手段和环境保护要求,提高勘查效率和质量、降低劳动强度和成本、实现节能降耗目标,是一条可持续、高质量发展之路。     

Depositional setting of the 2·1 Ga Francevillian macrobiota (Gabon): Rapid mud settling in a shallow basin swept by high‐density sand flows

The depositional setting of the 2·1 Ga fill of the Franceville Basin of Gabon is important for understanding the habitat (energy and availability of light and oxygen) and taphonomy of recently discovered early macro‐organisms buried in black shales in Unit FB . The available data bearing on the stratigraphy and sedimentology of Unit FB provide new insight into processes acting on the palaeo‐sea floor. The shales are interpreted to have formed as fluid mud deposits interstratified with structureless sands. The latter (Poubara sandstones) were emplaced during a forced regression during the terminal infill of fault‐bounded sub‐basins following a stage characterized by a ferruginous to anoxic water column. The structureless sandstones were deposited from high‐density gravity currents along with a locally strong bottom oscillation of the water column. Tuft structures preserved in cyanobacterial mats, together with the position of the macro‐organisms at the top of the sandstone beds within associated black shales, point to a water depth of less than 80 m. The relative sea‐level fall that drove deposition of the Poubara sandstones controlled the rise of a phototrophic ecosystem and also possibly favoured the supply of oxygen and nutrients via density flows.     

Chronostratigraphic framework and depositional environments in the organic‐rich,mudstone‐dominated Eagle Ford Group,Texas, USA

Since the beginning of the century, several authors have hypothesized and documented the presence of bottom currents during the deposition of mudstones, including mudstones rich in organic matter, challenging the assumption that persistent low‐energy conditions are necessary prerequisites for deposition of such sediments. More processes responsible for transport and deposition of mudstones mean also more processes acting contemporaneously in different parts of a basin. Without a precise and robust chronostratigraphic framework, however, it is not possible to characterize these differences. The new data reported here provide a profoundly different understanding of the controls on sedimentation in distal continental shelf platforms. To enhance the understanding of the different coeval environments of deposition coexisting in a muddy system, the Upper Cretaceous Eagle Ford Group, deposited on the Comanche carbonate platform, has been investigated by integrating sedimentology, mineralogy, geochemistry and palaeoecology, and creating age models in different physiographic sectors using biostratigraphy and geochronology. Data from two cores and 41 outcrops were analysed with a telescopic approach, from grain scale to basin scale. Nine temporal stages over a ca 8 Myr interval (ca 98 to 90 Ma) were defined in an area that spans 75 000 km². Finally, the different environments of deposition recorded within each of the nine stages were interpreted. The construction of the chronostratigraphic framework also allowed: measuring the duration of a basin‐wide gradational increase in energy in the water column (ca 1 Myr) and a hiatus confined into the shallower water sector (ca 2 Myr); determining the mean eruption frequency of volcanoes (ca 9 kyr); and the time of inundation of the Western Interior Seaway (97·5 to 97·1 Ma). The context, the outcrops–cores–logs correlations, the large data set (Appendix  S1 ), the high‐precision and well‐calibrated constraints represent an unprecedented contribution for future regional facies models of organic‐rich units and for improvements of key aspects in the industry of unconventional resources.     

Molecular characterization of dissolved black nitrogen via electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Combustion produces a complex mixture of polycondensed aromatic compounds known as black carbon (BC). Such products can become remobilized from char and soil in the form of dissolved BC (DBC). Ultra-high resolution Fourier transform ion cyclotron resonance mass spectrometry (ESI–FT-ICRMS) analysis of a variety of soil and char leachates showed that a significant proportion of DBC compounds contained one or more nitrogen atoms. While the presence of black nitrogen (DBN) in dissolved organic matter (DOM) has been reported, its molecular features were uncharacterized. Here we present results of FT-ICRMS characterization of DBN, where assigned formulae were validated on the basis on their ¹³C isotope signatures and fragmentation patterns obtained via collision induced dissociation. Possible chemical structures were assigned for several DBN formulae and suggest that nitrogen was incorporated into the core ring system as a pyrrole-type moiety. Most DBN compounds existed as part of homologous series where homologs differed by a mass corresponding to CO₂, suggesting that they were polysubstituted with carboxylic acid groups. The environmental contribution of such novel, aromatic, combustion-derived nitrogen compounds with respect to global nitrogen cycling remains elusive. The biogeochemical implications of the input of such fire-derived products to aquatic ecosystems as part of climate change therefore need to be assessed.     

The Black Sea basins structure and history: New model based on new deep penetration regional seismic data. Part 1: Basins structure and fill

This work is based upon results of interpretation of about 8872 km-long regional seismic lines acquired in 2011 within the international project Geology Without Limits in the Black Sea. The seismic lines cover nearly the entire Black Sea Basins, including Russia, Turkey, Ukraine, Romania and Bulgaria sectors. A new map of acoustic basement relief and a new tectonic structure scheme are constructed for the Black Sea Basins. The basement of the Black Sea includes areas with oceanic crust and areas with highly rifted continental crust. A chain of buried seamounts, which were interpreted as submarine volcanoes of Late Cretaceous (Santonian to Campanian) age, has been identified to the north of the Turkish coast. On the Shatsky Ridge, probable volcanoes of Albian age have also been recognized. Synorogenic turbidite sequences of Paleocene, Eocene and Oligocene ages have been mapped. In the Cenozoic, numerous compressional and transpressional structures were formed in different parts of the Black Sea Basin. During the Pleistocene–Quaternary, turbidites, mass-transport deposits and leveed channels were formed in the distal part of the Danube Delta.