藻源性湖泛水体显黑颗粒的元素形态分析与鉴定

湖泛现象是我国超富营养化浅水湖泊面临的最严峻环境问题之一,水体发黑、发臭是湖泛水体最显著和基本的物理特征.针对太湖湖泛显黑颗粒缺乏从元素形态直接给出证据的问题,针对室内模拟藻体和沉积物存在下形成的湖泛水体,采用多种图谱分析技术,对厌氧截留分离的显黑颗粒物质及其化学组成和元素形态进行了分析鉴定.扫描电镜-X射线能谱分析与荧光光谱分析表明:湖泛水体显黑颗粒物质以藻类残体和悬浮沉积物颗粒物为主,其组成元素以C、O、Si为主;与未发生湖泛的对照样相比,湖泛水体显黑颗粒物样品中具有更高的Fe、S含量.X射线光电子能谱Fe、S微区分析进一步表明:湖泛显黑颗粒物样品中Fe主要以Fe(Ⅱ)的形式存在、S则以还原态S2-的形式赋存,两者具有共同化合成Fe S的充要条件.因此,缺氧厌氧条件下,湖泛水体的显黑物质组成是Fe S,它可由水体中Fe2+和ΣS2-通过化学共沉淀形成,并主要通过吸附于悬浮颗粒物之上而使得整个水柱呈现黑色,指示湖泛的暴发过程和维持状态.     

大气模式估算的东亚区域人为硫酸盐和黑碳气溶胶辐射强迫及其时间变化特征

本文利用大气环流模式及大气化学模式所得气溶胶资料,估算了相对1850s时期硫酸盐和黑碳气溶胶引起的全球及东亚区域人为辐射强迫,重点分析其在东亚区域的季节和长期变化特征.结果表明,就当前全球年平均全天空而言,人为硫酸盐气溶胶对大气顶的直接和云反照率强迫分别为-0.37和-0.98 W·m-2,黑碳气溶胶对大气顶和整层大气的辐射强迫值为0.16和0.47 W·m-2;中国东部区域是目前上述气溶胶辐射强迫最强的区域,硫酸盐的直接和间接辐射强迫分别超过-2.0和-4.0 W·m-2,黑碳对大气顶和整层大气的直接辐射强迫分别可达2.0和5.0 W·m-2;估算的东亚区域上述气溶胶辐射强迫仍在不断增强,峰值预计出现在2010s时段,而且中国东部较强的辐射强迫还可能维持至2030 s左右;在未来中、高排放情景下,东亚区域以上两种气溶胶预计对全球气溶胶辐射强迫有更大的贡献.分析还表明,夏季东亚区域较强的水汽会增强吸湿性硫酸盐气溶胶的光学厚度和晴空直接辐射强迫;云的作用一方面会强化东亚区域全天空条件下大气顶黑碳的辐射强迫,另一方面会影响硫酸盐气溶胶间接云反照率强迫的季节变化;上述气候特征的差异使得东亚区域的气溶胶辐射强迫表现出与欧美区域有所不同的特征.本文所用的气溶胶资料与模式气象场的偏差会给气溶胶辐射强迫计算带来一些不确定性,进一步改进气候模式中气溶胶过程、水汽和云等气象场的模拟将有助于获得更为合理的区域气溶胶辐射强迫估算结果.     

Attenuation mechanisms in fractured fluid-saturated porous rocks: a numerical modelling study

Seismic attenuation mechanisms receive increasing attention for the characterization of fractured formations because of their inherent sensitivity to the hydraulic and elastic properties of the probed media. Attenuation has been successfully inferred from seismic data in the past, but linking these estimates to intrinsic rock physical properties remains challenging. A reason for these difficulties in fluid-saturated fractured porous media is that several mechanisms can cause attenuation and may interfere with each other. These mechanisms notably comprise pressure diffusion phenomena and dynamic effects, such as scattering, as well as Biot's so-called intrinsic attenuation mechanism. Understanding the interplay between these mechanisms is therefore an essential step for estimating fracture properties from seismic measurements. In order to do this, we perform a comparative study involving wave propagation modelling in a transmission set-up based on Biot's low-frequency dynamic equations and numerical upscaling based on Biot's consolidation equations. The former captures all aforementioned attenuation mechanisms and their interference, whereas the latter only accounts for pressure diffusion phenomena. A comparison of the results from both methods therefore allows to distinguish between dynamic and pressure diffusion phenomena and to shed light on their interference. To this end, we consider a range of canonical models with randomly distributed vertical and/or horizontal fractures. We observe that scattering attenuation strongly interferes with pressure diffusion phenomena, since the latter affect the elastic contrasts between fractures and their embedding background. Our results also demonstrate that it is essential to account for amplitude reductions due to transmission losses to allow for an adequate estimation of the intrinsic attenuation of fractured media. The effects of Biot's intrinsic mechanism are rather small for the models considered in this study.     

震源物理:进展和趋势

本文根据第二十届IUGG大会交流的情况和提供的材料,结合作者以往的文献积累,评述了近四年震源物理的主要进展和趋势.主要内容分为地震动力学破裂复杂性的研究,摩擦本构行为和失稳机制的研究,线弹性断裂力学的应用,分形和混沌等四个方面.     

The factors controlling the partitioning of polybrominated diphenyl ethers and polychlorinated biphenyls in the water-column of the Pearl River Estuary in South China

In this study, the distribution and partition of polybrominateddiphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in water from the Pearl River Estuary were investigated. A seasonal dependence for dissolved and particle phase PCB and PBDE levels was observed. A high dissolved phase level occurred in the dry season. The positive correlation between POC content in the particles and phase distribution coefficients (K_p) suggested that POC may play an important role in determining the partition of PBDEs and PCBs. A linear correlation between the observed log K_OC and log K_OW for PBDEs and PCBs was found with slopes less than one. The observed log K_OC values were lower than the predicted log K_OC values for PBDEs (except for BDE28). The log K_OC values were higher than the predicted values for PCBs. A combination of sorption to colloids (10-98% for PBDEs and less than 25% for PCBs) and adsorption to BC was responsible for this observation.     

Glacier response to the change in atmospheric circulation in the eastern Mediterranean during the Last Glacial Maximum

In this study, we document glacial deposits and reconstruct the glacial history in the Karagöl valley system in the eastern Uludağ in northwestern Turkey based on 42 cosmogenic ¹⁰Be exposure ages from boulders and bedrock. Our results suggest the Last Glacial Maximum (LGM) advance prior to 20.4 ± 1.2 ka and at least three re-advances until 18.6 ± 1.2 ka during the global LGM within Marine Isotope Stage-2. In addition, two older advances of unknown age are geomorphologically well constrained, but not dated due to the absence of suitable boulders. Glaciers advanced again two times during the Lateglacial. The older is exposure dated to not later than 15.9 ± 1.1 ka and the younger is attributed to the Younger Dryas (YD) based on field evidence. The timing of the glaciations in the Karagöl valley correlates well with documented archives in the Anatolian and Mediterranean mountains and the Alps. These glacier fluctuations may be explained by the change in the atmospheric circulation pattern during the different phases of North Atlantic Oscillation (NAO) winter indices.     

东北黑土退化动态监测体系建设构想

本文根据近期对黑土退化的研究,并结合相关文献资料,对黑土退化、保护及遥感监测体系的研究现状进行了总体分析,并在此基础上提出了黑土退化监测体系建设构想,并从东北黑土退化监测体系总全框架、结构、功能以及各部分的关系出发,对体系各部分所需采用的监测方法、监测内容等问题进行了进一步的探讨。     

河西走廊“2010.4.24”黑风成因分析

利用常规探测资料和地面加密观测资料,对2010年4月24日河西走廊出现的区域性特强沙尘暴和民勤出现的黑风天气过程进行了天气动力学诊断和中尺度分析。结果表明,地面冷锋所伴随的强风暴是产生黑风的主要原因。乌拉尔山高压脊强烈发展,迫使极地强冷空气向南爆发是这次黑风产生的大尺度触发系统;700hPa河西走廊变形场的强斜压性既有...     

Hydrodynamic modelling of mesoscale eddies in the Black Sea

A three dimensional structure of mesoscale circulation in the Black Sea is simulated using the Proudman Oceanographic Laboratory Coastal Ocean Modelling System. A number of sensitivity tests reveal the response of the model to changes in the horizontal resolution, time steps, and diffusion coefficients. Three numerical grids are examined with x-fine (3.2 km), fine (6.7 km) and coarse (25 km) resolution. It is found that the coarse grid significantly overestimates the energy of the currents and is not adequate even for the study of basin-scale circulation. The x-fine grid, on the other hand, does not give significant advantages compared to the fine grid, and the latter is used for the bulk of simulations. The most adequate parameters are chosen from the sensitivity study and used to model both the basin-scale circulation and day-to-day variability of mesoscale currents for the months of May and June of 2000. The model is forced with actual wind data every 6 h and monthly climatic data for evaporation, precipitation, heat fluxes and river run-off. The results of the fine grid model are compared favourably against the satellite imagery. The model adequately reproduces the general circulation and many mesoscale features including cyclonic and anticyclonic eddies, jets and filaments in different parts of the Black Sea. The model gives a realistic geographical distribution and parameters of mesoscale currents, such as size, shape and evolution of the eddies.     

黑色硅钙铀矿的研究

本文描述了产于花岗岩内淋积铀矿床中的黑色硅钙铀矿。文中提供了化学分析、X射线数据和其它矿物学数据。研究结果表明,它和黄色硅钙铀矿的差别是含有U~(4+),但矿物中U~(4+)的存在形式还不清楚。