2015年11月沈阳地区一次PM2.5重污染过程综合分析

利用多源观测资料综合分析了2015年11月沈阳地区一次PM2.5 重污染天气的气象条件、垂直风场演变、大气边界层特征以及污染物的来源。结果表明:本次重污染过程中,沈阳市区PM2.5浓度长达81h超过250μg · m^-3 ,其中峰值浓度达到1287μg · m^-3 ,重污染期间PM2.5 /PM10 的比例最高为90%。受地面倒槽和黄淮气旋影响,近地面层持续存在的逆温层、高相对湿度和弱偏北风为颗粒物吸湿增长和长时间聚集提供有利的天气条件。风廓线雷达风场资料显示在重污染期间,近地面层存在弱风速区、凌乱风场和弱下沉气流。利用风廓线雷达资料计算了边界层通风量(Ventilation Index,VI)和局地环流指数(Recirculation,R),边界层通风量VI和PM2.5 存在明显的负相关,非污染日VI是重污染日的2倍,局地环流指数R在重污染天气前大于0.9,而在污染期间部分空间R小于0.8。通过后向轨迹模式和火点监测资料分析发现,沈阳上空300m高度气团来自于生物质燃烧区域,而且沈阳地区NO2和CO浓度的变化与PM2.5一致,说明本次重污染过程也可能和生物质燃烧有关。     

北京奥运会期间NO2浓度降低原因分析

2002～2008年,北京市城区和近郊8月的NO2月均浓度大体呈现逐年下降趋势,其中前5年二者均以每年约10%的降幅下降,2008年发生显著下降,降幅达40%左右。利用嵌套网格空气质量模式系统(NAQPM/IAP),采用敏感性试验方法,评估了气象条件与污染控制措施对北京奥运会期间大气NO2浓度降低的影响,评估不同污染控制措施对NO2浓度降低的作用。研究结果表明,污染控制措施是NO2浓度降低的主要影响因素,其中面源的污染控制措施对于NO2浓度降低的作用最明显。     

A numerical study of tropospheric ozone in the springtime in East Asia

The Models-3 Community Multi-scale Air Quality modeling system (CMAQ)coupled with the Regional Atmospheric Modeling System (RAMS)is applied to East Asia to study the transport and photochemical transformation of tropospheric ozone in March 1998．The calculated mixing ratios of ozone and carbon monoxide are compared with ground 1evel observations at three remote sites in Japan and it is found that the model reproduces the observed features very well．Examination of several high episodes of ozone and carbon monoxide indicates that these elevated levels are found in association with continental outflow,demonstrating the critical role of the rapid transport of carbon monoxide and other ozone precursors from the continental boundary layer．In comparison with available ozonesonde data,it is found that the model-calculated ozone concentrations are generally in good agreement with the measurements,and the stratospheric contribution to surface ozone mixing ratios is quite limited．     

工业部门污染物治理协同控制温室气体效应评价——基于重庆市的实证分析

以高能耗为主要特征的工业部门是大气污染物和温室气体的重要排放源.为推动协同管控,文中结合生态环境部在重庆市组织开展的试点工作,对工业企业NOx污染治理协同控制温室气体的效应进行了量化分析.结果表明,以末端治理为手段的NOx治理措施协同控制温室气体的效果为负,即工业企业去除1 t NOx会直接或间接增加CO2排放1.81...     

The Role of Planetary Boundary-Layer Parameterizations in the Air Quality of an Urban Area with Complex Topography

The effect of different planetary boundary-layer (PBL) parameterization schemes on the spatial distribution of atmospheric pollution over the complex topography of the greater Athens area is investigated. Four PBL schemes originally implemented in a numerical meteorological model and a fifth one simulating the urban effect are examined. Two different atmospheric conditions are analyzed; a typical summer and a typical winter pollution episode. The relative importance of chemical and physical processes of the pollution predictions is discussed using process analysis. It is revealed that, for primary pollutants, a local scheme seems more adequate to represent the maximum observed concentrations while, completely different in structure, a non-local scheme reproduces the mean observed values in the basin. Concerning secondary pollutants, peak concentration differences, due to the different PBL schemes, are smoothed out. Nevertheless, the PBL scheme selection shapes the horizontal and the vertical extension of maximum values. The non-local and semi non-local schemes are superior to the others, favouring strong vertical mixing and transport towards the surface. The stronger turbulence accommodated effectively by the semi non-local urban scheme enhances ozone production along the sea-breeze axis and preserves the high ozone concentrations during the nighttime hours in the urban core.     

Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.     

珠穆朗玛峰北坡山谷太阳辐射和大气的特征与分析

2006年5月27日～6月30日HEST2006大气科学实验对珠峰北坡山谷的辐射(总辐射、净辐射)和温、湿度、风等进行了综合观测.沿珠峰北坡山谷布设了3个观测站,3个测站的辐射、温度、风都表现出明显的日变化规律,它们在08:00或09:00(地方时,下同)达到极大值.3个测站总辐射和净辐射的日变化都七匕较一致.从日变化最大值出现的时间来看,各站的辐射通量早于气温,气温早于风速.3个测站中任意2站之间辐射(总辐射、净辐射)最大值之比与温度和风速最大值之比均比较接近.因辐射状况、地形结构、大气温度等不同,远离珠峰区域的风一天之内多次改变风向,靠近珠峰区域则24h都为南风.珠峰北坡山谷不同区域风向风速变化存在明显时差,南风强于北风,且持续时间长.研究表明,辐射能量对于珠峰北坡大气运动具有重要的驱动作用,是控制和改变其大气运动方式最基本、最重要的因子.净辐射在不同区域风向转变或风速变化过程中起着决定性的作用.     

雷州半岛近40年来气温和降水的变化

利用1961～2000年雷州半岛5个气象站的月平均降水量、平均最高、最低气温等资料，对雷州半岛40年和近10年的变化作了较为全面的分析。     

近50年火山喷发和太阳活动对我国气候影响的研究

利用特征向量分析与时序叠加分析和谱分析相结合的方法，分析了近50a来我国地面气温和降水场中火山喷发和太阳活动的气候信号，强烈的火山喷发导致全国大部分地区降温，喷发1a多以后降温最明显，并能持续约半年。除这个主信号以外，青藏高原、东南沿海和东北地区都可能出现较为复杂的温度变化，温度变化与太阳活动之间的联系更多地反映在二者的振荡关系上。在降水场中的火山信号较弱，表现为火山喷发后的秋冬季节南方地区降水偏多。在青藏高原积雪和深层地温的变化中，没有发现火山和太阳活动信号。     

简单热带海气耦合模型中的缓慢扰动I:对称和反对称于赤道的运动

文中讨论了在局地热平衡情况下简单模式中的热带海气耦合扰动 ,指出参数 KH,KS和α决定着耦合扰动性质 ,并研究了使用抛物线柱函数展开时所截项数多寡对耦合扰动性质的影响以及对称和反对称于赤道的耦合扰动特征