(Re) deposition of loess in southern Limbourg,the Netherlands 3. Field evidence for conditions of deposition of the middle and upper silt loam complexes,and landscape evolution at Nagelbeek

This paper is about conditions and processes during the accumulation of the Upper Pleniglacial Middle and Upper Silt Loam complexes at Nagelbeek, Limbourg, a Weichselian stratigraphical type locality. The complexes correlate with Hesbayan and Brabantian loesses in Belgium, formed between 28,000 and 12,400 yrs BP. They are characterized by sediment features (cracks, mass deformations, and cut-and-fill features) that are ascribed to a cryogenic regimen. The main Middle Silt Loam subunit contains contraction cracks deformed and further modified by masswasting. Intra-Upper-Pleniglacial pedogenic intervals are inferred from three greyish bands, from a truncated weathered zone surmounting the Middle Silt Loam, and from an aeolian-cumulic palaeosol at the base of the Upper Silt Loam. Latter two zones and an intervening erosional unconformity were cryogenically reworked, less than 22,000 yrs BP, to form a complex stratigraphical marker-zone: the ‘Horizon à Langues de Nagelbeek’. Morphological variants of the marker-zone are described. The geomorphic evolution of the Nagelbeek upland, from Saalian to Holocene times, is summarized in unconformity maps and a time diagram.     

Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer

The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the _m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most _m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised _m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear _m relation for the stable case; (3) data that define collinear _m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of _m and z/L.     

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.     

<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.     

沁水煤田霍东地区山西组主要煤层对比

运用标志层、层间距、物性特征、煤层本身特征等方法，对霍东地区沁安矿区和沁源矿区山西组1号、2号、3号煤层进行对比，认为沁安矿区未沉积3号煤层，该矿区现有的两个煤与沁源矿区的1号、2号煤层可比，而不是2号、3号煤层，其中既有定性又有定量，较成功的解决了南北两大矿区山本组主要可采煤层间的对比问题。     

古鄱阳湖盆地东北缘白晋纪地层的新材料—兼论陆相地层清理后的问题讨论

古鄱阳湖盆地东北缘白垩系的田坂群历来趋向“二分”，但从对剖在再观察入手，认为田坂群纵向上经历了粗→细→粗的巨旋回，这种巨旋回与盆地演化规律，发展阶段相一致，因而“三分”显著，该剖面地学，9沉积学的一些新发现，不仅便于地层划分与对比，而且对盆内层序地层，岩相分析，构造演化阶段研究都具重要意义。     

Histological bone structure of Lower Cretaceous dinosaurs from southwest Istria (Croatia)

Recently discovered dinosaur bones in submerged near-shore deposits of southwest Istria include one vertebra, one femur, and two rib fragments. They all show well-developed vascularization. The large amounts of primary bone tissue in the vertebral and femoral compacta as well as in one rib fragment suggest that they belong to sub-adult animals which were growing rapidly. The structure of a second rib fragment differs in that it consists of secondary bone. The absence of lines of arrested growth is evident in all investigated bones. This suggests a sustained manner of bone deposition.     

Intracrystalline fractionation of Fe in synthetic (Fe, Mg, Zn) - bearing staurolite: a Mössbauer spectroscopic study

⁵⁷Fe-Mössbauer spectra of eleven Fe-Mg-bearing staurolite samples, synthesized at 5, 20 and 25 kbar and 680°C, ranging in composition from x_Fe?=1.00 to x_Fe?=0.15, and of two Zn-Fe-bearing staurolite samples, synthesized at 20 kbar and 700°C with x_Fe?=0.10 and x_Fe?=0.32 were collected at room temperature. The spectra reveal that about 80% of Fe_tot (in case of Fe-Mg-bearing staurolite) and about 70% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the three subsites Fe1, Fe2 and Fe3 of the tetrahedral T2-site. The refinement of the spectra results in almost identical values for the isomer shift (IS) (±1.0 mm/s) but significantly different values for the quadropole splitting (QS) for the three subsites which is in accordance with the different distortions of these sites. About 8% of Fe_tot (in case of Fe-Mg-bearing staurolite) and 13% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the octahedral M4 site, while the remainder percents of Fe_tot indistinguishably occur as Fe²⁺ at the octahedral M1 and M2 sites of the kyanite-like part of the structure. Within the whole Fe-Mg-staurolite solid solution series the Mössbauer parameters QS of the sites M4 and (M1, M2) vary systematically with composition whereas IS remains constant. There is a high negative correlation of the total Mg-content with Fe-occupation of all the Fe-bearing sites indicating a continuous substitution of Fe²⁺ by Mg on all these sites. Synthetic Fe-staurolites show no increasing occupation of the octahedral sites by two-valent cations with pressure, as was assumed by several authors.     

When are relative variograms useful in geostatistics?

The relative variogram has been employed as a tool for correcting a simple kind of nonstationarity, namely that in which local variance is proportional to local mean squared. In the past, this has been linked in a vague way to the lognormal distribution, although if {Z_t; t D}is strongly stationary and normal over a domain D,then clearly {exp (Z_t); t D}will stillbe stationary, but lognormal. The appropriate link is made in this article through a universal transformation principle. More general situations are considered, leading to the use of a scaled variogram.