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11.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental
Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software
package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters
of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was
performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e.,
without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic
glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites,
fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and
a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements
(Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations,
similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis
which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to
the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture
of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger
of Sr and Ba is emphasized.
相似文献
Luigi Marini (Corresponding author)Email: |
12.
Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years. 相似文献
13.
Klauea historical summit lavas have a wide range in matrix 18OVSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, 18O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine 18O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma 18O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine 18O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination 相似文献
14.
This article describes a unique flood hazard, produced by the dramatic expansion of wetlands in Nelson County, located within
the North American Prairie Pothole Region of North Dakota, USA. There has been an unprecedented increase in the number, average
size, and permanence of prairie wetlands, and a significant increase in the size of a closed lake (Stump Lake) due to a decade-long
wet spell that began in 1993 following a prolonged drying trend. Base-line land cover information from the 1992 USGS National
Land Cover Characterization dataset, and a Landsat TM scene acquired 9 July 2001 are used to assess the growth of the closed
lake and wetland pond surface areas, and to analyze the type and area of various land cover classes inundated between 1992
and 2001. The open water profile in Nelson County changed from one marked by relatively comparable coverage of closed lake
and wetland pond areas in 1992, to one in which wetland open water accounted for the vast majority of total open water in
2001. The bulk of the wetland pond area expansion occurred by displacing existing wetland vegetation and agricultural cropland.
Producers responded to the flood hazard by filing Federal Crop Insurance Corporation (FCIC) claims and enrolling cropland
in the Conservation Reserve Program (CRP), a federal land retirement program. Land taken out of agricultural production has
had an enormous impact upon the agricultural sector that forms the economic base of the rural economy. In 2001 the land taken
out of production due to CRP enrollment and preventive planting claims represented nearly 42% of Nelson County’s 205.2 K ha
base agricultural land. The patterns obtained from this detailed study of Nelson County are likely to be the representative
of the more publicized flood disaster occurring within the Devils Lake Basin of North Dakota. 相似文献
15.
GUI Maochang * WU Lingjuan . Institute of Oceanology Chinese Academy of Sciences Qingdao China. Laboratory of Numerical Modeling for Atmospheric Sciences Geophysical Fluid Dynamics Institute of Atmospheric Physics Chine-se Academy of Sciences Beijing China. Graduate School Chinese Academy of Sciences Beijing China 《海洋学报(英文版)》2005,(4)
1 IntroductionIt is well known that interaction between the trop-ical ocean and atmosphere produces the largest inter-annual climate signal, El Nino-Southern Oscillation(ENSO). In past decades many efforts have been madein understanding and predicting ENSO: such as the hy-pothesis of Bjerknes (1969) that ENSO arises as aself-sustained cycle in which SSTA in the Pacific O-cean causes the trade winds to strengthen or slackenand that this in turn drives the ocean circulation changesthat … 相似文献
16.
H. Jonsson K. Viken Sandnes D. Schiedek R. Schneider B. E. Grsvik A. Goksyr 《Marine environmental research》2004,58(2-5):655
In an attempt to learn more about the cytochrome P450 (CYP) system of mussels, we used protein databases and alignment software to extract highly conserved CYP sequences. From these alignments synthetic peptides were produced and used for rabbit immunisation, which yielded polyclonal antibodies against the CYP families 2 and 4. The antibodies were evaluated with Western Blot and ELISA assays, using digestive gland microsomal samples from the mussel Mytilus edulis. Western Blots revealed immunoreactions for both antibodies. The anti-CYP2 sequence rendered one major immunopositive protein of ≈49 kDa size, and weak signals for proteins of ≈41 and 56 kDa size. The anti-CYP4 sequence rendered two major bands of ≈56 and 59 kDa size, and also a weak immunoreaction with a protein of ≈43 kDa size. ELISA rendered only weak signals even with a 1:50 dilution of IgG-purified serum. A 10-day exposure to Aroclor 1254 did not appear to affect any of the immunopositive proteins, while total PCBs in soft bodies increased from 14–40 ng/g DW in controls to 373–638 ng/g DW in exposed mussels. 相似文献
17.
In order to clarify the formation and circulation of the Japan/East Sea Intermediate Water (JESIW) and the Upper portion of
the Japan Sea Proper Water (UJSPW), numerical experiments have been carried out using a 3-D ocean circulation model. The UJSPW
is formed in the region southeast off Vladivostok between 41°N and 42°N west of 136°E. Taking the coastal orography near Vladivostok
into account, the formation of the UJSPW results from the deep water convection in winter which is generated by the orchestration
of fresh water supplied from the Amur River and saline water from the Tsushima Warm Current under very cold conditions. The
UJSPW formed is advected by the current at depth near the bottom of the convection and penetrates into the layer below the
JESIW. The origin of the JESIW is the low salinity coastal water along the Russian coast originated by the fresh water from
the Amur River. The coastal low salinity water is advected by the current system in the northwestern Japan Sea and penetrates
into the subsurface below the Tsushima Warm Current region forming a subsurface salinity minimum layer.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
18.
Roles of Continental Shelves and Marginal Seas in the Biogeochemical Cycles of the North Pacific Ocean 总被引:4,自引:0,他引:4
Chen-Tung Arthur Chen Andrey Andreev Kyung-Ryul Kim Michiyo Yamamoto 《Journal of Oceanography》2004,60(1):17-44
Most marginal seas in the North Pacific are fed by nutrients supported mainly by upwelling and many are undersaturated with
respect to atmospheric CO2 in the surface water mainly as a result of the biological pump and winter cooling. These seas absorb CO2 at an average rate of 1.1 ± 0.3 mol C m−2yr−1 but release N2/N2O at an average rate of 0.07 ± 0.03 mol N m−2yr−1. Most of primary production, however, is regenerated on the shelves, and only less than 15% is transported to the open oceans
as dissolved and particulate organic carbon (POC) with a small amount of POC deposited in the sediments. It is estimated that
seawater in the marginal seas in the North Pacific alone may have taken up 1.6 ± 0.3 Gt (1015 g) of excess carbon, including 0.21 ± 0.05 Gt for the Bering Sea, 0.18 ± 0.08 Gt for the Okhotsk Sea; 0.31 ± 0.05 Gt for
the Japan/East Sea; 0.07 ± 0.02 Gt for the East China and Yellow Seas; 0.80 ± 0.15 Gt for the South China Sea; and 0.015 ±
0.005 Gt for the Gulf of California. More importantly, high latitude marginal seas such as the Bering and Okhotsk Seas may
act as conveyer belts in exporting 0.1 ± 0.08 Gt C anthropogenic, excess CO2 into the North Pacific Intermediate Water per year. The upward migration of calcite and aragonite saturation horizons due
to the penetration of excess CO2 may also make the shelf deposits on the Bering and Okhotsk Seas more susceptible to dissolution, which would then neutralize
excess CO2 in the near future. Further, because most nutrients come from upwelling, increased water consumption on land and damming
of major rivers may reduce freshwater output and the buoyancy effect on the shelves. As a result, upwelling, nutrient input
and biological productivity may all be reduced in the future. As a final note, the Japan/East Sea has started to show responses
to global warming. Warmer surface layer has reduced upwelling of nutrient-rich subsurface water, resulting in a decline of
spring phytoplankton biomass. Less bottom water formation because of less winter cooling may lead to the disappearance of
the bottom water as early as 2040. Or else, an anoxic condition may form as early as 2200 AD.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
19.
Sediment-starved sand ridges on a mixed carbonate/siliciclastic inner shelf off west-central Florida
S. E. Harrison S. D. Locker A. C. Hine J. H. Edwards D. F. Naar D. C. Twichell D. J. Mallinson 《Marine Geology》2003,200(1-4):171-194
High-resolution side-scan mosaics, sediment analyses, and physical process data have revealed that the mixed carbonate/siliciclastic, inner shelf of west-central Florida supports a highly complex field of active sand ridges mantled by a hierarchy of bedforms. The sand ridges, mostly oriented obliquely to the shoreline trend, extend from 2 km to over 25 km offshore. They show many similarities to their well-known counterparts situated along the US Atlantic margin in that both increase in relief with increasing water depth, both are oriented obliquely to the coast, and both respond to modern shelf dynamics. There are significant differences in that the sand ridges on the west-central Florida shelf are smaller in all dimensions, have a relatively high carbonate content, and are separated by exposed rock surfaces. They are also shoreface-detached and are sediment-starved, thus stunting their development. Morphological details are highly distinctive and apparent in side-scan imagery due to the high acoustic contrast. The seafloor is active and not a relict system as indicated by: (1) relatively young AMS 14C dates (<1600 yr BP) from forams in the shallow subsurface (1.6 meters below seafloor), (2) apparent shifts in sharply distinctive grayscale boundaries seen in time-series side-scan mosaics, (3) maintenance of these sharp acoustic boundaries and development of small bedforms in an area of constant and extensive bioturbation, (4) sediment textural asymmetry indicative of selective transport across bedform topography, (5) morphological asymmetry of sand ridges and 2D dunes, and (6) current-meter data indicating that the critical threshold velocity for sediment transport is frequently exceeded. Although larger sand ridges are found along other portions of the west-central Florida inner shelf, these smaller sand ridges are best developed seaward of a major coastal headland, suggesting some genetic relationship. The headland may focus and accelerate the N–S reversing currents. An elevated rock terrace extending from the headland supports these ridges in a shallower water environment than the surrounding shelf, allowing them to be more easily influenced by currents and surface gravity waves. Tidal currents, storm-generated flows, and seasonally developed flows are shore-parallel and oriented obliquely to the NW–SE trending ridges, indicating that they have developed as described by the Huthnance model. Although inner shelf sand ridges have been extensively examined elsewhere, this study is the first to describe them in a low-energy, sediment-starved, dominantly mixed siliciclastic/carbonate sedimentary environment situated on a former limestone platform. 相似文献
20.
J. Perbos P. Escudier F. Parisot G. Zaouche P. Vincent Y. Menard F. Manon G. Kunstmann D. Royer L. -L. Fu 《Marine Geodesy》2003,26(3):147-157
On 7 December 2001, Jason-1 was successfully launched by a Boeing Delta II rocket from the Vandenberg Air Force Base, California. The Jason-1 satellite will maintain the high accuracy altimeter service provided since 1992 by TOPEX/Poseidon (T/P), ensuring the continuity in observing and monitoring the Ocean Dynamics (intraseasonal to interannual changes, mean sea level, tides, etc.). Despite one-fourth the mass and power, the Jason-1 system has been designed to have basically the same performance as T/P, measuring sea surface topography at a centimetric level. This new CNES/NASA mission also provides near real-time data for sea state and ocean forecast. The first two months of the Jason-1 mission have been dedicated to the assessment of the overall system. The goals of this assessment phase were:
1. To assess the behavior of the spacecraft at the platform and payload levels (Jason-1 being the first program to call on the PROTEUS versatile multimission platform for Low and Medium Earth Orbit Missions developed in partnership between Alcatel Space and CNES);
2. To verify that platform performance requirements are met with respect to Jason-1 requirements;
3. To verify that payload instruments performance requirements evaluated at instrument level are met;
4. To assess the performance of the Jason-1 Ground System.
This article will display the main outputs of the assessment of the system. It will demonstrate that all the elements of the onboard and ground systems are within the specifications. Provision of data to the Jason-1 Science Working Team started at the end of March 2002. This is the goal of a six-month phase after closure of the initial assessment phase to derive the error budget of the system in terms of altimetry user products. 相似文献
1. To assess the behavior of the spacecraft at the platform and payload levels (Jason-1 being the first program to call on the PROTEUS versatile multimission platform for Low and Medium Earth Orbit Missions developed in partnership between Alcatel Space and CNES);
2. To verify that platform performance requirements are met with respect to Jason-1 requirements;
3. To verify that payload instruments performance requirements evaluated at instrument level are met;
4. To assess the performance of the Jason-1 Ground System.
This article will display the main outputs of the assessment of the system. It will demonstrate that all the elements of the onboard and ground systems are within the specifications. Provision of data to the Jason-1 Science Working Team started at the end of March 2002. This is the goal of a six-month phase after closure of the initial assessment phase to derive the error budget of the system in terms of altimetry user products. 相似文献