鄂尔多斯盆地庆城地区延长组7段致密油特征及油源分析

鄂尔多斯盆地三叠系延长组7段(长7段)半深湖—深湖相优质油源岩是油气的重要来源,包括黑色页岩和暗色泥岩,作为盆地重要的供烃源岩一直是研究的热点。为了明确不同烃源岩的贡献及油气来源,通过对庆城地区长7段致密油特征进行分析,对原油进行精细划分,并对源岩有效性进行分析,进一步明确油源对应关系,研究表明,庆城地区长7段黑色页岩和暗色泥岩均对油气成藏有贡献,其中黑色页岩贡献最大,长7₃段暗色泥岩次之,长7₂和长7₁段暗色泥岩贡献较小;原油为低密度、中—低黏度和低凝固点的轻质油。根据生标物特征将原油划分为3类,A类原油具有低C₃₀重排藿烷/C₂₉藿烷、低C₂₉Ts/C₂₉藿烷、低Ts/Tm的特征,由黑色页岩贡献,主要分布于长7₁段;C类原油具有高C₃₀重排藿烷/C₂₉藿烷、高C₂₉Ts/C₂₉藿烷、高Ts/Tm的特征,主要由暗色泥岩贡献,...     

A new method for the quantification of different redox-species of molybdenum (V and VI) in seawater

A new method for the direct determination of reduced and oxidized Mo species (Mo (V) and Mo (VI)) in seawater was developed and used for the first time. The method includes the complexation of Mo (V) with tartrate, solid phase extraction of the Mo (V)–tartrate complex by a XAD 7HP resin, followed by elution with acidic acetone. In this study, the eluted Mo (V) was quantified by graphite furnace atomic absorption spectrometry. The detection limit of this protocol was on the order of 0.2 nM. The analytical precision was 10% of ~ 10 nM. This method was successfully applied to the determination of Mo (V) and Mo (VI) in surface and bottom waters at the head of Peconic River Estuary. Total Mo (Mo (V) + Mo (VI)) ranged from 100–120 nM in most bottom saline waters, and 2.5–15 nM for surface fresher waters. Concentrations of Mo (V) in these environments ranged from 0 nM to ~ 15 nM, accounting for 0%–15% of the total dissolved Mo pool. The time series experiments showed that the Mo speciation changed within 1 h after the water collection, and therefore it is strongly suggested that speciation analysis be carried out within the first 15 min. However, since these are the first Mo speciation data in concentration ranges typical of normal marine and coastal waters, additional research may be required to optimize the methodology and further explore Mo cycling mechanisms.     

Geochemistry constraints of Mesozoic–Cenozoic calc-alkaline magmatism in the South Shetland arc, Antarctica

Geochemical data from basalts, basaltic andesites, and andesites of the Mesozoic–Cenozoic (143–44 Ma) from Livingston, Greenwich, Robert, King George, and Ardley Islands of the South Shetland archipelago, Antarctica, are presented. The rocks have variable SiO₂ of approximately 46–61 wt%, Al₂O₃ of 15–26 wt%, and total alkali (K₂O+Na₂O) of 2–6 wt%. Most samples have low Mg#, Cr, and Ni, which indicates that they have undergone significant fractional crystallization from mantle-derived melts. The presence of olivine cumulatic in the samples from Livingston and Robert Islands explains some high MgO, Ni, and Cr values, whereas low Rb, Zr, and Nb values could be related to undifferentiated magmas. N-MORB-normalized trace element patterns show that South Shetland Islands volcanic rocks have a geochemical pattern similar to that found for other island arcs, with enrichment in LILE relative to HFSE and in LREE relative to HREE. The geochemistry pattern and presence of calcic plagioclase, orthopyroxene, Mg-olivine, and titanomagnetite phenocrysts suggest a source related to the subduction process. The geochemical data also suggest magma evolution from the tholeiitic to the calc-alkaline series; some samples show a transitional pattern. Samples from the South Shetland archipelago show moderate LREE/HREE ratios relative to N-MORB and OIB, depletion in Nb relative to Yb, and high Th/Yb ratios. These patterns probably reflect magma derived from a lithospheric mantle source previously modified by fluids and sediments from a subduction zone.

Resumo

Dados geoquímicos de basaltos, andesitos basálticos e andesitos mesozóicos–cenozóicos (143–44 Ma) das ilhas Livingston, Greenwich, Robert, King George e Ardley do Arquipélago Shetland do Sul, Antártica são discutidas neste artigo. As rochas tem conteúdos de SiO₂ variando de 46 a 61%, Al₂O₃ de 15 a 26% e álcalis (K₂O+Na₂O) de 2 a 6%. A maior parte das amostras tem conteúdos baixos de Mg#, Cr e Ni, indicando que sofreram significante cristalização fracionada de fusões derivadas do manto. A presença de fases cumuláticas nas amostras das ilhas Livingston e Robert explicaria os elevados valores de MgO, Ni, Cr, enquanto que baixos valores de Rb, Zr e Nb observados nas amostras destas ilhas poderiam estar relacionados a magmas não diferenciados. Os padrões de elementos-traço normalizados pelo N-MORB mostram que as rochas vulcânicas das Ilhas Shetland do Sul têm padrão geoquímico similar àqueles encontrados em outros arcos de ilhas com enriquecimento em LILE em relação aos HFSE e em ETRL em relação aos ETRP. O padrão geoquímico e a ocorrência de fenocristais de plagioclásio cálcico, ortopiroxênio, olivina magnesiana e titanomagnetita sugerem origem relacionada a processos de subducção. Dados geoquímicos obtidos para as amostras do arquipélago Shetland do Sul sugerem um magma evoluindo de toleítico para cálcico-alcalino, observando-se em algumas amostras um padrão transicional. As amostras do arquipélago Shetland do Sul mostram em relação ao N-MORB e OIB, moderadas razões ETRL/ETRP, empobrecimento em Nb relativo a Yb e elevada razão Th/Yb Estes padrões refletem, provavelmente, magma derivado de uma fonte mantélica litosférica, que foi modificada por fluídos e sedimentos da zona de subducção.     

城乡劳动力的转移与城市化

本文从城市化基本定义出发,探讨了劳动力在农村与城市两大经济载体之间流动的机制,指出农业容纳力与排斥力、城市吸引力与吸收力是劳动力流动的决定因素,并在对四个因素进行相互关系分析的基础上,阐明了均衡与非均衡条件下劳动力转移的不同途径。     

TRMM卫星降水反演数据在珠江流域的适用性研究——以东江和北江为例

为评估最新一代TRMM 3B42-V7卫星降水反演数据产品在珠江流域的精度和适用性,选取位于珠江流域下游的东江和北江流域为研究区域,基于地面雨量站点数据评估了该产品的精度和适用性,并结合可变下渗容量（Variable Infiltration Capacity,VIC）水文模型进行了水文模拟验证。对比分析结果表明,在网格尺度上,大多数网格日尺度相关系数达到0.60以上,月尺度相关系数达到0.90以上,3B42-V7产品表现出较好的精度,在区域尺度上精度得到了进一步提高;水文模拟验证分两种情景下进行,情景Ⅰ的结果表明,当水文模型由地面雨量站点数据率定时,3B42-V7产品数据的水文模拟效果不佳,个别区间内存在对洪峰流量明显的低估;情景Ⅱ的结果表明,由3B42-V7产品数据重新率定水文模型时径流模拟效果有了较大改善,说明该产品可在一定程度上作为资料缺乏地区的降水数据来源。     

基于à trous小波变换的Landsat 7 ETM＋图像融合研究

 以胶州湾及周边海岸带为研究区，采用Landsat 7 ETM+数据，提出一种基于à trous小波变换的全色图像和多光谱图像融合改进算法。对全色图像和多光谱图像进行适当层数的小波分解，多光谱图像的低频部分采用全色图像和其低频分量的比来调制； 最高分解层外的其余分解层采用多光谱图像和全色图像在该层分解系数的加权和，加权系数由局部区域能量比来确定； 最高分解层则采用绝对值最大准则。实验表明，该方法得到的图像可提高空间分辨率，对多光谱图像的光谱信息扭曲也较小，为提高海岸带地物分类和信息提取精度奠定了基础。     

丽江7.0级地震地下流体异常特征

通过对１９９６年２月３日云南丽江Ｍｓ７．０地震前震中周围水位、水氡、水汞、泉点宏观等地下流体共７１个台项观测资料的异常及综合特征分析，初步认为震前异常数量较多，异常时间分布具有整体性、同步性、集中性的特点，但异常主要集中在短期阶段，临震异常不突出；突间分布具有集中性和非均匀性，孕震区至远场影响区的异常比例最高，震源区内为相对“盲区”，且突出而肯定的宏观异常极少；异常的时空演变特征复杂，总体没有规律     

Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.     

The eastern continuation of the Cadomian orogen: U–Pb zircon evidence from Saxo-Thuringian granitoids in south-western Poland and the northern Czech Republic

We report U–Pb single zircon ages from three pre-Variscan granitoids in the NE part of the Bohemian Massif. The Platerówka granodiorite from the Lausitz-Izera Unit, the Polish Sudetes, has been dated at 533±9 Ma. The Bitouchov granite form the SW part of the South Krkonoe Unit, the Czech Sudetes, gave an age of 540+11/–10 Ma, and the Wdroe granodiorite in the Fore-Sudetic Block yielded 548±9 Ma. All these latest Vendian/Early Cambrian granitoids represent the post-tectonic expression of a late Proterozoic Cadomian orogenic cycle and demonstrate the eastward extent of the Cadomian basement into the Variscan orogen. Granodiorites of similar age have so far been reported from Brittany and especially from the Saxo-Thuringian Terrane to the NE and SW of the Elbe Fault Zone. We conclude that the Saxo-Thuringian Terrane extends across the Elbe and Sudetic Marginal Fault Zones into the Fore-Sudetic Block.     

新疆511铀矿床7号采区U-Se-Re-Mo等元素分布特点

Re、Se是中国急需的紧缺矿种,对国家的资源战略与环境安全保障具有重要影响。新疆伊犁盆地511矿床在开采铀的过程中,发现了Re、Se和Mo等元素存在富集的现象。文章以511矿床7号采区为例,采取野外地质调查与室内分析测试及综合研究相结合的技术路线,以探求Re、Se、Mo等元素的分布特点及其与U元素富集之间的关系。研究表明,Re和Se在空间上与砂岩铀矿体密切共生,说明在511矿床中矿源等条件具备的情况下,7号采区内的层间氧化作用促使Re和Se富集成矿,证实了511铀矿床中与U密切相关的Se、Re等元素具有线状分布的特点。