Variations in dissolved CO2 and CH4 in a first‐order stream and catchment: an investigation of soil–stream linkages

Spatial and seasonal variations in CO₂ and CH₄ concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO₂ concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO₂ concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l^?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO₂ were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO₂ concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO₂ concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO₂. Streamwater CH₄ concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l^?1) than those of CO₂ and showed no seasonal variation, nor any relationship with soil atmospheric CH₄ concentrations. However, stream CH₄ was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO₂ can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.     

2-D or 3-D interpretation of conductivity anomalies: example of the Rhine-Graben conductivity anomaly

Summary. Evidence of a conductivity anomaly in the Rhine-Graben was first given about 15 years ago and consequently led to the definition of various models of induction in the region for periods ranging from a few minutes to a few hours. These models reflect two antagonistic ways of explaining the observed anomalous variations of the magnetic field: direct induction in a two-dimensional (2-D) structure or static distortion of telluric currents by the resistive crystalline Vosges (France) and Schwarzwalde (Germany) massifs. We discuss the two approaches using a simple formalism. In particular, we show that the self-induction related to the anomalous currents flowing in the Rhine-Graben is negligible for periods larger than 1000 s, and that, even though the static distortion of telluric currents does account for the observed anomaly, 2-D models can explain some of its features. We also show how the channelled currents are induced in the large sedimentary basins surrounding the area under study.
An experimental verification of this result is given.     

Observations of the OH Radical in Comet C/1995 O1 (Hale-Bopp) with the Nançay Radio Telescope

We present OH 18-cm observations of comet Hale-Bopp (C/1995 O1) at the Nançay radio telescope. On nucleus and offset position observations allowed us to obtain both OH production rates and quenching radii. The maximum OH production rate was reached around perihelion, at about10³¹ s^-1.     

A magnetostratigraphic comparison between 14C years and varve years during the Late Weichselian,indicating significant differences between the time-scales

A ¹⁴C-dated magnetostratigraphy of absolute declination and inclination between 12500 and 10000 ¹⁴C yr BP was recently developed for southern Sweden. Recently also the Swedish geochronological time-scale, based on c. 11 500 annually deposited clay-varves, was connected with the present. It should therefore be possible to compare the two chronologies with a reliable magnetostratigraphic record in an appropriate clay-varve section. We have found such a site within the Middle Swedish end-moraine zone. Statistical correlations between the two independently dated time-scales suggest that at 10500–10200 ¹⁴Cy r BP the varve chronology exceeds the ¹⁴C chronology by the order of 500-600 varve yr. Other correlations indicate that the difference between the two chronologies was less at 11000 ¹⁴C yr BP, and further correlations between the time-scales at 12000 ¹⁴C yr BP suggest that the difference between the chronologies increased steadily from 12000 to 10000 ¹⁴C yr BP. If these correlations are correct they imply that the ¹⁴C production rate increased steadily during the Late Weichselian.     

Models of the formation of the solar nebula

Models of the collapse of a protostellar cloud and the formation of the solar nebula reveal that the size of the nebula produced will be the larger of $\text{R}{}_{\mathrm{<mtext>CF</mtext>}}\text{≡ J}{}^2\text{/k}{}^2\text{GM}{}^3\text{and}\text{R}{}_{\mathrm{<mtext>V</mtext>}}\text{≡ (GMv/2c}{}_{\mathrm{<mtext>c</mtext>}}{}^3\text{)}\text{1}\text{2}$ (where J, M, and c_s are the total angular momentum, total mass, and sound speed of the protosetellar material; G is the gravitational constant; k is a number of order unity; and v is the effective viscosity in the nebula). From this result it can be deduced that low-mass nebulas are produced if P ≡ (R_V/R_CF)² ? 1; “massive” nebulas result if P ? 1. Gravitational instabilities are expected to be important for the evolution of P ? 1 nebulas. The value of J distinguishes most current models of the solar nebula, since P ∝ J^?4. Analytic expressions for the surface density, nebular mass flux, and photospheric temperature distributions during the formation stage are presented for some simple models that illustrate the general properties of growing protostellar disks. It does not yet seem possible to rule out either P ? 1 or P < 1 for the solar nebula, but observed or possible heterogeneities in composition and angular-momentum orientation favor P < 1 models.     

Toxic effects of Zn2+, Cu2+, Cd2+ and NH3 on Chinese prawn

This study deals with the toxic effects of Zn²⁺, Cu²⁺, Cd²⁺ and NH₃ on Chinese prawn (Penaeus orientalis). The median lethal concentrations of the toxic matters on Chinese prawn were determined. Cd²⁺>Cu²⁺>Zn²⁺>NH₃-Nm is the toxic order of these chemicals to Chinese prawn. The toxic order of concentrated Zn²⁺ and Cd²⁺ in tissues and organs of Chinese prawn is in the order. gill>shell+appendage>viscera>muscle.     

Generalized Born scattering of elastic waves in 3-D media

It is well known that when a seismic wave propagates through an elastic medium with gradients in the parameters which describe it (e.g. slowness and density), energy is scattered from the incident wave generating low-frequency partial reflections. Many approximate solutions to the wave equation, e.g. geometrical ray theory (GRT), Maslov theory and Gaussian beams, do not model these signals. The problem of describing partial reflections in 1-D media has been extensively studied in the seismic literature and considerable progress has been made using iterative techniques based on WKBJ, Airy or Langer type ansätze. In this paper we derive a first-order scattering formalism to describe partial reflections in 3-D media. The correction term describing the scattered energy is developed as a volume integral over terms dependent upon the first spatial derivatives (gradients) of the parameters describing the medium and the solution. The relationship we derive could, in principle, be used as the basis for an iterative scheme but the computational expense, particularly for elastic media, will usually prohibit this approach. The result we obtain is closely related to the usual Born approximation, but differs in that the scattering term is not derived from a perturbation to a background model, but rather from the error in an approximate Green's function. We examine analytically the relationship between the results produced by the new formalism and the usual Born approximation for a medium which has no long-wavelength heterogeneities. We show that in such a case the two methods agree approximately as expected, but that in a media with heterogeneities of all wavelengths the new gradient scattering formalism is superior. We establish analytically the connection between the formalism developed here and the iterative approach based on the WKBJ solution which has been used previously in 1-D media. Numerical examples are shown to illustrate the examples discussed.     

THE DIVERGENCE-CONVERGENCE EFFECT OF SURFACE CURRENT AND ITS ACTION ON THE BOHAI SEA

The action of the wind field and the influence of topography can cause divergence or convergence of surface current. The existence of the divergence-convergence effect is proved and the dynamical significance of the divergent or convergent state and its link with many marine phenomena are pointed out. Divergence fields of surface current in the Bohai Sea in winter and summer are obtained by numerical modelling describing the divergence-convergence character of seasonally wind-driven current. The relation between the effect and seasonal marine phenomena is discussed. Study on the divergence-convergence effect of surface current (DCESC)can be an indirect method for testing the calculated results.