REE, Mn, Fe, Mg and C, O Isotopic Geochemistry of Calcites from Furong Tin Deposit, South China: Evidence for the Genesis of the Hydrothermal Ore-forming Fluids

The Furong tin deposit in the central Nanling region, South China, consists of three main types of mineralization ores, i.e. skarn-, altered granite- and greisen-type ores, hosted in Carboniferous and Permian strata and Mesozoic granitic intrusions. Calcite is the dominant gangue mineral intergrown with ore bodies in the orefield. We have carried out REE, Mn, Fe, and Mg geochemical and C, and O isotopic studies on calcites to constrain the source and evolution of the ore-forming fluids. The calcites from the Furong deposit exhibit middle negative Eu anomaly (Eu/Eu*= 0.311–0.921), except for one which has an Eu/Eu* of 1.10, with the total REE content of 5.49–133 ppm. The results show that the calcites are characterized by two types of REE distribution patterns: a LREE-enriched pattern and a flat REE pattern. The LREE-enriched pattern of calcites accompanying greisen-type ore and skarn-type ore are similar to those of Qitianling granite. The REE, Mn, Fe, and Mg abundances of calcites exhibit a decreasing tendency from granite rock mass to wall rock, i.e. these abundances of calcites associated with altered granite-type and greisen-type ores are higher than those associated with skarn-type ores. The calcites from primary ores in the Furong deposit show large variation in carbon and oxygen isotopic compositions. The δ¹³C and δ¹⁸O of calcites are −0.4 to −12.7‰ and 2.8 to 16.4‰, respectively, and mainly fall within the range between mantle or magmatic carbon and marine carbonate. The calcites from greisen and altered granite ores in the Furong deposit display a negative correlation in the diagram of δ¹³C versus δ¹⁸O, probably owing to the CO₂-degassing of the ore-forming fluids. From the intrusion to wall-rock, the calcites display an increasing tendency with respect to δ¹³C values. This implies that the carbon isotopic compositions of the ore-bearing fluids have progressively changed from domination by magmatic carbon to sedimentary carbonate carbon. In combination with other geological and geochemical data, we suggest that the ore-forming fluids represent magmatic origin. We believe that the fluids exsolved from fractionation of the granitic magma, accompanying magmatism of the Qitianling granite complex, were involved in the mineralization of the Furong tin polymetallic deposit.     

综合物探技术在煤系上覆薄硬岩矿区的应用初探——以山西潞安集团司马矿区为例

山西潞安集团司马矿区东高西低,西部延至长治盆地,矿区水系发育。主采3#煤层埋藏较浅,层位稳定。新生界不整合于下伏基岩之上,厚度变化较大,属典型的薄硬岩煤矿区。为准确提供矿区煤炭开采上限的地质依据,采用了综合勘探技术,其中利用三维地震勘探技术追踪新生界底面反射波及第四系"天窗"位置,利用直流电法与瞬变电磁法提供电性分层,并对其解释结果进行相互印证。勘探实例表明,三维地震勘探、电法勘探与钻探的综合运用不仅可解决薄硬岩煤矿区新生界厚度、含水层富水性及第四系缺失等问题,还可提供新生界含水层与基岩含水层之间的水力联系、制约因素等资料。     

相干体技术在煤矿断层及陷落柱精细解释中的应用

根据相干体技术原理和主要参数选取原则,对五阳矿区进行了以断层和陷落柱为主要研究对象的解释工作。应用实例表明：相干体技术可有效解决本区断层断点较多、切割关系复杂、空间展布规律难以把握和常规解释误差较大等问题;同时,对不规则环状相邻陷落柱的边界及直径较小的陷落柱都有十分灵敏的反映,特别是对较大断层附近的微小构造也可作出较为可靠的解释。     

煤炭地下气化区高密度三维地震勘探技术研究

地下煤层气化的燃烧范围,气化燃烧热力影响边界、形态、方向,气化区冒落带的发展高度及气化煤层裂隙发育程度,是开展煤炭地下气化工程迫切需要解决的问题。基于煤炭地下气化工程试验区地震地质情况,从地震响应入手,在分析煤炭地下气化后地震波场响应特征的基础上,提出了运用高密度三维地震采集技术结合全三维地震属性解释技术,高精度识别煤炭地下气化燃烧范围、气化热力影响边界的方法。实际勘探成果表明,本方法地震成像清晰,预测精度高,与钻探结果吻合较好。     

高密度三维地震技术在潞安矿区高河煤矿的应用效果

对潞安矿区高河煤矿进行了高密度三维地震勘探试验,通过实验获得区内合理的采集参数,并在处理和解释中采用了多项关键技术,如分频剩余静校正迭代技术、叠前时间偏移技术、正演模型技术、三维可视化技术、属性体切片和彩色剖面联合技术等。高密度三维地震勘探解释结果与常规三维地震勘探解释结果的对比表明,高密度三维地震能够提高构造成像准确度和精度,避免误判,还可以提高下组煤层反射波的能量和连续性,是进一步提高潞安矿区三维地震勘探精度的有效技术手段。     

FY-3D卫星MWHS-2辐射率资料直接同化对台风“米娜”预报的影响*

文章基于天气研究和预报(weather research and forecasting, WRF)模式中的FY-3D卫星微波湿度计Ⅱ(micro-wave humidity sounder 2, MWHS-2)辐射率资料的直接同化模块, 采用三维变分(three dimensional variation, 3DVar)方法在晴空条件下同化MWHS-2辐射率资料, 考察MWHS-2辐射率资料同化对台风“米娜”(2019)预报的影响。文中设计了4组试验, 第一组试验不同化任何资料, 第二组试验同化了单独的全球通信系统(global telecommunications system, GTS)常规资料, 第三组试验联合同化了GTS常规资料和MWHS-2辐射率资料, 第四组试验将MWHS-2辐射率资料换成先进技术微波探测计(advanced technology microwave sounder, ATMS)辐射率资料同化。研究结果表明: 偏差订正后各通道观测和背景场差值的均值趋于0, 同化后分析场相对观测的标准差与均方根误差较背景场显著减小, 同化过程是有效的。与仅同化GTS常规资料和同化ATMS资料的试验相比, 同化晴空MWHS-2辐射率资料后的增量场在台风中心附近有负的高度增量和正的温度增量, 从动力与热力上有助于台风的维持。在确定性预报最后的12h, 同化晴空MWHS-2辐射率资料的试验能够改进500hPa环流形势的模拟, 加强西南方向引导气流的强度, 从而最终减小台风路径预报的误差。     

闽江口外海域MIS 5和MIS 3的地震地层学特征和古环境

通过闽江口外海域进行的高分辨率浅地震剖面(拖筏)调查,揭示了MIS 6末期以来最大厚度约90 m的沉积地层。研究了MIS 5和MIS 3地震层序的反射波结构特征,基于地震相分析识别沉积地貌类型;结合深海氧同位素海平面变化曲线,阐述了两时期研究区的沉积环境、特殊地貌的分布和体系域阶段;最后简要探讨了海侵视强度(视高度)及其影响因素。在MIS 5,研究区主要为滨浅海环境,在MIS 5.3和MIS 5.1局部发育了赛江水下三角洲、潮流沙脊和滨海沙坝等沉积地貌;在初期和低海面亚期为陆相环境,发育了闽江和赛江河道,分别经南部和东北部向东入海(台湾海峡)。在MIS 3,研究区普遍为海水覆盖,以滨浅海环境为主,局部发育闽江水下三角洲叶瓣和潮流沙脊。MIS 5的海平面远高于MIS 3,但是典型地震剖面的研究表明,前者的海侵视强度(视高度)低于后者,推断这一现象主要与构造沉降有关,沉积物压缩也有一定的影响,这也可以解释南部海区MIS 5.2的古闽江河道要远低于当时海平面的现象。     

‘Born to Run’: Remembering C.P. Pow

C.P. Pow was my confidant, colleague and (occasional) collaborator for more than 20 years. He had fought a valiant and dignified battle with an aggressive cancer but ultimately succumbed to it in July 2021. I will reminisce a few of the little known traits of Pow which had shaped him to become the conscientious, obliging and humble academic that he was known for.     

新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

3 D inversion of borehole gravity data using cokriging

Borehole gravity has been used in mineral exPloration recently with the advent of slim-hole gravime-ters. It is logical to Perform inversion to utilize the information in the newly acquired data. The i...