Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

康定片麻岩岩石化学特征的初步研究

川西地区康定片麻岩(原称澄江—晋宁期岩浆岩第Ⅳ期的酸性岩)的主体是富钠质的英云闪长质-奥长花岗质片麻岩(灰色片麻岩);尚有少量花岗质片麻岩,系灰色片麻岩遭受钾质交代而成。其岩石化学特征与太古代花岗地体一致.灰色片麻岩属低铝型,以相对富铁和不具Eu异常为特征。它与川滇交界区晚太古代垭口片麻岩等一起构成川西滇中地区的片麻岩基底.     

New Investigation on the Space Group of Chevkinite

Chevkinite specimen from a rare-earth mineral deposit in Sichuan,southwest ofChina have been studied in detail by means of transmission electron microscope(TEM).The selected area electron diffraction(SAED)and convergent beam electron diffraction(CBED)patterns,obtained from different crystal zone axis direction,proved coineidently that the space group of chevkinite is C2/m.Fringe lattice image obser-vation showed the mineral crystal is structurally uniform in microscale,and it is anideal specimen for electron diffraction analysis.The mineral studied here is similar to theone from Bayan Obo,Inner Mongolia,China,in chemical composition and REE distri-bution.The chemical formula of the crystal is(Ce,La,…,Ca)_4 Fe~2-(Fe,Ti,Nb)_2O_8 (Si_2O_7)_2 .From our study,we come to the conclusion that the space group of the natu-ral chevkinite is C2/m,instead of P2_1/a as synthetic one.Up to now,chevkinitecompositionally similar to the synthetic one,in which the complete replacements of Ce,La by Nd and Fe by Mg or Co o     

中国西部三维速度结构及其各向异性

本文用覆盖中国的358条勒夫面波路径资料,研究了10.45-113.80s范围内中国西部的三维SH波速度结构.结果表明,各构造单元的SH波速度结构均有明显的差别.作为稳定块体的塔里木盆地,壳内重力分异程度较高,上、中、下地壳厚度差别小,壳内无明显的低速层,地壳平均速度比较小;上地幔低速层埋深大且层中速度大;区内横向变化小.构造活动区如天山、青藏高原,其突出的特征是下地壳厚度大且速度大,上地幔盖层速度值相当高.这与西伯利亚、印支板块的挤压有密切的关系.青藏高原东部及其北、东边缘地区壳内存在低速层,上地幔低速层埋深浅,一些地区存在壳幔过渡层.面波各向异性研究表明,青藏高原、天山及印支板块北缘下存在明显的各向异性,以构造边缘地区及上地幔低速层附近最为突出.印度板块、西伯利亚板块与中国大陆间的碰撞引起强大的水平压力和一定的下插作用,是造成青藏高原隆起、地壳增厚、天山隆起的最根本的因素,同时也促成壳幔中辉石、橄榄石的定向排列和物质运移,因而出现明显的各向异性现象.     

银催化HDEA电化学发光法测定矿样中的痕量银

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。     

高岭石的结晶有序度及其对纸张涂布粘浓度的影响

粘浓度是纸张涂布的一项重要指标,测定的变化范围从46.4—72％。用Hinckley方法测定了高岭石的结晶度指数,从0.57变化至1.40。当粘浓度>67％时,结晶度指数>1。粘浓度<67％,结晶度指数<1,有序高岭石有利于粘浓度提高。随着结构无序化,晶粒变小,晶片变薄,比表面增加,晶体边缘和角易破损,使粘浓度降低。结构无序化破坏了颗粒的均匀性,使颗粒长/厚比增加,粘浓度降低。高岭石八面体中Fe~(3+)的存在一定程度上影响了有序度。     

延庆、怀来地区地壳深部磁性构造与地震的研究

应用三维磁性层反演理论和方法，对延庆、怀来地区航磁资料进行了数据处理，反演计算了该区磁性基底埋深、居里等温面埋深和视磁化强度分布。揭示了延庆盆地、矾山盆地、怀来盆地、涿鹿盆地等四个相互联通盆地的磁性基底的定量特征。对该区地震发生的深部原因和地壳内不同特性块体与地震的关系进行了探讨；对该区地震分布的特点进行了研究；初步提出了该区地震的危险区划和今后的重点监测区。     

独山子地区荒漠土的￣（14）C年龄测定及意义

通过对独山子地区荒漠土碳酸盐淀积层的￣１４Ｃ年龄测定，探讨了碳酸盐淀积层碳的来源及其￣１４Ｃ年龄的可靠性问题。提出了根据碳酸盐淀积层的无机碳年龄，对确定土壤的年龄是有意义的     

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.     

利用Radon变换进行三度体重磁异常反演

从Ｒａｄｏｎ变换角度分析解释了重磁三度体异常和二度体异常之间的等价关系，提出了利用Ｒａｄｏｎ正变换将三度体异常转化为二度体异常，对二度体异常做一维反演，然后将反演结果通过反Ｒａｄｏｎ变换实现三维场源图象重建的思想，并付诸实施，在微机上通过模型检验，证明该方法实用、可行。