The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.     

Microbial production of CO2 in red soil in Stone Forest National Park

Lunan stone forest is a kind of typical karst in China, which is mainly developed under red soil. In the winter of 1999, three study sites were chosen in stone forest national park according to vegetation cover, geomorphologic location and soil types. CO2 concentration was measured with Gastec pump at different depths of soil (20, 40, 60 cm) and at the same time soil samples were gathered and soil properties such as soil moisture, pH, soil organic content were analyzed and the total number of viable microbes were counted in laboratory. In the study, dependent variable was chosen as the mean soil log (PCO2), and soil properties were chosen as the independent variables. Multiple stepwise regression analysis showed that the total amount of microbes and soil moisture are the best indicators of the CO2 production, with the equation LOG(PCO2) = - 0.039(TNM) - 0.056(Mo) + 1.215 accounting for 86% of the variation of the soil CO2 concentration, where TNM is the total number of microbes in the soil and Mo is the moisture of soil sample.     

不同浓度Li2SO4水溶液结构的X射线衍射研究

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。     

光催化氧化法处理难降解废水的研究进展

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。     

陕北新庄地区延长组长2油层组储层特征

一般河道砂体的正粒序性决定了其下部物性条件优于上部，但新庄地区长2油层组河道砂体的物性特征截然相反，而是中上部物性条件好，下部物性条件普遍差。在储层岩石学特征、孔隙类型等研究的基础上，对此进行了探讨，认为造成其特殊性的原因主要是由于压实、胶结、次生加大等作用。指出河道边滩砂体中上部储层为该区的主力储层。     

利用高铁钾长石粉合成13X沸石分子筛的实验研究

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。     

A comparison of the evolution of diamondiferous quartz-rich rocks from the Saxonian Erzgebirge and the Kokchetav Massif: are so-called diamondiferous gneisses magmatic rocks?

The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.     

深圳市东湖矿泉水形成机理探讨

深圳市东湖矿泉水是自然界十分稀少的锶—锌—偏硅酸碳酸复合型矿泉水，通过对矿泉水赋存地的地质与水文地质条件的分析，并结合其水文地球化学特征，认为东湖矿泉水形成的主要控制性因素是构造作用和变质作用；在特定的水文地质条件下，深部碳酸盐类岩石受热硅化变质而产生大量CO2气体，使得各种化学元素在含有大量CO2的地下水的溶滤作用下不断迁移和富集而形成该区地下水中良好的元素组合。在其特征成分中，偏硅酸来自裂隙渗透水的溶滤和岩浆期后热液水的作用，微量元素锶主要来源于钾长石、钙长石，锌则主要来自岩浆活动以及岩脉中的黑云母、角闪石、辉石等铁镁硅酸盐矿物；并认为目前矿泉水含水层仍处于良好的地质环境保护下。     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).