Geological Relationships Between the Intrusions,Country Rocks,and Ni-Cu-PGE Sulfides of the Kharaelakh Intrusion,Noril′sk Region:Implications for the Roles of Sulfide Differentiation and Metasomatism in Their Genesis

The Ni-Cu-platinum group element sulfide ore deposits of the Kharaelakh Intrusion,Noril′sk Region,Siberia,represent a large concentration of sulfides associated with a small differentiated intrusion formed at the edge of the Siberian Craton in the roots of the Siberian Trap flood basalt.The deposit is associated with an intrusion that occupies a flanking periclinal structure adjacent to the Noril′sk-Kharaelakh Fault.The intrusion is strongly differentiated and comprises taxitic gabbrodolerites,picritic gabbrodolerites,and gabbrodolerites within the main body which in turn forms a chonolith within a sheet-like intrusion that extends laterally to form extensive undifferentiated sills of gabbrodolerite.The intrusion substantially replaces the stratigraphy of the country rocks,and although it appears to have exploited the axis of structures developed in response to transtension,the intrusion has created space by both mechanical dilation of stratigraphy and magmatic replacement of pre-existing sedimentary rocks.The frontal lobes of the main intrusion have complex apophyses of gabrodolerite on a range of scales that demonstrate replacement of the sedimentary rocks and link to the development of an extensive metamorphic halo in the country rocks.This halo is much narrower over the main body of the intrusion,and these observations have implications for the thermal history of the intrusion.Mg-skarns and breccias are developed in the roof of the main body of the intrusion.Within the intrusion,the taxitic rocks contain vesicles and the blebby sulfides developed in the picritic and taxitic gabbrodolerites appear to have a linkage to volatile phases.Cuprous sulfide mineralization developed at the roof of the Kharaelakh Intrusion is associated with metamorphosed and skarn-bearing country rocks,and appears to have been generated by a combination of sulfide fractionation and associated metasomatism.The geological relationships appear consistent with a chonolith model for the development of the differentiated intrusion and mineralization,but the extent of metasmorphism of the country rocks appears to be related to the unusual thickness of gabbrodolerite apophyses at the flanks of the intrusion rather than metamorphism produced by the passage of mafic magma through the intrusion.Variations in disseminated sulfide compositions and metasomatic textures in the skarns are described,and a model is proposed which balances traditional views on the evolution of the magma conduits with the impact of magmatic fluids transported through the magma column(i.e.transmagmatic fluids).The importance of structures in controlling the nature of the conduit,and the resultant small intrusions with excess sulfide is a feature of many other Ni-Cu sulfide deposits including Voisey′s Bay,and it is suggested that the sulfides are more likely to have beentransported from depth into their final resting place rather than developed by in-situ equilibration of sulfide with fresh magma in the chonolith.     

铂族元素的表生地球化学研究进展

基性-超基性岩及黑色页岩等风化过程中铂族元素发生了活化和迁移。铂族元素在岩体附近土壤、植物和水体等表生介质中的迁移富集特征可以用来寻找岩浆型铂族元素矿床。黑色页岩风化过程中，Os的表生迁移对海洋^187Os／^188Os值上升有重要意义。此外，作为重金属元素，机动车铂族元素催化剂在环境中的释放，也会带来潜在的生态环境和人体健康问题。     

新疆磁海铁矿区镁铁-超镁铁岩地球化学特征及其地质意义

磁海铁矿床地处塔里木盆地北缘北山成矿带内, 为一与镁铁-超镁铁岩有关的岩浆分异-矿浆贯入-热液交代型复成因铁矿床。对磁海矿区镁铁-超镁铁岩的岩石学特征和岩石地球化学特征等进行了较为系统的研究, 认为这套镁铁-超镁铁岩石属于铁质钙碱性玄武岩系列。稀土及微量元素特征与原始地幔成分接近,表明岩浆上升侵位过程中局部遭受陆壳混染。结合前人的研究成果, 认为该矿床形成于后碰撞拉张构造环境。原始岩浆的结晶分异和后期热液蚀变对磁海铁矿形成和富集起重要作用。     

河北省邢台将军墓低质超贫铁矿地质特征与开发利用前景

铁矿资源分为富铁、贫铁,随着市场需求增大和资源的枯竭,超贫铁矿将逐渐发展为主要方向,本文就河北省邢台县将军墓一带铁矿地质特征,将其定名为低质超贫铁矿,认为该类型资源在一定条件下具有很好的开发利用前景。     

丁二酸桥联双核铜Cu(C_3N_2H_4)_2(C_4H_5O_4)_2晶体的超分子结构及形貌特征

用XRD,SEM和TEM研究新型配合物Cu(C3N2H4)2(C4H5O4)2的超分子结构和微观形貌,并对新型晶体的平衡外形进行模拟计算,结果表明:该配合物分子具有丁二酸桥联的双核铜结构,中心铜离子处在2个咪唑和4个丁二酸以单齿配位组成的八面体中心,在ab平面,分子中有十四元大环,环内Cu(1)-Cu(2)原子间距为0.8031nm,C(2)-C(2′)为0.4183nm;在ac平面,沿着[010]方向分子内呈现凹的六边形纳米级孔洞;沿[100]方向分子依靠弱的氢键作用,层状堆积成三维超分子结构。此外,随着丁二酸的碳链沿[001]方向无限延伸,形成以铜离子为交叉中心的带状拓扑构型。SEM观察到晶体表面形成有明显的凹坑,区域呈现层状阶梯,说明晶体在(100)面遵照台阶-扭折模型呈层状生长结晶。TEM微区形貌像显示晶体存在条纹和缺陷结构,整体保持柱状构型,这与模拟的晶体平衡外形呈柱状一致。模拟结果表明晶体最易外显晶面为(100)面,外显比例达41.247%,这与晶体超分子层沿[100]方向通过氢键作用堆积,键作用力较弱密切相关。     

水源钻机在超深土层绳索取心钻进中的应用

山西省清徐县区域地质调查项目设计800、2000、3000 m科学钻探孔,以调查填补新生界底板埋深控制空白区,各孔钻入基岩30 m完钻。要求全孔取心,岩心采取率≮85%,岩心直径≮60 mm,采用塑料保护管采取原状岩样。针对超深软土层、各组地层特性及厚度未知、钻遇基岩完钻深度未知、大直径高保真全孔取心、项目价格远低于目前市场成本等难题,经过“水源钻机+大提钻取心+长裸眼孔段”实施800 m孔、“岩心钻机+绳索取心+套管固井”实施640 m参数对比孔,创新性使用“水源钻机+绳索取心+长裸眼孔段”工艺完成了2000 m孔的施工。该工艺岩心采取率达到93%,孔径和孔斜符合地质要求,为3000 m孔顺利施工打下了坚实的基础,为同类型项目提供了经验和借鉴。     

三江南段景洪大勐龙地区基性高压变质岩岩石地球化学特征及其大地构造意义

本文以三江南段景洪大勐龙地区新发现的退变榴辉岩和蓝片岩为研究对象,对其进行了系统的地球化学、原岩性质及锆石U-Pb定年的综合研究.大勐龙地区退变榴辉岩呈透镜状产于白云钠长石英片岩、白云母片岩和斜长角闪(片)岩中,其原岩为亚碱性拉斑玄武岩,球粒陨石标准化稀土元素配分曲线呈轻稀土弱亏损、重稀土平坦型的分布特征,不具有Nb、...     

滇中新元古代裂谷盆地充填序列及演化模式:对Rodinia超大陆裂解的响应

以滇中新元古代裂谷盆地沉积充填为研究对象,开展了系统的沉积学和盆地分析研究。结果表明,滇中新元古代裂谷盆地具有4个充填序列,分别代表盆地的4个发展阶段。其中,序列I为柳坝塘组及陆良组下段,沉积时限为820~800 Ma,属低密度浊流和深水饥饿沉积,代表裂谷盆地的快速沉降阶段;序列II为澄江组、陆良组上段及牛头山组,沉积时限为800~725 Ma,属扇三角洲-湖泊沉积,代表裂谷盆地的成熟发展阶段;序列III为南沱组,沉积时限可能为725~635 Ma,属大陆冰川沉积,代表裂谷盆地开始向被动大陆边缘盆地转换的阶段;序列IV主要为陡山沱组,沉积时限为635~551 Ma,属潮坪沉积,为裂谷盖地层。进一步研究揭示,滇中新元古代裂谷盆地由幼年期分布局限的小型同向半地堑盆地群演化为成熟期统一的大型半地堑盆地,属上叠滑脱盆地。综合研究证实,滇中新元古代裂谷盆地应为陆内裂谷盆地,是Rodinia超大陆裂解的产物。     

三峡大坝下游溶解氧变化特性及影响因素分析

根据三峡工程坝区水域实测数据,分析了水库蓄水以后大坝上、下游断面溶解氧浓度和溶解氧饱和度的变化特性,探讨了水位、流量因素对大坝下游水体溶解氧量的影响。结果表明,坝身孔口过流水体大量掺气后进入下游河道导致下游水体溶解氧浓度和饱和度显著增加,甚至达到超饱和状态。由于电站过流基本不改变水体溶解氧量,在电站和坝身孔口同时过流时,两种水体掺混后,下游溶解氧量主要受流量比的影响。此外,下游溶解氧量随流量的增加和下游水位的升高而增大。过坝总流量超过35 000 m3/s,下游水位超过68 m以及坝身孔口过流流量占总流量的绝大部分时,需特别重视溶解氧超饱和现象对水生生物可能造成的影响。     

滇东寒武系层序地层学特征

介绍了对滇东寒武系进行层序地层学研究所采用的方法、层序的基本特征及取得的主要成果。确定有１０个层序，其时限为１～１０Ｍａ，其中下寒统武有６个，中、上寒武统各２个。此外还划分出次层序２７个、组合层序２个。此项研究工作对本区寒武系地层划分与对比、界线的确定具有重要意义：（１）沧浪铺阶生物地层的争论，是由于滇东存在两个Ⅰ型层序边界，乌龙箐段与红井哨段为假整合关系，故生物带发育不完整；（２）双龙潭组与西王庙组应为同时异相沉积体；（３）双龙潭组顶部时限，以ＳＢ２ｉ为标志，应与娄山关组底部边界对比，故可能上延至晚寒武世早期