广东大宝山南部铅-锌多金属矿床地质特征及找矿方向

大宝山南部铅-锌矿床赋存于大宝山向斜内的中泥盆统东岗岭组下亚组碳酸盐岩地层中,矿床的形成与地层、构造、岩浆活动有关,通过对该矿床成矿特征及控矿因素的分析,对比矿区外围凉桥—新江、官坪—大镇两个有利成矿远景区的成矿地质条件,研究认为,这两个远景区的成矿地质条件与大宝山南部铅-锌金属矿床基本类似,在矿区外围多个矿化集中区中,最具找矿潜力。     

Comparison of components and distribution of heavy metals in sediments, suspended particulate matter and surface coatings in natural waters

Solid phases, such as surface coatings （SC）, suspended particulate matter （SPM） and deposited sediments （DS）, contribute to the pool of heavy metals in natural waters. Their existing and forming conditions lead to potential differences in enrichment capacity of pollutants, chemical compositions and crystals. In this study, the contents of heavy metals in SC, SPM and DS were determined by GF-AAS after digestion with a mixture of concentrated HNO3 and HClO4. The selective extraction method was employed to remove Fe, Mn oxides and organic matters and associated heavy metals （Cu, Pb, Zn）. X-ray diffraction analyses were performed to characterize the crystals in the samples. The results showed that no significant difference in the contents of Fe-oxides in DS, SPM and SC was found, but the contents of Mn-oxides and organic matter follow the order of SC〉SPM〉DS. The significant crystal characters were observed in DS, SPM and SC, and the kinds of minerals and crystallization degree follow the order of DS〉SC〉SPM. In addition, quartz was the most important matter of crystals in the solid phases. Enrichment capacity follows the order of SPM〉SC〉DS for Pb, Cu and Zn. Organic matter was the major sorbent for Cu, and Mn oxides and organic matter played an important role in the enrichment of Zn. However, Pb was absorbed mainly by Fe oxides. Moreover, compared with Fe oxides and organic matter, Mn oxides had a great enrichment capacity for these metals. Although DS, SPM and SC were formed in the same water system, contents of chemical components, crystals and enrichment capacities to heavy metals were obviously different.     

Environmental investigation for causality and remediation of cadmium contaminated soils in Tak Province, Thailand

Highly elevated cadmium concentrations in paddy soil in the Mae Sod District, Tak Province, Thailand, was detected and widely reported in 2003. This emergence provoked public interest and demands for responsibility and remedial actions. As zinc mines and concentrator were located in the upstream area, mining activities were proclaimed a contamination source. Department of Primary Industries and Mines （DPIM）, a governmental organization responsible for mining and mineral processing, was thus challenged to verify the reliability of post monitoring data displaying consistently low heavy metal concentrations in compliance with the standard limits for over 15 years. Detailed survey and deep-going research on the causes, boundary and severity of cadmium contamination as well as the environmental impact alleviation were consequently conducted. Environmental samples were accumulated systematically for 2 years throughout the areas of upstream and downstream mining sites. A total of 259 soil samples from 53 spots at the depths of 0-20, 20-40, 40-60 and 60-200 cm were drilled with hand auger. Samples of water, stream sediment and mine tailing were also collected. Chemical analysis for cadmium （Cd）, zinc （Zn） and lead （Pb） concentrations with AAS and ICP were undertaken. The contaminated area was finally defined to spread over approximately 18 square kilometer mainly of mountainous mineralizing land and colluvium.     

Effect of oxidation potential and zinc sulphate on the separation of chalcopyrite from pyrite

The effects of oxidation potential (Eh) and zinc sulphate on the separation of chalcopyrite from pyrite were investigated at pH 9.0. The flotation recovery of these minerals is Eh dependent with maximum separation obtained at 275 mV SHE. Zinc sulphate addition improved this mineral separation at an Eh value of 275 mV by selectively depressing pyrite flotation. A different result was obtained at lower Eh values where zinc sulphate addition improved chalcopyrite flotation but had no or little effect on pyrite flotation. These opposite effects of zinc sulphate on mineral flotation were reconciled by examining the surface species of these minerals. The selective depression of pyrite flotation by zinc sulphate was also confirmed in the flotation of two copper ores.     

Investigation of lead and zinc dispersion from an abandoned mine site at Tyndrum, Scotland, using tree bark measurements

Tyndrum was an industrial mining area from 1741 until the 1920s where the main ores extracted were lead sulphide （galena） and zinc sulphide （sphalarite）. Situated in central Scotland, the now deserted site is identified as a highly polluted, barren area where the original waste residues from the mine, an ore processing and a smelting site are clearly evident. Previous studies have suggested that high levels of lead and zinc contaminants are still dispersed from this former mine site, both atmospherically and through fluvial transport. For example, high concentrations of Pb, identified by its isotopic signature as originating in Tyndrum, have been found in sediments in Loch Tay, 25 km east of this area. This paper presents the results of a study of the occurrence and magnitude of airborne contamination by dispersion from the former mine site using measurements of metal concentrations in tree bark. These naturally occurring ‘bio monitors＇, which accumulate airborne materials including heavy metals, have become an effective alternative to the more costly air-filter system, which is restricted in scope and coverage. Bark samples were acquired from Scots pine （Pinus sylvestris） trees, which are abundant around the derelict mine site. Suitable locations were chosen to investigate atmospheric transport and deposition of contaminants within the area.     

碳酸钙共沉淀-火焰原子吸收光谱法测定卤水中痕量铜铅锌

以碳酸钙共沉淀卤水中的痕量Cu、Pb、Zn，用火焰原子吸收光谱法测定。对试剂的加入量、富集时间、酸度等影响因素进行了实验，选择了最佳的共沉淀条件。方法已用于卤水分析，加标回收率为Cu94．0％～97．6％、Pb94．0％。102％、Zn93．4％-102％。对卤水样品6次测定的相对标准偏差为Cu0．49％、Pb0．79％、Zn1．85％。     

阿尔金山东段山前砾石钙膜累积速率及其在估算断层活动年代方面的应用

干旱－半干旱地区冲洪积物顶面土壤中发育的砾石钙膜含有明显的年龄信息,其工及由统计计算得到的累积速率可用来估算所在冲洪积物或土壤的形成年代。     

Petrochemistry of Late Miocene to Quaternary Igneous Rocks and Metallogenesis in Southwest Hokkaido, Japan

Abstract: Southwest Hokkaido is largely covered by Late Miocene to Quaternary igneous rocks, and has a large number of gold veins and base-metal veins of the same age. Investigation of the silica-normalized concentration of elements has revealed regional petrochemical zoning; large ion lithophile elements (LILE) and K₂O/(Na₂O+K₂O) of the rocks increase toward Japan Sea, whereas total FeO, CaO, and ⁸⁷Sr/⁸⁶Sr decrease. Mapped concentration isoplethes of these elements are not ideally parallel to the volcanic front, but protrude to the west at Funka Bay, and to the northwest at Matsumae Peninsula. Isoplethes of ⁸⁷Sr/⁸⁶Sr show similar patterns and two more northwestward protrusions in the northeast (Jozankei block) of southwest Hokkaido. Contrary to the general petrochemical trend, both high– and low-LILE volcanic rocks occur in the Jozankei block. The ore deposits are distributed in four metallogenic zones; manganese–base–metal zone on the Japan Sea side, pyrite-limonite zone mainly along the volcanic front, gold zone in the middle, and two units of gold–base–metal zone. The northern unit of this zone is in the Jozankei block, and seems a part of the gold zone overlapped by the manganese–base–metal zone. Thus, as a rule, pyrite–limonite, gold, and base-metal deposits accompany low–, intermediate–, and high-LILE igneous rocks, respectively. Individual deposits and volcanic rocks make chains oblique to the zones and the volcanic front. The majority of the ore deposits are distributed along ridges of Bouguer anomalies overlapped by the volcanic chains, which apparently control the patterns of the petrochemical isoplethes. This is typical for two volcanic chains to the north and south of Funka Bay, where the petrochemical isoplethes protrude to the west. This indicates that both the igneous activity and the mineralization have been under the control of tectonic fractures at the roots of the volcanic chains. The geological, petrochemical and metallogenic data support the idea that the chemical characteristics of the deposits are correlated mainly with the chemistry of the associated magmas, and partly with that of the host rocks.     

Geochemical demobilization of metallic pollutants in solid waste—implications for arsenic in waterworks sludges

During stabilization or demobilization of contaminants in solid waste materials, different approaches can be taken, which also can be combined: (1) sufficient long-term buffer capacity can be provided, according to the environmental conditions; (2) permeability for dissolved contaminants can be reduced by secondary mineral precipitations or by soft gels injected into the pore space of the waste body; and (3) new formations of ‘reservoir minerals' can incorporate potential pollutants in their internal structure. Emphasizing the geochemical engineering approach, two examples are presented from the field of water management, both focussing on the demobilization of arsenic species. The first example (after Driehaus, W., 1994. Arsenentfernung mit Mangandioxid und Eisenhydroxid in der Trinkwasseraufbereitung. Vol. 133, Ser. 15, VDI-Reports, Düsseldorf, 117 pp.) relates to the problems during purification of arsenic-rich raw water, suggesting the potential application of iron and manganese oxide minerals as oxidizing agents and mineral lattice structures for the elimination of arsenic. In the second example, contaminated sludges from water treatment plants were investigated for their leaching characteristics and long-term stability. A pH-stat test procedure was used to assess the leaching characteristics of metals at typical pH values. Due to the presence of iron and manganese oxides pentavalent arsenic is protected against conversion into the mobile trivalent form at neutral to low pH. Experimental data suggest that co-disposal with reducing organic matter and alkaline stabilization material or wastes could negatively influence the binding properties and, therefore, should be avoided.