含羟基西佛碱型大环冠醚铜(Ⅱ)、锌(Ⅱ)配合物的合成与表征

利用模板法合成 1种新的含醇羟基西佛碱型大环冠醚 L (7,11-二氮杂 - 3,15 -二氧杂 - 4 ,5 ;8,10 ;13,14-三苯并环十六 - 6 ,11-二烯 - 1-醇 )的铜、锌配合物。经元素分析 ,IR、MS分析确定配合物的组成 M(L2 ) (NO3 ) 2 及其配位情况 ,由模板反应得到 [1+ 1]型西佛碱大环化合物。 DMF溶液中的电导数据证实它们均属非电离型 ,并运用 TG- DTA分析比较铜、锌配合物的热稳定性。     

Marine diatom Thalassirosira weissflogii nutrient drawdown and its physiological status variation challenged to zinc and cadmium exposure

The uptake of zinc and cadmium by a species of marine diatom Thalassirosira weissflogii and the nutrient variation (phosphorus and silicon) in the culture medium were estimated when exposed to zinc and cadmium stress under controlled laboratory conditions.It was found that low cadmium addition could stimulate the culture to grow with a relatively high rate and exert its toxicity at the elevated concentration.The cellular uptake of zinc and cadmium by the diatom varied in the ranges of 1.21~3.75 and 0.060~0.629 fmol per cell respectively in the whole cultivation period.The mean cellular phosphorus and silicon drawdowns were constant with 0.26~0.42 and 0.30~0.46 pmol per cell respectively in those healthy cultures.It is illustrated that the algal cells can adjust some physiological mechanisms to decrease metal accumulation and keep metal homeostasis in the organism.The correlation analysis results further indicate that the cellular cadmium uptake might be closely related with the cellular phosphorus, silicon drawdown and the growth rate of diatom (P<0.05, 0.001, 0.01); and the cultures grow better in good conditions, the lower amount of phosphorus, silicon materials are consumed by a single cell to keep a high efficiency of utilization.     

Heavy metal pollution in Wellington Harbour

Heavy metal analysis of the < 20 μm fraction of marine sediments from Wellington Harbour and Waiwhetu Stream have shown that the Waiwhetu Stream is easily the most polluted area in the Wellington Harbour system with Pb and Zn in the extremely polluted category and Cu, Cd, and Hg in the moderately to strongly polluted category. These elements have different distributions in the stream sediments reflecting their different sources from adjacent factories. In Wellington Harbour itself, the central basin of the harbour suffers from minimal pollution. Pb, and to a lesser extent Zn and Cu, are the main pollutants and local enrichment of these elements is noted in Lambton Harbour basin, off Pencarrow and Moa Point outfalls, in Evans Bay, and off Petone and Kaiwharawhara. The geochemical data do not enable us to identify the source of the pollutants unambiguously. A summary of the history of waste discharges into the harbour suggests that heavy metal pollution may have been higher in the past.     

龙门山南段宝兴至荥经地区铅锌矿的成矿条件和成矿模式

通过龙门山南段宝兴至荥经地区区域地质、铅锌矿化特征的研究，划分矿化类型，着重分析区域成矿地质条件，提出“层─盆─破─热”是本区层控型铅锌矿形成的基本因素。总结出铅锌矿在本区形成时间有“三个高峰期”，空间集中于“一带两弧”的时空分布规律。在分析不同矿化类型成矿模式的基础上，建立了区域综合理想成矿模式，为本区找矿靶区和预测区的确定奠定了坚实基础。     

吉尔吉斯斯坦Au、Cu、Pb、Zn、W、Sn矿床潜力评价——基于1∶100万地球化学数据

吉尔吉斯斯坦是中亚天山金属成矿带的重要组成部分,矿产资源丰富,金属矿产种类齐全.吉尔吉斯斯坦国家尺度(1∶100万)地球化学填图覆盖了吉尔吉斯斯坦全境约19万km2,分析测试了69种元素,填补了吉尔吉斯斯坦国家尺度地球化学填图空白,为吉尔吉斯斯坦基础地质、矿产开发、环境保护、农业生产等多个方面研究提供了基础地球化学数据...     

湖南保靖县且溪科铅锌矿地质特征

且溪科铅锌矿位于湖南省保靖县。区内倒转褶皱和断裂构造彼此贯通,形成良好的导矿构造系统,对区内铅锌矿的控制最为明显。铅锌矿体呈似层状形态大致顺层产于寒武系下统清虚洞组灰色中层夹薄层条带状粉—细晶云岩、砾屑白云岩和层间碎裂岩、角砾岩内。矿区铅锌矿床的形成是区域构造、矿区地质构造、沉积建造、热液活动等多种地质作用的综合产物,其中矿区地层岩性与岩相、构造是本矿床成矿控制的主要因素。位于麻栗场断层上盘褶皱构造内的寒武系下统清虚洞组上段白云岩,是该区铅锌矿的主要找矿方向,有希望找到大中型铅锌矿床。     

大深度隐伏多金属矿地气探测试验

以广西大厂矿区内埋深超过800 m的95号锌铜矿体为研究对象,采用快速地气采样装置和ICP-MS分析技术对大深度隐伏多金属矿进行地气测量试验.结果表明,矿体上方Zn、Cu地气异常超过背景值3倍以上,Pb、As、Cd、Bi、Co、Cs、Mo、Rb等也呈现显著异常,证实采用地气测量探测埋深超过800 m的大深度隐伏矿体是完全可行的.     

新疆阿克陶县塔木-卡兰古铅锌矿带矿床地质和硫同位素特征

新疆塔木—卡兰古铅锌矿带位于塔里木板块西南缘之晚古生代碳酸盐台地环境中。矿化以铅锌矿为主 ,个别矿床含铜。矿床赋存于中泥盆统—下石炭统三个控矿的古含水层中 ,矿体形态复杂 ,富矿段往往赋存于多组断裂构造交汇部位。矿石根据其结构大体可分两类 :一类呈角砾状构造 ,硫化物呈浸染状 ,共 (伴 )生赤铁矿和磁铁矿 ;另一类矿石中硫化物以胶状、草莓状结构为主。硫化物硫同位素值具有较宽的范围 ,δ3 4 S为 - 39.2‰～ 14‰ ,主要集中在 - 2 9.3‰～- 17.7‰和 - 3.6‰～ 5 .1‰两个区间 ,分别与上述两类矿石相对应。研究表明 ,位于泥盆系与石炭系间的第二古含水层是最重要的找矿层位 ,角砾岩带是重要的找矿评价标志 ,矿床成因可能属密西西比河谷型 (MVT) ,两种性质差异很大的低温热液混合引起成矿物质的沉淀和成矿     

硫化矿氧化率测定问题的研究：Ⅲ.硫化锌矿中氧化锌的分离测定

研究了络合剂乙二胺作为分离流化锌矿中锌矿物的选择性溶剂的优越性及其具体应用条件。１０％乙二胺－１０％（ＮＨ４）２ＳＯ４溶液于室温下电磁搅拌浸取,氧化锌矿物的浸取率＞９７％,而闪锌矿等在该溶剂体系中溶解率≤０．２％,具有比较高的选择性。方法已用于实际样品分析。     

广西老厂式铅锌矿床成因研究

老厂式铅锌矿是产于泥盆系和寒武系不整合界面之间的脉状中温热液铅锌矿床，受断裂构造控制。成矿物质来源于深部岩浆和基底地层，成矿流体以岩浆水为主，混有部分雨水的混合水。矿床成因属沉积-岩浆热液改造富集矿床。