极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

应力波与可滑移岩石界面间的相互作用研究

研究了应力波与用节理刚度系数描述的线性滑移岩石界面间的相互作用，给出了其透、反射波幅的一般表达式。通过应力波垂直人射界面时的具体分析，反映出岩石界面的节理刚度对应力波传播的重要影响，并揭示了岩石界面对应力波的高频滤波作用。     

Properties of wave velocity for two types of granitoids at high pressure and temperature and their geological meaning

The wave velocity for two types of granitoids was measured using the analytic method of full-wave vibration at high pressure and high temperature. The laws of velocity changes for them differ with the pressure boost and temperature rise, and the velocity change of S-type is more violent than that of I-type. The “softening point” of compressional wave velocity (V μ) is also revealed during the measurement for two types of granitoids imitating the pressure and temperature at a certain depth. But the depth of “softening”, V_p after “softening” and the percentage of V_p’s drop around the “sofrening point” for two types of granitoids are obviously different. The depth of “softening” is 15 km approximately and V_p after “softening” is 5.62 km/s for S-type granitoid. But for I-type granitoid the depth of “softening” is 26 km approximately and V_p after “softening” is 6. 08 km/s. Through careful analysis of rock slices after the experiment, it was found that the “softening” of elastic-wave velocity is caused by the partial melting of granite. Combined with the results of geophysical prospecting, these results suggest that the low-velocity layers developing in the interior of Earth crust are related to thc partial melting of different types of granitoids. The formation of the low-velocity layer in the upper-middle Earth crust is closely related to the development of S-type granitoid, but that in the lower Earth crust is closely related to the development of I-type granitoid.     

Geometric form of Haiyuan fault zone in the crustal interior and dynamics implications

The deep seismic reflection data on profile HY2 are reprocessed by the method of simultaneous inversion of velocity distribution and interface position. By the travel-time inversion with the data of the diving wave Pg and fault plane reflection wave, we determine the geometric form and velocity of Haiyuan fault zone interior and surrounding rock down to 10 km depth. The measured data show that the amplitudes have strong attenuation in the range of stake number 37–39 km, suggesting the fault zone has considerable width in the crustal interior. The results of this paper indicate that to the north of the fault zone the crystalline basement interface upheaves gradually from southwest to northeast and becomes shallow gradually towards northeast, and that to the south of the fault zone, within the basin between Xihua and Nanhua mountains, the folded basement becomes shallow gradually towards southwest. The obliquity of the fault zone is about 70° above the 3 km depth, about 60° in the range of the 3–10 km depths. From the results of this paper and other various citations, we believe that Haiyuan fault zone is in steep state from the Earth’s surface to the depth of 10 km. Foundation item: Joint Seismological Science Foundation of China (201001) and State Key Basic Research Development and Programming Project (95-13-02-02). Contribution No. RCEG200308, Exploration Geophysical Center, China Earthquake Administration.     

Are open fractures necessarily aligned with maximum horizontal stress?

Fluid flow in fractured rock is an increasingly central issue in recovering water and hydrocarbon supplies and geothermal energy, in predicting flow of pollutants underground, in engineering structures, and in understanding large-scale crustal behaviour. Conventional wisdom assumes that fluids prefer to flow along fractures oriented parallel or nearly parallel to modern-day maximum horizontal compressive stress, or S_Hmax. The reasoning is that these fractures have the lowest normal stresses across them and therefore provide the least resistance to flow. For example, this view governs how geophysicists design and interpret seismic experiments to probe fracture fluid pathways in the deep subsurface. Contrary to these widely held views, here we use core, stress measurement, and fluid flow data to show that S_Hmax does not necessarily coincide with the direction of open natural fractures in the subsurface (>3 km depth). Consequently, in situ stress direction cannot be considered to predict or control the direction of maximum permeability in rock. Where effective stress is compressive and fractures are expected to be closed, chemical alteration dictates location of open conduits, either preserving or destroying fracture flow pathways no matter their orientation.     

Green''''s functions for uniformly distributed loads acting on an inclined line in a poroelastic layered site

Based on one type of practical Biot's equation and the dynamic-stiffness matrices of a poroelastic soil layer and half-space, Green's functions were derived for uniformly distributed loads acting on an inclined line in a poroelastic layered site. This analysis overcomes significant problems in wave scattering due to local soil conditions and dynamic soil-structure interaction. The Green's functions can be reduced to the case of an elastic layered site developed by Wolf in 1985. Parametric studies are then carried out through two example problems.     

预测有效波高的深度学习模型研究

研究基于RNN、LSTM、GRU深度学习模型,针对NOAA浮标数据集中的44013、44014、44017浮标的数据,通过斯皮尔曼相关性分析提高模型预测效果。实验结果表明,在进行相关性分析后,S-RNN、S-LSTM、 S-GRU的预测效果均比原始RNN、LSTM、GRU模型预测效果好。此外,提出一种基于LSTM的LSTM-Attention 波高预测模型,并进行相关实验,量化LSTM-Attention模型的预测效果,实验结果表明LSTM-Attention模型有更好的预测效果。为评估模型的泛化能力,研究还提出了一种采用邻近浮标数据进行学习,预测浮标缺失数据的方 法。实验结果表明,该方法的预测精度可以达到97.93%。本研究为海浪预测提供了新的方法和思路,也为未来深 度学习模型在海浪预测中的应用提供了参考。     

利用探地雷达观测分析早春融雪前后沙丘表层土壤含水量的时空分布

积雪融水是古尔班通古特沙漠春季植物发育的重要水源, 快速获取早春沙丘的土壤水分变化具有十分重要的生态学意义. 2010年3、 4月分别使用探地雷达进行了多次测量实验, 结果显示: 1)融雪初期, 沙丘顶部土壤的自由水含量最大, 阳坡次之, 且融雪水在重力作用下沿坡面侧向缓慢流动, 在坡底汇集, 主导了融雪初期乃至整个春季沙丘表层土壤水分的分布格局; 2)融雪后期, 由于阴坡积雪和冻土消融相对滞后, 表层土壤含水量略高于阳坡, 而沙丘顶部由于融雪最早且融雪期间水分转移最多而表面最为干燥; 3)通过与时域反射仪的同步测量结果对比, 探地雷达的测量精度被有效控制在0.03范围内, 且探地雷达提供的连续数据更有利于从细节上把握土壤含水量的变化趋势, 为中小尺度土壤水分的动态研究提供了一种科学、 有效的技术手段.     

Shear wave velocities and primary influencing factors of Campi Flegrei–Neapolitan deposits

The Campi Flegrei caldera (Italy) has been the site of intense seismic activity over the past decades. This area is densely populated and includes important towns such as Napoli with historical sites and supporting many industries. For the proper use and management of the region, the evaluation of the dynamic properties of near-surface rocks is necessary.

The volcanological pattern has been reconstructed from the lithostratigraphies of several drillings. The most interesting and widespread pyroclastic products are the pozzolana deposit (soil) and the Neapolitan Yellow Tuff (rock). Both pozzolana and tuff products are covered by recent eluvial and coastal sandy deposits and younger volcanic products (<12 000 years). The characteristic ranges of the shear wave velocity (V_s) of the Campi Flegrei–Neapolitan soils and tuffs are defined and the primary influencing factors are evaluated. For the sandy deposits, the results show that eluvial and lacustral products have lower shear wave velocities than coastal products. For the volcanic products younger than 12 000 years b.p. the influence of vertical pressure is emphasized. As regards the pozzolana deposit (soil) and the Neapolitan Yellow Tuff (rock), a major influencing factor is shown by the textural characteristics and the different hardening degrees as a consequence of the diagenetic processes. The scattering of the V_s velocities for the same formation is so wide that only the variability ranges can be individuated. These results suggest a need to carry out detailed V_s measurements or, at least, to make a parametric study of the effect of the V_s ranges on seismic response analysis in order to give safe building codes.