藻体海水培养液中铜的化学存在形式

采用金属络合物通式模型,在IBM-PC计算机上计算了不同pH(7.5～9.5)、碱度(2.3～2.5mmol dm~(-3))和加入不同浓度的铜离子(1.0×10~(-4)～1.0mg dm~(-3))条件下,海水培养液中铜的主要化学存在形式分配的百分数。还给出了计算机程序框图和主要化学存在形式含量的百分数随pH、碱度和铜浓度变化图。     

考虑底摩擦的波浪折射计算

本文用考虑底摩擦的折射模式计算了浅水中波高和波向分布。作为一个例子,根据不同的摩擦系数和不同的边界条件计算了一种简单海底地形的折射系数、衰减系数和折射角,所得结果与不考虑底摩擦的折射模式结果进行比较,发展它们之间存在一些差异,表明在浅水中底摩擦对波高有一定影响。     

Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.     

An alternative approach to the structural motion analysis of wedge-beam offshore structures supporting a load

For convenience of dynamic analysis, some offshore structures such as fixed-type platforms are often modeled as the wedge beams supporting tip lumped masses. It is well-known that, due to the effect of the surrounding water, the natural frequencies of a beam in air (or dry beam) are different from those of the same beam immersed in water (or wet beam). However, if the natural frequencies and the associated mode shapes of a dry beam are calculated by taking account of the “added mass” for the immersed beam, then the last natural frequencies and mode shapes will be equal to the corresponding ones of the wet beam. Based on the last concept, the closed form solutions for natural frequencies and the associated mode shapes of the dry beam were determined first, then the partial differential equation of motion for the wet beam was transformed into a matrix equation by using the expansion theorem and the foregoing closed form solutions of free vibration responses for the dry beam. Solving the last matrix equation will give the required natural frequencies and the associated mode shapes of the wet beam. The formulation of this paper is available for the fully or partially immersed double tapered beams with either circular, square or rectangular cross-sections. The taper ratio for width and that for depth may be equal or unequal. The numerical results of this paper were compared with the existing results or the finite-element-method results and good agreement was achieved.     

The Formation and Circulation of the Intermediate Water in the Japan Sea

In order to clarify the formation and circulation of the Japan/East Sea Intermediate Water (JESIW) and the Upper portion of the Japan Sea Proper Water (UJSPW), numerical experiments have been carried out using a 3-D ocean circulation model. The UJSPW is formed in the region southeast off Vladivostok between 41°N and 42°N west of 136°E. Taking the coastal orography near Vladivostok into account, the formation of the UJSPW results from the deep water convection in winter which is generated by the orchestration of fresh water supplied from the Amur River and saline water from the Tsushima Warm Current under very cold conditions. The UJSPW formed is advected by the current at depth near the bottom of the convection and penetrates into the layer below the JESIW. The origin of the JESIW is the low salinity coastal water along the Russian coast originated by the fresh water from the Amur River. The coastal low salinity water is advected by the current system in the northwestern Japan Sea and penetrates into the subsurface below the Tsushima Warm Current region forming a subsurface salinity minimum layer. This revised version was published online in August 2006 with corrections to the Cover Date.     

海水现场水色色度及渤海水域水色色度分析

叙述了目前海水现场水色测量的弊端 ,指出数字化海洋水色的潜在应用价值 ;根据色度学及色度学的三原色基本理论 ,确定海洋现场水色的色度要素 ,使海洋现场水色标号统一为物理学中严格的颜色物理量。结合 1 996年渤海水域光谱反射测量 ,对渤海水域 4个典型站位的反射光谱做了水色色度分析 ,并进行了 2种测量方法的比较     

北太平洋亚热带环流区表层水中226Ra和228Ra的分布与变化

对1999年9～10月采自北太平洋亚热带环流区的19份表层海水样品的Ra同位素分析表明。研究海域表层水中的^226Ra、^228Ra放射性比度分别介于0．67～0．92、0．08～0．30Bq／m^3之间，平均值分别为0．74、0．11Bq/m^3．^226Ra/^228Ra)A．R．活度比的变化范围为0．11～0．44，平均值为0．19．上述数值明显低于近岸海域水体的相应值，表现为典型的开阔大洋水的特征．从空间分布的特征看，研究海域Ra同位素含量与^226Ra/^228Ra)A.R.值均呈均匀分布态势．将本研究结果与历史数据进行对比后发现，本研究获得的^226Ra、^228Ra放射性比度比20世纪60～80年代得到的数据来得低，可能与水体层化作用加强导致的Ra补充量的减少以及生物生产力升高导致的Ra迁出量的增加有关．北太平洋亚热带环流区表层水中Ra同位素的时间变化与文献报道的该海域叶绿素a、硅酸盐、磷酸盐含量与初级生产力的历史变化趋势相吻合．     

Non-local impact of large-scale engineering in harbors and gulfs on the environment

A system of numerical tools to predict the non-local long-term impact of large-scale constructions on the environment is described. The predictions have to be results of successive examination of free water oscillations, turbulent boundary layers on the sea bottom, and turbulent pulsation effects on sediment transport. Numerical results related to free water oscillations in diverse gulfs are shown, and non-local effects of the dam construction are found for an example of the Baltic Sea. Feasibility of suggested tools for turbulent flow is manifested.     

Variation in Water Masses on Shelf of Northern Bering Sea in September 2016-2018

Abstract

Based on hydrological data obtained during the 7th to 9th Chinese National Arctic Research Expeditions in the summers of 2016–2018, the main water structure on the shelf of the northern Bering Sea and the volume and heat fluxes of the Bering Strait throughflow were analyzed. Distinct variability was identified in the three Pacific water masses feeding the strait - Anadyr Water (AW), Bering Shelf Water (BSW) and Alaskan coastal water (ACW). Overall, the temperature and salinity of the entire section increased each year, with 2018 showing significant anomalies, i.e., a temperature anomaly of up to 1?°C and a maximum salinity anomaly of 2. From 2016 to 2018, the extent of the ACW gradually narrowed in the eastern part of this section, while the AW expanded eastward each year. The net volume transport through each of the three sections increased poleward from 1.65?Sv to 2.76?Sv, with the AW increasing from 0?Sv to 1.03?Sv, the BSW varying between 0.52–1.65?Sv, and the ACW gradually decreasing from 1.04?Sv to disappearing completely. The net heat fluxes were also poleward, varying between 25.77 TW and 61.50 TW, and showing a significant increase. Significant variations in magnitude and extent were observed in each water mass of the Bering Strait throughflow, which could produce widespread effects in the Arctic Ocean and the global ocean beyond.     

Mercury speciation in surface and deep waters of the Mediterranean Sea

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.