Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Coupled surface water–groundwater model and its application in the arid Shiyang River basin,China

The planning and management of water resources in the Shiyang River basin, China require a tool for assessing the impact of groundwater and stream use on water supply reliabilities and improving many environment‐related problems such as soil desertification induced by recent water‐related human activities. A coupled model, integrating rule‐based lumped surface water model and distributed three‐dimensional groundwater flow model, has been established to investigate surface water and groundwater management scenarios that may be designed to restore the deteriorated ecological environment of the downstream portion of the Shiyang River basin. More than 66% of the water level among 24 observation wells have simulation error less than 1·0 m. The overall trend of the temporal changes of simulated and observed surface runoff at the Caiqi gauging station remains almost the same. The calibration was considered satisfactory. Initial frameworks for water allocation, including agricultural water‐saving projects, water diversion within the basin and inter‐basin water transfer, reducing agricultural irrigation area and surface water use instead of groundwater exploitation at the downstream were figured out that would provide a rational use of water resources throughout the whole basin. Sixteen scenarios were modelled to find out the most appropriate management strategies. The results showed that in the two selected management options, the groundwater budget at the Minqin basin was about 1·4 × 10⁸ m³/a and the ecological environment would be improved significantly, but the deficit existed at the Wuwei basin and the number was about 0·8 × 10⁸ m³/a. Water demand for domestic, industry and urban green area would be met in the next 30 years, but the water shortage for meeting the demand of agricultural water use in the Shiyang River basin was about 2·2 × 10⁸ m³/a. It is suggested that more inter‐basin water transfer should be required to obtain sustainable water resource use in the Shiyang River basin. Copyright © 2009 John Wiley & Sons, Ltd.     

大姚、民乐-山丹地震前的中短期前兆

利用川滇及青藏块体北缘地区上世纪80年代至2003年的跨断层流动形变观测资料，借助应变强度比时序曲线，通过丽江Ms7．0、景泰Ms5．9等震例研究，获取与2003年7月大姚Ms6．2、Ms6．1地震和10月民乐-山丹Ms6．1地震孕育有关的中短期前兆异常。分析表明：①大姚、民乐-山丹地震前1年内异常场地数远超过场地总数的1／3，相对近源区异常在发震地区占一半；②大姚Ms6．2地震前半年内，盐源-丽江地块及其邻近区域以及北东向延伸的川滇交界地区异常明显增多，相对集中。2003年7～9月大幅减弱；而鲜水河断裂、楚雄-通海断裂南段有所增强；③民乐-山丹震前十余天至数月内相对近源区及其邻近构造区域呈现异常相对分散-相对集中且局部增强-一临震前减弱的时空演变特征。震后一个月内青藏块体北缘地区仍有近1／3的场地呈现异常(海原一六盘山断裂带尤为突出)。     

Hydrologic characteristics of lake‐ and stream‐side riparian wetted margins in the McMurdo Dry Valleys,Antarctica

Water is a limiting factor for life in the McMurdo Dry Valleys (MDV), Antarctica. The active layer (seasonally thawed soil overlying permafrost) accommodates dynamic hydrological and biological processes for 10–16 weeks per year. Wetted margins (visually wetted areas with high moisture content) adjacent to lakes and streams are potential locations of great importance in the MDV because of the regular presence of liquid water, compared with the rest of the landscape where liquid water is rare. At 11 plots (four adjacent to lakes, seven adjacent to streams), soil particle size distribution, soil electrical conductivity, soil water content and isotopic signature, width of the wetted margin, and active layer thaw depth were characterised to determine how these gradients influence physicochemical properties that determine microbial habitat and biogeochemical cycling. Sediments were generally coarse‐grained in wetted margins adjacent to both lakes and streams. Wetted margins ranged from 1·04 to 11·01 m in average length and were found to be longer at lakeside sites than streamside. Average thaw depths ranged from 0·12 to 0·85 m, and were found to be deepest under lake margins. Lake margins also had much higher soil electrical conductivity, steeper topographic gradients, but more gradual soil moisture gradients than stream margins. Patterns of soil water δ¹⁸O and δD distribution indicate capillary action and evaporation from wetted margins; margin pore waters generally demonstrated isotopic enrichment with distance from the shore, indicating evaporation of soil water. Lake margin pore waters were significantly more negative in D_XS (D_XS = δD‐8δ¹⁸O) than streamside pore waters, indicating a longer history of evaporation there. Differences between lake and stream margins can be explained by the more consistent availability of water to lake margins than stream margins. Differences in margin characteristics between lakes and streams have important consequences for the microbial habitat of these margins and their functional role in biogeochemical cycling at these terrestrial–aquatic interfaces. Copyright © 2009 John Wiley & Sons, Ltd.     

Data collection methodology for dynamic temperature model testing and corroboration

This article describes a data collection approach for determining the significance of individual heat fluxes within streams with an emphasis on testing (i.e. identification of possible missing heat fluxes), development, calibration and corroboration of a dynamic temperature model. The basis for developing this approach was a preliminary temperature modelling effort on the Virgin River in southwestern Utah during a low‐flow period that suggested important components of the energy balance might be missing in the original standard surface‐flux temperature model. Possible missing heat fluxes were identified as bed conduction, hyporheic exchange, dead zone warming and exchange and poor representation of the amount of solar radiation entering the water column. To identify and estimate the relative importance of the missing components, a comprehensive data collection effort was developed and implemented. In particular, a method for measuring shortwave radiation behaviour in the water column and an in situ method for separating out bed conduction and hyporheic influences were established. The resulting data and subsequent modelling effort indicate that hyporheic and dead zone heat fluxes are important, whereas solar radiation reflection at the water surface was found to be insignificant. Although bed conduction can be significant in certain rivers, it was found to have little effect on the overall heat budget for this section of the Virgin River. Copyright © 2009 John Wiley & Sons, Ltd.     

Concentration–discharge relationships reflect chemostatic characteristics of US catchments

Concentration–discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration–discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter‐annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter‐annual timescales. We compared these catchments' concentration–discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration–discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean‐alkalinity feedback regulating climate change. Copyright © 2009 John Wiley & Sons, Ltd.     

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.     

High chloride concentrations in the soil and groundwater under an oak hedge in the West of France: an indicator of evapotranspiration and water movement

Chloride is a major anion in soil water and its concentration rises essentially as a function of evapotranspiration. Compared to herbaceous vegetation, high transpiration rates are measured for isolated trees, shelterbelts or hedgerows. This article deals with the influence of a tree hedge on the soil and groundwater Cl^? concentrations and the possibility of using Cl^? as an indicator of transpiration and water movements near the tree rows. Cl^? concentrations were measured over 1 year at different depths in the unsaturated zone and in the groundwater along a transect intersecting a bottomland oak hedge. We observed a strong spatial heterogeneity of Cl^? concentrations, with very high values up to 2 g l^?1 in the unsaturated zone and 1·2 g l^?1 in the upper part of the groundwater. This contrasts with the low and homogeneous concentrations (60–70 mg l^?1) in the deeper part of the groundwater. Cl^? accumulation in the unsaturated zone at the end of the vegetation season allows us to identify the active root zone extension of trees. In winter, upslope of the tree row, downwards leaching partly renews the soil solution in the root zone, while the slow water movement under the trees or farther downslope results in Cl^? accumulation and leads to a salinization of the soil and groundwater. This salinization is of the same order as experimental conditions produce negative effects on oak seedlings. The measurement of Cl^? concentrations in the unsaturated zone under tree rows at the end of the vegetation season would indicate whether certain topographic, pedological or climatic conditions are likely to favour a strong salinization of the soil, as observed in the present study. Copyright © 2009 John Wiley & Sons, Ltd.     

Climatic control on river discharge simulations,Zackenberg River drainage basin,northeast Greenland

A spatially distributed, physically based, hydrologic modeling system (MIKE SHE) was applied to quantify intra‐ and inter‐annual discharge from the snow and glacierized Zackenberg River drainage basin (512 km²; 20% glacier cover) in northeast Greenland. Evolution of snow accumulation, distribution by wind‐blown snow, blowing‐snow sublimation, and snow and ice surface melt were simulated by a spatially distributed, physically based, snow‐evolution modelling system (SnowModel) and used as input to MIKE SHE. Discharge simulations were performed for three periods 1997–2001 (calibration period), 2001–2005 (validation period), and 2071–2100 (scenario period). The combination of SnowModel and MIKE SHE shows promising results; the timing and magnitude of simulated discharge were generally in accordance with observations (R² = 0·58); however, discrepancies between simulated and observed discharge hydrographs do occur (maximum daily difference up to 44·6 m³ s^?1 and up to 9% difference between observed and simulated cumulative discharge). The model does not perform well when a sudden outburst of glacial dammed water occurs, like the 2005 extreme flood event. The modelling study showed that soil processes related to yearly change in active layer depth and glacial processes (such as changes in yearly glacier area, seasonal changes in the internal glacier drainage system, and the sudden release of glacial bulk water storage) need to be determined, for example, from field studies and incorporated in the models before basin runoff can be quantified more precisely. The SnowModel and MIKE SHE model only include first‐order effects of climate change. For the period 2071–2100, future IPCC A2 and B2 climate scenarios based on the HIRHAM regional climate model and HadCM3 atmosphere–ocean general circulation model simulations indicated a mean annual Zackenberg runoff about 1·5 orders of magnitude greater (around 650 mmWE year^?1) than from today 1997–2005 (around 430 mmWE year^?1), mainly based on changes in negative glacier net mass balance. Copyright © 2007 John Wiley & Sons, Ltd.     

Five-year bio-monitoring of aquatic ecosystems near Artigas Antarctic Scientific Base,King George Island

Fildes Peninsula, in King George Island, Antarctica, has a great concentration of international facilities, and it has clearly been affected by human activities. The objective of this 5-year study was ...