水和水蒸气辅助粗晶三水铝石转化为勃姆石的机制研究

在165℃、175℃、185℃和195℃的温度条件下,对水热处理前和处理后的粗晶三水铝石样品分别进行了XRD分析和SEM表征,研究了粗晶三水铝石在水蒸气和热水中转变成勃姆石的相变过程。结果表明,水热条件下粗晶三水铝石转化成勃姆石的过程受控于溶解-再沉淀机制,而并非是通常认为的固体状态下的转变;相对于在热水中,水蒸气环境可以加速三水铝石向勃姆石的转化;所形成的勃姆石的粒径（4~7 μm）明显比前驱体三水铝石的粒径（120~200 μm）要小得多,表明可以利用粗晶三水铝石生产微晶勃姆石。在转化过程中,勃姆石微晶首先生长在三水铝石的晶体表面上,通过控制反应温度和反应时间,可形成壳层为勃姆石、壳下为三水铝石的具有双层结构的铝的氢氧化物颗粒,也有可能形成具有中空结构的勃姆石集合体颗粒。     

FLOW SEPARATION IN UNDISTURBED SOILS USING MULTIPLE ANIONIC TRACERS. PART 1. ANALYTICAL METHODS AND UNSTEADY RAINFALL AND RETURN FLOW EXPERIMENTS

Tracers provide one of the few ways of obtaining realistic information on the flows of water and solutes in undisturbed structured soils. Three fluorinated organic acids [pentafluorobenzoic acid, 2,6-diflurobenzoic acid and o-(trifluoromethyl) benzoic acid] and bromide were tested as anionic tracers in situations where the separation of different flow components is of interest. The fluorobenzoates were relatively conservative (approximately 90% for loam soil) although, in some instances, co-elution or complexation may lead to apparently non-conservative behaviour. Tracer mixtures applied to soils, were separated and quantified by high-performance liquid chromatography. The relative mobilities of the tracers were studied during unidirectional steady flow in large undisturbed soil columns brought back to the laboratory. The breakthrough curves showed highly dispersive behaviour, with very early breakthrough of solute and a long tail. Contributions to the column outflow of different simultaneous applications of rainfall and return flow, labelled with different tracers, were separated using multicomponent mixing equations. The results show the importance of preferential flow and relatively immobile storage in the transport process.     

FLOW SEPARATION IN UNDISTURBED SOIL USING MULTIPLE ANIONIC TRACERS. PART 2. STEADY-STATE CORE-SCALE RAINFALL AND RETURN FLOWS AND DETERMINATION OF DISPERSION PARAMETERS

A series of experiments designed to study the separation of flow components from two large undisturbed cores under steady-state rainfall (downward) and return (upward) flows under near-saturated conditions is summarized. The experiments were conducted on soil columns collected from Lancaster University and the Slapton Wood catchment, Devon. The use of the relatively conservative tracers, potassium bromide, o-(trifluoromethyl)benzoic acid and 2,6-difluorobenzoic acid and a combination of application rates made it possible to quantify the different sources of water contributing to the discharge hydrographs. There is significant retention of tracer within the cores, despite the application of several pore volumes of water. The use of steady flow conditions allowed the determination of dispersion coefficients, dispersivity and proportion of ‘mobile’ water content parameters of the advection–dispersion equation. It was found that there were significant differences between the dispersivities at different flow-rates under upward and downward flux conditions and that in the undisturbed cores studied here the apparent proportions of mobile pore water ranged between 0.33 and 1.0, with an apparently complex relationship to flux rate. Prediction of transport in undisturbed soil remains problematic and tracer experiments will continue to be needed to provide a fundamental understanding of the complex flow processes involved.     

唐山7.8级地震前地磁异常的综合分析

利用昌黎等台的磁测资料,并用多种方法进行综合分析,结果显示,在震前出现了约3个月的短期异常,这对于地震的预测预报有一定意义。     

季风低压诱发2018年8月广东特大暴雨过程分析

利用NCEP/FNL再分析资料和中尺度数值模拟方法探讨2018年8月27日—9月1日季风低压环境下广东特大暴雨过程的形成成因。利用扰动天气图方法分析发现,季风低压和西南急流为此次广东暴雨过程提供了有利的水汽条件和能量条件。熵变零线位置与降水落区位置有较好的对应,零线处能量有最大累积,有利于暴雨的发生发展,对预报暴雨降水落区有一定的指示意义。为进一步验证季风低压的影响机制,构建不同季风低压尺度的敏感性试验,即通过滤去季风低压环流中的扰动分量来改变季风低压的强度。结果表明：暴雨强度与季风低压尺度和强度存在密切的关系。当季风低压强度较强时,暴雨过程总雨量强;当季风低压强度较弱时,降水大为减少甚至无降水。诊断分析指出,能量螺旋度指数能够较好反映出不同情形下降水发生发展,在季风低压背景下,暴雨区能量螺旋度指数较大,降水强度较强。反之,随着季风低压强度减弱,能量螺旋度指数减小,降水减弱。     

太湖流域降雨与太湖水位关系分析

太湖流域快速城镇化、水利工程建设等人类活动对流域水文过程产生了较大影响.基于1981～2018年太湖流域日降雨、太湖水位实测资料,分析了流域降雨与太湖水位涨幅关系,旨在揭示变化环境下该地区降雨与水位关系的变化特征及可能的驱动因素.研究表明,2000年以来太湖水位抬高趋势明显,但同等时段降雨量条件下对应的太湖水位涨幅有所...     

川东北地区不同构造带地层水化学特征与油气保存的关系

判断油气藏保存条件的优劣,除了盖层和断层封闭性之外,还有油气水的化学特征,如地层水的交替或油气散失。通过对川东北地区地层水的水型、矿化度、水性系数等参数的综合分析认为,川东北宣汉—达县地区与通江—南江—巴中地区的地层水具有矿化度高和氯镁系数越大,变质系数、脱硫系数和碳酸盐平衡系数就越小的特点。矿化度、水性系数及水型的变化具有很好的一致性,表明该区存在有利于油气保存的水文地质条件。     

Application of flocculation combined with vacuum preloading to reduce river-dredged sludge

Abstract

To achieve the rapid dewatering of dredged sludge, the flocculation–vacuum-preloading method was tested indoors. In this study, the optimal mixing ratio of six flocculants was determined through the settling column test, and then the proposed method was tested. The water drainage and settlement were monitored during the test, while the soil moisture content and shear strength were measured after the test. The results show that all the flocculants had an optimal mixing ratio, and the addition of 0.8% FeCl₃ or 0.08% anionic polyacrylamide (APAM) in the sludge can better accelerate solid–liquid separation of the sludge. After the test, the water content in the sludge decreased from 140% to 60%. Compared with general vacuum preloading, the use of the proposed method increased the water drainage by 46.5% and 56.8% and decreased the soil volumes by 60.5% and 82.4% for FeCl₃ and APAM, respectively. Moreover, the corresponding shear strength was increased from 10 to 14 and 17?kPa. In addition, the use of APAM increased the solidification rate of heavy metals in the sludge to more than 80%, effectively inhibiting the migration of heavy metals.     

降雨量、土壤蓄水量对流动沙地土壤水分深层渗漏的影响

土壤水分深层渗漏是陆地近地层水分循环的重要环节。利用土壤水分深层渗漏记录仪对毛乌素沙地典型流动沙丘不同深度土层的土壤渗漏水量连续进行两年定点监测。结果表明：（1）2016年生长季（4月1日至10月31日）降水量为2017年的1.93倍,但50、100、200 cm沙层的渗漏水量分别是2017年同期的4.53、5.53,5.22倍。同时,渗漏水量与降雨量及土壤蓄水量的波峰较一致。（2）强降雨对深层渗漏水量的影响较大,土壤蓄水量的变化也与深层渗漏水量密切相关;降雨量较小时,土壤蓄水量与深层渗漏水量之间的关系更为密切。在连续降雨过程中,越往深处,渗漏的产生通常是多次降雨过程累积的结果,将土壤蓄水量作为中间变量,能更好地分析土壤深层渗漏过程。（3）当天蓄水量与次日渗漏水量的相关系数较高,土层越深,深层渗漏水量与土壤蓄水量的相关系数增加,二者之间的线性拟合的R²也相应增加。     

Strain analysis of a seismically imaged mass‐transport complex,offshore Uruguay

Strain style, magnitude and distribution within mass‐transport complexes (MTCs) are important for understanding the process evolution of submarine mass flows and for estimating their runout distances. Structural restoration and quantification of strain in gravitationally driven passive margins have been shown to approximately balance between updip extensional and downdip contractional domains; such an exercise has not yet been attempted for MTCs. We here interpret and structurally restore a shallowly buried (c. 1,500 mbsf) and well‐imaged MTC, offshore Uruguay using a high‐resolution (12.5 m vertical and 15 × 12.5 m horizontal resolution) three‐dimensional seismic‐reflection survey. This allows us to characterise and quantify vertical and lateral strain distribution within the deposit. Detailed seismic mapping and attribute analysis shows that the MTC is characterised by a complicated array of kinematic indicators, which vary spatially in style and concentration. Seismic‐attribute extractions reveal several previously undocumented fabrics preserved in the MTC, including internal shearing in the form of sub‐orthogonal shear zones, and fold‐thrust systems within the basal shear zone beneath rafted‐blocks. These features suggest multiple transport directions and phases of flow during emplacement. The MTC is characterised by a broadly tripartite strain distribution, with extensional (e.g. normal faults), translational and contractional (e.g. folds and thrusts) domains, along with a radial frontally emergent zone. We also show how strain is preferentially concentrated around intra‐MTC rafted‐blocks due to their kinematic interactions with the underlying basal shear zone. Overall, and even when volume loss within the frontally emergent zone is included, a strain difference between extension (1.6–1.9 km) and contraction (6.7–7.3 km) is calculated. We attribute this to a combination of distributed, sub‐seismic, ‘cryptic’ strain, likely related to de‐watering, grain‐scale deformation and related changes in bulk sediment volume. This work has implications for assessing MTCs strain distribution and provides a practical approach for evaluating structural interpretations within such deposits.