Reductive dissolution of arsenical ferrihydrite by bacteria

Mining and metallurgical processing of gold and base metal ores can lead to the release of arsenic into the aqueous environment as a result of the weathering and leaching of As-bearing minerals during processing and following disposal. Arsenic in process solutions and mine drainage can be effectively stabilized through the precipitation of ferrihydrite. However, under anaerobic conditions imposed by burial and waste cover systems, ferrihydrite is susceptible to microbial reduction. This research, stimulated by the paucity of information and limited understanding of the microbial reduction of arsenical ferrihydrite, was conducted on synthetic adsorbed and co-precipitated arsenical 6-line ferrihydrite (Fe/As molar ratio of 10/1) using Shewanella sp. ANA-3 and Shewanella putrefaciens CN32 in a chemically defined medium containing 0.045 mM phosphate concentration. Both bacteria were equally effective in their reducing abilities around pH 7, resulting in initial rates of formation of dissolved As(III) of 0.10 μM/h for the adsorbed, and 0.08 μM/h for the co-precipitated arsenical 6-line ferrihydrite samples. The solid phases in the post-reduction samples were characterized by powder X-ray diffraction (XRD), micro-XRD, scanning electron microscopy (SEM), transmission electron microscopy (TEM), electron microprobe and X-ray absorption spectroscopy (XAS) techniques. The results indicate the formation of secondary phases such as a biogenic Fe(II)–As(III) compound, akaganeite, goethite, hematite and possibly magnetite during bacterial reduction experiments. Holes and bacterial imprints measuring about 1–2 μm were observed on the surfaces of the secondary phases formed after 1200 h of reduction. This study demonstrates the influence of Fe and As reducing bacteria on the release of significant concentrations of more mobile and toxic As(III) species from arsenical 6-line ferrihydrite, more readily from the adsorbed than from the co-precipitated ferrihydrite.     

A natural cement analogue study to understand the long-term behaviour of cements in nuclear waste repositories: Maqarin (Jordan)

The geological storage of nuclear waste includes multibarrier engineered systems where a large amount of cement-based material is used. Predicting the long term behaviour of cement is approached by reactive transport modelling, where some of the boundary conditions can be defined through studying natural cement analogues (e.g. at the Maqarin natural analogue site). At Maqarin, pyrometamorphism of clay biomicrites and siliceous chalks, caused by the in-situ combustion of organic matter, produced various clinker minerals. The interaction of infiltrating groundwater with these clinker phases resulted in a portlandite-buffered hyperalkaline leachate plume, which migrated into the adjacent biomicrite host rock, resulting in the precipitation of hydrated cement minerals.In this study, rock samples with different degrees of interaction with the hyperalkaline plume were investigated by various methods (mostly SEM-EDS). The observations have identified a paragenetic sequence of hydrous cement minerals, and reveal how the fractures and porosity in the biomicrite have become sequentially filled. In the alkaline disturbed zone, C-A-S-H (an unstoichiometric gel of Ca, Al, Si and OH) is observed to fill the pores of the biomicrite wallrock, as a consequence of reaction with a high pH Ca-rich fluid circulating in fractures. Porosity profiles indicate that in some cases the pores of the rock adjacent to the fractures became tightly sealed, whereas in the veins some porosity is preserved. Later pulses of sulphate-rich groundwater precipitated ettringite and occasionally thaumasite in the veins, whereas downstream in the lower pH distal regions of the hyperalkaline plume, zeolite was precipitated.Comparing our observations with the reactive transport modelling results reveals two major discrepancies: firstly, the models predict that ettringite is precipitated before C-A-S-H, whereas the C-A-S-H is observed as the earlier phase in Maqarin; and, secondly, the models predict that ettringite acts as the principal pore-filling phase in contrast to the C-A-S-H observed in the natural system. These discrepancies are related to the fact that our data were not available at the time the modelling studies were performed. However, all models succeeded in reproducing the porosity reduction observed at the fracture–rock interface in the natural analogue system.     

Leaching potential and redox transformations of arsenic and selenium in sediment microcosms with fly ash

The unintended release of coal ash to the environment is a concern due to the enrichment of contaminants such as arsenic (As) and selenium (Se) in this solid waste material. Current risk assessments of coal ash disposal focus on pH as the primary driver of leaching from coal ash. However, redox speciation of As and Se is a major factor for their mobilization potential and has received much less attention for risk assessments, particularly in disposal scenarios where coal ash will likely be exposed to microbially-driven redox gradients. The aim of this study was to demonstrate the differences of aerobic and anaerobic conditions for the leaching of As and Se from coal ash. Batch sediment-ash slurry microcosms were performed to mimic an ash spill scenario and were monitored for changes in As and Se speciation and mobilization potential. The results showed that the dissolved As concentrations were up to 50 times greater in the anaerobic microcosms relative to the aerobic microcosms during the two week incubation. This trend was consistent with As redox speciation determined by X-ray absorption spectroscopy, which indicated that 55% of the As in the solid phase at the end of the experiment was present as As(III) (a more leachable form of arsenic relative to As(V)). In the aerobic microcosms, only 13% of the As was As(III) and the rest was As(V). More than half of the Se was present as Se(IV) in the original fly ash and in the aerobic microcosms, while in the anaerobic microcosms Se was gradually transformed to less soluble Se(0) species. Likewise, dissolved Se concentrations were up to 25 times greater in the aerobic microcosms relative to anaerobic conditions. While the overall observations of As and Se mobilization potential from coal ash were consistent with expectations for aqueous and solid phase speciation of these elements, the findings directly show the relevance of these processes for coal ash disposal. These results highlight the need to select appropriate environmental parameters to include in risk assessments as well as provide potential geochemical monitoring tools through the use of dissolved Se/As ratios to determine the redox conditions of ash storage and spill sites.     

羽毛还是鳞片

简要介绍了羽毛的结构、类型、发育过程、起源及早期演化,讨论了"单根管状羽毛"的性质,指出这种管状结构不是羽毛,而是高度变形的特化鳞片。尽管羽毛与爬行动物的鳞片同源,而且羽毛是由恐龙身上的鳞片演变而来,但关键在于小囊领的分异和羽枝脊的出现与否。也就是说,在形态结构上,如果表皮的角质化衍生物出现了羽根和羽小枝,就应该将其称为羽毛,未发生这种分异的结构应当归于高度变形的特化鳞片。同时还讨论了德国法兰克福圣肯堡自然历史博物馆收藏的带纤维状结构的鹦鹉嘴龙和俄罗斯西伯利亚发现的植食性恐龙(Kulindadromeus zabaikalicus),认为二者发育的纤维状结构或羽毛状结构不是羽毛,而是高度变形的特化鳞片,并不存在鳞片与羽毛共生的现象。就目前的材料而言,羽毛仅限发育于兽脚类恐龙中,并不是所有的恐龙均发育羽毛。     

基于图像处理技术的养殖池集污特性研究

本文针对养殖池的集污试验,研究了用于量化分析污物聚集面积的图像处理技术,并将其用于方形圆切角养殖池在边侧管式射流方式下的集污特性研究。图像处理技术包括图像预处理、图像增强、图像分割、轮廓提取四个步骤,成功获得了污物的量化分布面积。在养殖池集污特性研究方面,本文研究了射流流速为24cm/s条件下,不同射流角(射流方向与池壁夹角)对污物聚集效果的影响。结果表明,方形圆切角养殖池存在一个最优的射流角度,本文研究条件下,最优角度约为40°。本文研究结果,可为养殖池水力驱动优化布置提供参考。     

A crack in the facade? Situating Singapore in global flows of electronic waste

Singapore is alleged to be a key node in global flows of e‐waste prohibited under the Basel Convention. We combine a close reading of the Convention and related documents with findings from nonparticipant observation of and interviews with Singapore‐based traders of discarded electronics. The case offers both important conceptual and empirical findings for future studies of territory in market‐making activity. Conceptually, our research suggests that it may be analytically useful in such studies to conceptualize territory without presupposing that it is generated as a result of separate domains or logics such as ‘the political’ or ‘the economic’. Empirically, we find that the regulatory framework of the Convention, combined with the action of traders based in Singapore, generates a territorialization of the city‐state such that it operates as a crack in the regulatory edifice of the Convention, even as Singapore lawfully fulfils its obligations to it. Moreover, allegations premised on the role of Singapore as a facilitator of global e‐waste dumping misrepresent its crucial role as a conduit of electronic equipment for the significant reuse markets elsewhere in Southeast Asia and beyond. The case indicates that the allegations against Singapore hinge on the city‐state being territorialized as a ‘developing country’.     

A physically-based model of long-term food demand

Reducing hunger while staying within planetary boundaries of pollution, land use and fresh water use is one of the most urgent sustainable development goals. It is imperative to understand future food demand, the agricultural system, and the interactions with other natural and human systems. Studying such interactions in the long-term future is often done with Integrated Assessment Modelling. In this paper we develop a new food demand model to make projections several decades ahead, having 46 detailed food categories and population segmented by income and urban vs rural. The core of our model is a set of relationships between income and dietary patterns, with differences between regions and income inequalities within a region. Hereby we take a different, more long-term-oriented approach than elasticity-based macro-economic models (Computable General Equilibrium (CGE) and Partial Equilibrium (PE) models). The physical and detailed nature of our model allows for fine-grained scenario exploration. We first apply the model to the newly developed Shared Socio-economic Pathways (SSP) scenarios, and then to additional sustainable development scenarios of food waste reduction and dietary change. We conclude that total demand for crops and grass could increase roughly 35–165% between 2010 and 2100, that this future demand growth can be tempered more effectively by replacing animal products than by reducing food waste, and that income-based consumption inequality persists and is a contributing factor to our estimate that 270 million people could still be undernourished in 2050.     

Polymetallic Nodule Mining, Waste Disposal, and Species Extinction at the Abyssal Seafloor

The size of individual mining blocks for polymetallic nodule extraction seems to be rather small, not more than 100 km² in the French mining claim. Even when adding an additional resedimentation zone to the directly impacted area, the size of the affected seabed would remain below 200 km². We assume that even rare species in the abyss inhabit larger areas and propose discussions of the International Seabed Authority and other stakeholders for the different subregions on mining strategies from the perspective of exploitation versus species extinction and conservation. Although impacts of waste disposal at the abyssal seafloor are different from those of nodule mining, the 200 km² concept may also be applied.     

青岛市垃圾卫生填埋场选址问题研究

垃圾卫生填埋法将是青岛市今后若干年内垃圾处理的主要方法，结合青岛市城市发展的规划思路，提出在保护环境，尤其是海洋环境的基础上，应寻找内陆场地进行垃圾卫生填埋。经遴选，小涧一带最有前景，经论证，认为小涧一带从地形地貌、地表水发育，场地取土条件，环境水文地质条件、构造条件及经济条件等各方面均满足选址要求     

胶州湾娄山河口海域制碱白泥治理方法初探

文章从如何解决制碱废泥—白泥的治理角度出发,分析了胶州湾娄山河口海域制碱白泥的性状及分布现状,对比国内外制碱企业对于白泥的处置方法,针对淤积多年的白泥浅滩提出三种污染治理方案,并探讨了各种方案的实施对附近海域环境的影响。研究成果可为青岛市污染治理、环境规划与管理、海洋环境保护提供科学依据。