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11.
12.
十四株海洋微藻脂肪酸组成的研究 总被引:5,自引:0,他引:5
对 4个门的 14株 (红藻门 8株 ,甲藻门 1株 ,隐藻门 2株 ,绿藻门 3株 )海洋微藻进行了脂肪酸含量测定 ,微藻在确定的条件下生长 ,指数生长末期收获。结果表明 ,各门的微藻都有其独特的脂肪酸特征 :红藻中含有大量的 2 0 :4 n- 6和 2 0 :5n- 3,其中紫球藻 R2 5含量最高 ,占总脂肪酸的4 9.8% (AA占总脂肪酸的 2 0 .5% ,EPA占总脂肪酸的 2 9.3% )。隐藻的主要脂肪酸是 16 :0、18:1n- 9、18:3n- 3、18:4 n- 3、2 0 :5n- 3、2 2 :5n- 3。与其它甲藻有别的虫黄藻 ,18:4 n- 3含量很少并且不含EPA,其主要合成的是 16 :0、18:1n- 9和 2 2 :6 n- 3。 C16和 C18的不饱和脂肪酸是本实验研究的 3株绿藻的主要脂肪酸 相似文献
13.
14.
运用光谱分析和GC-MS方法首次从卡氏豆荚软珊瑚Lobophytumcatelai中分离和鉴定出8个化合物:l,十六碳酸;2,异丁基十六碳酸酯;3,鲨肝醇;4十六酸丙酯;5,2,3一二羟基丙基十八酸酯;6,2β,3β-环氧基-5α-雄甾烷-17-醇;7,14-甲基-5α-胆甾-8-稀-3-酮;8,2α,3α一环氧基-5α-雄甾烷-17-醇。 相似文献
15.
养殖对虾与海捕对虾鉴别方法初探 总被引:1,自引:1,他引:1
通过对养殖中国对虾(Penaeus orientalis)和海捕中国对虾肌肉煮熟后的失水率,提取物中的甜菜碱和氧化三甲胺含量,以及虾肉脂质中所含脂肪酸组成和含量进行了分析比较,得到下列结果:(1)两类对虾鲜样煮熟后失水率相差6%以上;(2)海捕对虾肌肉中的甜菜碱和氧化三甲胺含量比养殖对虾的高,两者有显著差别;(3)养殖对虾肌肉所含C18:2ω6为17.3±1.5%,海捕对虾为2.0±0.8%。从以上结果本文推荐以脂肪酸C18:2ω6含量来鉴别养殖对虾与海捕对虾。 相似文献
16.
The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O
8
2–
) at 351 nm followed by the reactions of sulfate radicals (SO
4
–
) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk
1=(3.3±1.0)×105 l mol–1 s–1 andk
2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k
1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk
2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k
3=(1.3±0.3)×104 l mol–1 s–1 andk
4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k
3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk
4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets. 相似文献
17.
The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > FeIII-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)3(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity. 相似文献
18.
Stephanie de Villiers 《中国地球化学学报》2006,25(B08):146-146
Acidification is considered the most important one of the primary chemical stress factors that impact on freshwater ecosystems. In unpolluted freshwater systems, the primary controls on the degree of acidification are factors such as the geological substrate of the catchment area, the presence of organic acids secreted by vegetation in the river system, and equilibrium exchange of carbon dioxide with the atmosphere. Anthropogenic factors that can impact on the degree of acidification of freshwater systems include agricultural, mining and industrial activities, either through direct runoff into river systems or through deposition of atmospheric pollutants from these sources. The capacity factors alkalinity and acidity, which represent the acid- and base-neutralizing capacity (ANC and BCN) of an aqueous system, have been used as more reliable measures of the acidic character of freshwater systems than pH. Unlike pH, ANC and BNC are not affected by parameters such as temperature and pressure. Therefore, ANC has been employed as a predictor of biological status in critical load assessments. Freshwater systems with ANC's eq/L isμeq/L are considered sensitive to acidification, ANC=0 μbelow 150 commonly used as the predictor for fish species such as trout in lakes, and an eq/L as more realistic for streams. Acid-neutralizing capacity μANC value of 40 (ANC) can be determined by titration with a strong acid to a preselected equivalence point. Alternatively, it can be calculated as the difference between base cations ([BC]) and strong acid anions ([SAA]): ANC=[BC]- [SAA]=[Ca^2+]+[Mg^2+]+[Na^+]+[K^+]-[SO4^2-]-[NO3^-]-[Cl^-] To date, there has been no attempt to establish the ANC of South Africa's freshwater ecosystems or variability therein, despite the fact that long-term water quality monitoring data exist for all the parameters needed to calculate it according to the above equations. As a result, the relationship between the acid neutralizing capacity of freshwater ecosystems in South Africa and biodiversity factors, such as fish status, is unknown. Results of the first comprehensive (country-wide scale) evaluation of the acid neutralizing capacity of river systems in South Africa will be presented. Long-term monitoring data obtained from the Department of Water Affairs and Forestry (DWAF) from most of South Africa's river systems were used to establish geographic and temporal variabilities in ANC. The results show that the Berg and Breede River systems are most susceptible to acidification, and that geological substrate appears to explain most of the geographic variabilities observed. 相似文献
19.
Houyi ZHENG Congqiang LIU Zhongliang WANG 《中国地球化学学报》2006,25(B08):174-174
Bedrock weathering and atmospheric deposition are the two primary sources of base cations (K^+, Na^+, Ca^2+ and Mg^2+) to forest ecosystems. Therefore, the key problem is to understand the relative inputs from these two sources and the cycling in the ecosystem. This study focuses on the effects of acid deposition on cation cycling in a small-forested karstic catchment in Guizhou Province. Sr isotope ratios were used as a tracer for understanding the transport process between the different cation pools: rock, soil, surface water, atmospheric deposition and plant. The samples of wet deposition, total deposition, throughfall, surface and ground waters, vegetation, and soil were monthly collected. The exchangeable Sr^2+ and Ca^2+ in soil samples were extracted by using 1 M ammonium acetate. The leaf-tissue samples were ashed at 550℃, and the residue was digested in ultrapure HClO4 and HNO3. All water samples were filtrated through 0.45 μm aperture filter paper. Base cation concentrations and Sr isotopic composition were analyzed for all the samples. The results show that acid deposition (average pH 4.9) frequently occurred in the studied region. Cation abundance follows an increasing manner from rainwater, throughfall, to surface water or ground water samples, suggesting that acid deposition at first eiuviates Ca^2+ , Mg^2+ and Sr^2+ from leaf, then the exchangeable cations from soil, and at last cations accumulate in surface water or ground water. 相似文献
20.
Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream (pH 2.98-3.40), 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization. 相似文献