First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.     

Response of A Gravel - Bed River To Dam Closure: Insights From Sediment Transport Processes And Channel Morphodynamics

This work deals with the impacts of dams on large gravel -bed rivers in terms of altering coarse transport regimes and the relationship with river morphodynamics. Using data collected by a tracer -based monitoring programme carried out in a 4 -km -long study sector of the Parma River (Italy), located downstream from a relatively recently established dam, we applied a virtual velocity approach to estimate the coarse bed material load at four river cross -sections. Monitoring and calculation results provided new insights into the impacts of the dam on streambed material mobility and the sediment regime over the 17 -month calculation period. A longitudinal gradient of effects was observed along the study sector. Sections located closer to the dam are characterized by more evident impacts due to deficits in coarse sediment input from upstream. Sediment mobility here is strongly altered, especially in the highly armoured main channel, and the overall bed material load is extremely low. A partial recovery of sediment dynamics was observed at the sections located further from the dam, where estimates indicate higher sediment yield. The observed longitudinal trend in the coarse sediment transport regime matches the morphology, as the river shifts downstream from a sinuous configuration with alternate bars to a wandering one. The novel insights into alteration of coarse sediment dynamics and the relationship with river morphodynamics are potentially applicable to many other fluvial contexts affected by similar impoundments. © 2019 John Wiley & Sons, Ltd.     

The influence of channel morphology on bedload path lengths: Insights from a survival process model

Tracer studies are a commonly used tool to develop and test Einstein-type stochastic bedload transport models. The movements of these tracers are controlled by many factors including grain characteristics, hydrologic forcing, and channel morphology. Although the influence of these sediment storage zones related to morphological features (e.g., bars, pools, riffles) have long been observed to “trap” bedload particles in transport, this influence has not been adequately quantified. In this paper we explore the influence of channel morphology on particle travel distances through the development of a Bayesian survival process model. This model simulates particle path length distributions using a location-specific “trapping probability” parameter (p_i ), which is estimated using the starting and ending locations of bedload tracers. We test this model using a field tracer study from Halfmoon Creek, Colorado. We find that (1) the model is able to adequately recreate the observed multi-modal path length distributions, (2) particles tend to accumulate in trapping zones, especially during large floods, and (3) particles entrained near a trapping zone will travel a shorter distance than one that is further away. Particle starting positions can affect path lengths by as much as a factor of two, which we confirm by modelling “starting-location-specific” path length probability distributions. This study highlights the importance of considering both tracer locations and channel topography in examinations of field tracer studies. © 2020 John Wiley & Sons, Ltd.     

Bed material transport estimated from the virtual velocity of sediment

This study evaluates the possibility of determining bed material transport using the virtual rate of travel of individual particles, dimensions of the active layer of the streambed, and porosity and density of streambed material. Magnetically tagged stones and scour indicators were employed in Carnation Creek, British Columbia, to quantify transport rates. Observations cover flows up to 36 m³ s⁻¹ (τ* = 0·081). Transport rates, ranging from 0·090 to 9·7 kg s⁻¹ (0·12–13·2 m³ h⁻¹), display a relatively sensitive trend with maximum stream power, as expected. Error analysis indicates that uncertainty in virtual velocity covers the majority of sample variance. An evaluation of the two measurement techniques used to delineate active layer dimensions, magnetically tagged stones and scour indicators, indicates that they yield comparable depths, widths and transport rates over the range of flows observed. Issues for further study are discussed. © 1998 John Wiley & Sons, Ltd.     

2011年3月日本福岛核电站核泄漏在海洋中的传输

使用全球版本的迈阿密等密度海洋环流模式对2011年3月日本福岛核电站泄漏在海洋中的传输以及扩散进行了数值模拟。数值模式中核废料(示踪物)排放情景采取等通量连续排放,排放时间从3月25日开始,分别持续20 d以及1 a,两种情形分别积分20 a。为了减少海洋环流年际变化带来的数值模拟的的不确定性,20 a的模式积分分别用2010年、1991-2011年、1971-1991年以及1951-1971年4个不同时段的NCEP/NCAR逐日再分析资料作为大气强迫场,因此每种排放情形包含4个数值试验。模拟结果的分析表明,不同核废料排放情景及其在不同时段大气资料对海洋模式的驱动下,模拟的示踪物总体的传输扩散路径(包括表层以及次表层)、传输速率以及垂直扩展的范围没有显著的差异。集合平均数值模拟的结果显示:在两种排放情景下,日本福岛核泄漏在海洋的传输路径受北太平洋副热带涡旋洋流系统主导,其传输路径首先主要向东,到达东太平洋后,再向南向西扩散至西太平洋,可能在10~15 a左右影响到我国东部沿海海域,且海洋次表层的传输信号比表层信号早5 a左右。通过进一步分析模式积分过程中最大示踪物浓度随时间变化发现,在积分第20 a(2031年3月),海洋表层和次表层浓度的最高值分别只有模式积分第一年浓度的0.1%和1%。在积分的20 a里,排放的核废料主要滞留在北太平洋海域(超过86%±1.5%的核废料在积分结束时,滞留在北太平洋),而在积分的前10 a(2021年之前),几乎所有的核废料滞留在北太平洋;在核废料的垂直分布上,主要集中在海洋表层至600 m的深度,在积分的20 a时间里,没有核废料信号扩散至1 000 m以下的深度。数值模拟的结果也表明核废料浓度减弱的强度以及演变的时间特征主要受洋流系统的影响,与排放源的排放时间长短关系不大。值得指出的是,更加准确地评估一个真实的核泄漏事故对海洋环境所造成的可能影响,还需要考虑大气中的放射性物质的沉降以及海洋生态对核物质的响应。     

2011年3月日本福岛核电站核泄漏在海洋中的传输

使用全球版本的迈阿密等密度海洋环流模式对2011年3月日本福岛核电站泄漏在海洋中的传输以及扩散进行了数值模拟。数值模式中核废料(示踪物)排放情景采取等通量连续排放,排放时间从3月25日开始,分别持续20 d以及1 a,两种情形分别积分20 a。为了减少海洋环流年际变化带来的数值模拟的的不确定性,20 a的模式积分分别用2010年、1991-2011年、1971-1991年以及1951-1971年4个不同时段的NCEP/NCAR逐日再分析资料作为大气强迫场,因此每种排放情形包含4个数值试验。模拟结果的分析表明,不同核废料排放情景及其在不同时段大气资料对海洋模式的驱动下,模拟的示踪物总体的传输扩散路径(包括表层以及次表层)、传输速率以及垂直扩展的范围没有显著的差异。集合平均数值模拟的结果显示:在两种排放情景下,日本福岛核泄漏在海洋的传输路径受北太平洋副热带涡旋洋流系统主导,其传输路径首先主要向东,到达东太平洋后,再向南向西扩散至西太平洋,可能在10~15 a左右影响到我国东部沿海海域,且海洋次表层的传输信号比表层信号早5 a左右。通过进一步分析模式积分过程中最大示踪物浓度随时间变化发现,在积分第20 a(2031年3月),海洋表层和次表层浓度的最高值分别只有模式积分第一年浓度的0.1%和1%。在积分的20 a里,排放的核废料主要滞留在北太平洋海域(超过86%±1.5%的核废料在积分结束时,滞留在北太平洋),而在积分的前10 a(2021年之前),几乎所有的核废料滞留在北太平洋;在核废料的垂直分布上,主要集中在海洋表层至600 m的深度,在积分的20 a时间里,没有核废料信号扩散至1 000 m以下的深度。数值模拟的结果也表明核废料浓度减弱的强度以及演变的时间特征主要受洋流系统的影响,与排放源的排放时间长短关系不大。值得指出的是,更加准确地评估一个真实的核泄漏事故对海洋环境所造成的可能影响,还需要考虑大气中的放射性物质的沉降以及海洋生态对核物质的响应。     

Conceptual modelling to assess how the interplay of hydrological connectivity,catchment storage and tracer dynamics controls nonstationary water age estimates

Although catchment storage is an intrinsic control on the rainfall–runoff response of streams, direct measurement remains a major challenge. Coupled models that integrate long‐term hydrometric and isotope tracer data are useful tools that can provide insights into the dynamics of catchment storage and the volumes of water involved. In this study, we use a tracer‐aided hydrological model to characterize catchment storage as a dynamic control on system function related to streamflow generation, which also allows direct estimation of the nonstationarity of water ages. We show that in a wet Scottish upland catchment dominated by runoff generation from riparian peats (histosols) with high water storage, nonstationarity in water age distributions is only clearly detectable during more extreme wet and dry periods. This is explained by the frequency and longevity of hydrological connectivity and the associated relative importance of flow paths contributing younger or older waters to the stream. Generally, these saturated riparian soils represent large mixing zones that buffer the time variance of water age and integrate catchment‐scale partial mixing processes. Although storage simulations depend on model performance, which is influenced by input variability and the degree of isotopic damping in the stream, a longer‐term storage analysis of this model indicates a system that is only sensitive to more extreme hydroclimatic variability. Copyright © 2014 John Wiley & Sons, Ltd.     

Chemical and isotopic assessment of surface water–shallow groundwater interaction in the arid Grande river basin,North-Central Chile

ABSTRACT

This paper analyses the composition of surface water and shallow groundwater in the Grande River basin, North-Central Chile, using this information to characterize water interactions. Chemical and isotopic data for surface water and groundwater (7 and 6 sampling locations, respectively) were obtained from three sampling campaigns performed in March–April (autumn), August–September (late winter) and December (early summer) 2012. Precipitation samples were also collected. Data was processed using spatial distribution charts, Piper and Stiff diagrams, and multivariate analysis. In general, the results for each method converge on a high degree of connectivity between surface water and shallow groundwater in the study area. Furthermore, approximately a 10% of groundwater contribution to the surface flow discharge was estimated for a particular reach. This multi-method approach was useful for the characterization of surface water–groundwater interactions in the Grande River basin, and may become a suitable and replicable scheme for studies in arid and semi-arid basins facing similar water management challenges.

Editor D. Koutsoyiannis; Associate editor B. Dewals     

Characterising the distribution of near-shore submarine groundwater discharge along a coastline using 222Rn and electrical conductivity

The spatial and temporal distribution of near-shore fresh submarine groundwater discharge (SGD) was characterised from the coastal aquifers of the Willunga Basin, South Australia, an extensive aquifer system that supports an important viticultural region. Measurements of electrical conductivity (EC) and ²²²Rn (radon) activity were collected at 19 sites along the coastline during the Southern Hemisphere spring (2011) and summer (2013). At each site, samples were collected from the surf zone as well asporewater from beach sediment in the intertidal zone. Surf-zone radon activity ranged from <5 to 70mBq L^–1, and intertidal porewater radon ranged over two orders of magnitude (220–36 940 mBq L^–1) along the Willunga Basin coastline during both surveys. Overall, surf-zone and porewater EC was lower in the spring 2011 survey than in the summer 2013 survey. Porewater EC was similar to that of coastal water at most sites along the coastline, except at three sites where porewater EC was found to be lower than coastal water during both surveys, and three sites where evaporated seawater was observed in the summer survey. Based on the patterns in radon and EC along the coastline, two sites of localised fresh SGD were identified, in addition to a groundwater spring that is known to discharge to the coast. The results indicate that near-shore fresh SGD occurs as localised seeps rather than diffuse seepage along the entire coastline. The apparent absence of groundwater discharge at most locations is also consistent with current evidence suggesting that extensive groundwater pumping within the basin has resulted in seawater intrusion across much of the coastline. These observations also suggest that previous studies are likely to have over-estimated SGD rates from the Willunga Basin because they assumed that SGD occurred along the entire coastline.     

Wind and freshwater influence over hydrocarbon dispersal on Patos Lagoon, Brazil

The two-dimensional barotropic, hydrodynamic and transport model MOHID is applied to the Patos Lagoon system using a nested modelling approach to reproduce both the lagoon and estuary hydrodynamics. A new Lagrangian oil spill model is presented and used to simulate a hypothetical oil spill in the estuary. Hydrodynamic fields are validated and used to force the oil model. Results show that the hydrodynamics of this system is mainly controlled by the wind and freshwater discharge. The dispersion, concentration and thickness evolution of the oil in the first day after the spill is determined by the equilibrium between these two factors. The freshwater discharge is the major factor controlling the oil dispersion for discharges greater than 5000 m3 while the wind assumes control for lower discharge amounts. The results presented are a first step toward a coastal management tool for the Patos Lagoon.