氧化还原条件对红枫湖沉积物磷释放影响的微尺度分析

选取贵州红枫湖为研究对象,在实验室条件下模拟了自然、好氧和厌氧条件下沉积物内源磷的释放过程,联合应用微电极技术和沉积物磷形态分析对沉积物—水界面开展了微尺度观测与研究.结果表明,厌氧条件下红枫湖沉积物总磷含量显著降低,且主要是NaOH提取态磷(NaOH-P)和残渣态磷(rest-P)含量降低所致,厌氧条件下沉积物孔隙水中磷酸盐浓度明显升高,而好氧条件下沉积物孔隙水磷酸盐浓度显著降低,反映厌氧条件显著促进了红枫湖沉积物磷释放.厌氧条件下沉积物内部溶解氧浓度下降、硫还原活动增强可能是导致NaOH-P释放的主要原因.O_2浓度的降低加速了沉积物还原作用并产生大量H2S,进而与二价铁离子形成硫化亚铁沉淀,最终导致NaOH-P(Fe-P)释放到孔隙水中.好氧条件向厌氧条件的转换可通过改变沉积物内部pH值分布和微生物活动促使rest-P释放:厌氧条件下,厌氧微生物不仅可以消耗硫酸根产生H_2S,导致pH值降低,还可消耗有机质,将有机磷转变为无机磷.上述研究结果表明,沉积物—水界面氧化还原环境可影响沉积物氧渗透深度、pH值分布、微生物活动、硫循环以及有机质降解过程,进而控制沉积物磷的形态转化与释放.联合应用微电极技术和沉积物磷形态分析对湖泊沉积物—水界面开展微尺度观测研究是揭示沉积物内源磷释放机制与控制因素的有效途径.     

沉水植物驱动的水环境钙泵与水体磷循环的关系

水体磷循环是水柱和对应的沉积物中发生的各种非生物和生物的磷迁移转化过程.与此同时,沉积物中钙通过沉水植物吸收和转运,从该类植物的叶面释放至水柱中,释放的Ca2+与水柱中的CO23-一起形成碳酸钙.在这一过程中,水柱中少量溶解性磷分配在碳酸钙中形成CaCO3-P共沉淀,导致水体中可溶性磷向难溶性磷转化,这种由沉水植物驱动的水环境钙泵在水体磷循环中发挥着重要作用.研究证明,沉水植物菹草叶面上有CaCO3-P共沉淀的形成,且这种共沉淀的含磷量变化范围很宽.另一方面,新近沉积物中钙与磷的沉淀物存在一个由聚磷酸盐向磷灰石逐渐演变过程,而沉水植物叶面上的含磷共沉淀作用是否也存在由聚磷酸盐向磷灰石的变质过程,该过程在沉水植物生长期间是否发生关系到沉水植物除磷效果值得深入研究.本文从水体磷循环概述、钙在水体磷循环中的作用和沉水植物驱动的水环境钙泵假说及其在水体磷循环中的意义等方面综述了钙在水环境中的迁移对水体磷循环的贡献.     

STUDY ON RELATIONSHIP BETWEEN THE ACTIVITY OF MIYALUO FAULT AND WENCHUAN EARTHQUAKE SEQUENCE

Under the background of thrusting stress regime, a large number of strike-slip earthquakes occurred on the Miyaluo Fault during the Wenchuan earthquake sequence process, which is in the southern part of the Longmenshan Fault. In order to find the cause of their occurrence, stress tensors in subregions near the Miyaluo Fault are estimated. The result shows that in both north and south side of the Miyaluo Fault, the direction of principal compressive stress is nearly perpendicular to the Longmenshan Fault, and its dip is nearly horizontal, and the direction of tensile stress is nearly vertical. While in the Miyaluo fault zone, the direction of principal compressive stress is SWW-NEE, and its dip is nearly horizontal, the direction of principal tensile stress is NNW-SSE, also its dip is nearly horizontal. It is consistent with sinistral shear stress state in the Miyaluo fault zone. It was referred that the behavior of Miyaluo Fault during the Wenchuan earthquake sequence process was caused by tearing effect generated from unbalanced forces of two sides of the fault. To understand the rupture mode of the aftershocks in subregions as described above, the total seismic moment tensors are estimated by adding the corresponding component separately of the seismic moment tensor of aftershocks in each region. The result shows the similar trend of total seismic moment tensor components in the north and south side of the Miyaluo Fault(indicating the consistency of rupture mode in the north and south side of the Miyaluo Fault), and most seismic moment tensor components in the south side is higher than that in the north side, especially the compression component perpendicular to Longmenshan Fault and expansion component in the vertical direction. It indicates that thrusting component in the southeast direction in the south side is greater than that in the north side, and the thrusting difference causes the sinistral tearing effect of the Miyaluo Fault. We also find that the sinistral tearing component of the Miyaluo Fault is the same order of magnitude with the thrusting difference of its two sides, which indicates that the tearing effect of Miyaluo Fault can be completely explained by thrusting difference of its two sides. According to the analysis, we put forward the dynamic model of the Miyaluo Fault, which can explain the above phenomenon.     

不同供氧方式对水库底泥氮磷释放的影响

采用实验室模拟试验,研究了三种供氧方式——曝气、投加过氧化氢和投加过氧化钙对水库底泥氮磷释放的影响.研究结果表明:(1)溶解氧是控制底泥氮磷释放的重要因素,厌氧条件能加速底泥释放磷和氨氮;(2)曝气、投加过氧化氢和投加过氧化钙均能显著提高底部水体的溶氧水平,并能有效抑制底泥氮磷的释放.三种供氧方式对底泥释磷的控制效率依次为:投加CaO2>曝气>投加H2O2;对氨氮释放的控制效率则为:曝气>投加CaO2>投加H2O2.     

强震前地磁总场F02测值的空间相关特征研究

收集全国102个地磁台站2008年至2015年数字化地磁资料, 运用地磁空间相关法计算每日凌晨02时各台站地磁总场F之间的空间相关系数。 在使用相同的异常判别标准的情况下, 研究时段的17个中强地震中发现在2009年9月19日陕西宁强5.1级地震, 2011年11月1日四川青川5.4级地震, 2013年1月23日辽宁灯塔5.1级地震, 2013年7月22日甘肃岷县6.6级地震和2013年10月31日吉林前郭5.5级地震前均具有较为明显的空间相关低值异常现象。 通过总结5个震例的异常特征, 笔者发现其异常形态极其相似, 且平均的异常持续时间为20天, 而地震就发生在异常开始后3个月内; 同时, 地震发生在异常集中区中心附近, 且这个异常区域大小在500 km左右。 这一研究结果对于进一步分析地震前地磁空间相关异常特征积累了丰富的资料。     

基于多格网算法的卫星图像恢复

将求解二次椭圆偏微分方程问题的多格网算法应用到卫星影像的恢复中。其基本思想是在将由总变分求极小生成的偏微分方程离散成为差分方程的过程中,采用不同大小的格网。在取得较好恢复结果的同时,提高了传统图像恢复算法的运算效率,降低了恢复运算所需要的时间。     

1997年3月9日漠河日全食外日冕结构及相对强度分布

利用简单的视频图像采集系统 ,对 1 997年 3月 9日用PanasonicNV -S880EN型摄像机拍摄的黑龙江漠河日全食黄光 (加GG1 1滤光片 )和白光日冕观测资料进行计算处理 ,得到大于 1 .5R⊙ 的太阳活动低年外日冕结构及其相对强度分布。     

Annual Variation of Benthic Nutrient Fluxes in Shallow Coastal Waters (Gulf of Trieste, Northern Adriatic Sea)

Abstract. Benthic fluxes of dissolved N. Si and P nutrients, alkalinity, dissolved inorganic C (DIC), and O₂ from sediments in the Gulf of Trieste (northern Adriatic, Italy) were measured monthly for 16 months, using laboratory incubated flux chambers at in siru temperatures in the dark. The annual average fluxes were: 02 = -19.3 ± 8.2, DIC = 13.7 ± 9.6, NO3 = -0.04 ± 0.16, NH4 = 0.3 ± 0.4. PO₄= 4.001 ± 0.01, Si = 0.9 ± 0.1 mmol m-² d^-1, with strong temporal fluctuations. The highest effluxes of all nutrients and DIC were observed in the summer. Small effluxes of DIC and NH4 and influxes of Si and PO4 were observed in late winter. Only NH₄ (ca. 50%) and Si (ca. 70%) fluxes were significantly correlated with temperature. This correlation suggests that the rate of downward input and the quality of sedimented organic matter (autochthonous and allochthonous) were superimposed on the temperature fluctuations. High DIC, NH₄ and Si effluxes observed in May 1993 during low temperature were due to the degradation of sedimentary organic matter produced by an early spring bloom of benthic microalgae which occurred about 6 weeks earlies while the autumn phytoplankton bloom was simultaneously reflected in enhanced benthic fluxes due to higher temperature. The role of benthic biological advection in this transport across the sediment-water interface, evaluated by comparison between measured benthic and calculated diffusive fluxes from nutrient pore water concentrations, was of minor importance. This is probably due to low infaunal activity throughout the year it was localized mostly in the narrow surficial layer. The annual average diffusive fluxes of NH4 and PO4 were higher than those measured, probably due to the presence of nitrificationdenitrifi-cation processes and redox-dependent chemical reactions at the oxic sediment-water interface, respectively. Only during bottom-water hypoxia in September 1993 did strong PO₄ effluxes prevail. Calculations based on the Redfield stoichiometry of oxic decomposition of organic N to NH4 and NO3, and differences between diffusive and measured NH₄ fluxes showed that denitrifkation averaged 0.8 mmol m^-2 d^-1. Significant correlations between NH₄ and PO₄ DIC and Si, and NH4 and Si fluxes suggested their parallel regeneration and utilization at the sediment-water interface. The nutrient fluxes observed were not significantly linked to O₂ consumption, suggesting also that anaerobic oxidation processes were important at the sediment-water interface in the gulf. The N, P and Si nutriqnts released from sediment pore waters are probably utilized in benthic microalgal and bottorn-hater primary production. This indicates that pelagic and benthic communities in the central part of the Gulf of Trieste function relatively independently of each other.     

中国南极长城湾及附近海区1993/1994年夏季表层水样无机氮、磷酸盐的浓度及其分布状况

1993／1994年南极夏季对中国南极长城湾及附近海区表层海水四种营养盐浓度及其分布状况作了调查。结果表明，NH4－N、NO3－N、NO2－N及PO4－P的大致浓度分别是2．13、7．07、0．74和1．12μg·dm-3。一般来说，湾内高于湾外氮盐于12月份常出现高值。四种形态的无机盐类之最高、最低浓度出现的时间和站位不尽一致。∑N／P递减次序大致是12月，2月，1月。水温变化与NH4－N、PO4－P浓度和∑N／P的变化常较一致，而与NO2－N则常不一，一些站位上营养盐浓度偏低可能与浮游植物摄取有关。结果显示了调研海区的浅水内湾特征。浮游植物所需营养充分。该湾仍维持正常状态。     

Periodicities in Global Mean TEC from GNSS Observations

As an important measurement parameter, global total electron content (TEC) is appropriate for the study of the Sun–Earth connection. In this paper, the wavelet technique is employed to investigate the periodicities in global mean TEC during 1995–2008. Analysis results show several remarkable components (including 27-day, semiannual and annual cycles) existing in global mean TEC with obvious time-variable characteristics, besides 11-year cycle. After analyzing sunspot numbers and solar extreme ultra-violet (EUV) radiation variations during this time period, except for semiannual variations, close correlation between global mean TEC and solar variations is found, especially, a strong resemblance of the 27-day fluctuation exists in global mean TEC, sunspot and solar EUV radiation variations.