总磷作为饮用水生物稳定性控制指标的研究

根据国内提出的控制饮用水生物稳定性的可同化有机碳(AOC)标准,通过配制水样研究了AOC及细菌再生长潜力(BRP)同水中磷含量的关系;同时针对净水工艺试验出水水样,考察了水中的磷同其生物稳定性的关系。结果表明,对于配水水样,在一定的磷浓度范围内,磷是水中细菌生长的限制因子;在净水试验工艺出水水样中添加50μg/L的PO₄3--P后,AOC增加了55%,BRP增加了123%,表明水中磷是其生物稳定性的限制因子。由于常规的净水工艺对水中的磷可以有效去除,把水中总磷(TP)控制在5μg/L内来提高饮用水生物稳定性具有一定的可能性和现实性。     

Chemical analyses of campbell Island fresh waters

Ten samples of freshwater from Campbell Island were analysed for their main ionic constituents. All show a preponderance of sodium and chloride derived from sea water. Potassium, calcium, and magnesium gave slightly higher concentrations than would be expected if derived solely from sea water. It is con‐eluded that the excess potassium is derived from the underlying rocks and soil, and the excess calcium and magnesium from the sea by fractionation into salt particles.     

The total operating characteristic to measure diagnostic ability for multiple thresholds

The relative operating characteristic (ROC) is a popular statistical method to measure the association between observed and diagnosed presence of a characteristic. The diagnosis of presence or absence depends on whether the value of an index variable is above a threshold. ROC considers multiple possible thresholds. Each threshold generates a two-by-two contingency table, which contains four central entries: hits, misses, false alarms, and correct rejections. ROC reveals for each threshold only two ratios, hits/(hits + misses) and false alarms/(false alarms + correct rejections). This article introduces the total operating characteristic (TOC), which shows the total information in the contingency table for each threshold. TOC maintains desirable properties of ROC, while TOC reveals strictly more information than ROC in a manner that makes TOC more useful than ROC. We illustrate the concepts with an application to land change science.     

原子荧光测定食品中总砷方法的改进与探讨

针对国标《GB 5009.11—2003食品中总砷及无机砷的测定》中的原子荧光-湿法消解测定总砷的方法中存在的难于控制完全消解样品、测定结果不稳定,试剂用量大的问题,对原方法进行了3点改进。一是利用浓硫酸沸点高,能脱水碳化破坏有机物的特性,通过高温浓缩硫酸对样品进行两次脱水碳化消解,使样品消解的更完全,且节省试剂;二是针对样品中砷形态的多样性,加强温度控制,低温消解、降低易挥发砷化合物的损失,高温加速样品消解,缩短操作时间;三是加盖小漏斗制造回流,减少易挥发砷化合物的损失,使方法易操作、节省试剂。用改进的方法测定菠菜粉(GBW10015)、海带粉(GBW08517)和虾粉(CNAS T0442)中的总砷,不少于6个平行样的测定结果均位于参考值范围的中间部分,且RSD值均小于7%,表明改进的方法准确、稳定。结果还表明,200℃的硫酸、高氯酸的混合酸和高温浓硫酸均能有效消解样品中砷甜菜碱和砷糖类化合物。     

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高精度边角网数据采集与处理系统的设计与实现

在水利、桥隧等工程施工和形变监测中,特别是在山区,GPS网的精度往往不能满足设计要求,一般需要布设地面边角网,采用高精度智能型全站仪进行数据的采集。本文从一体化测量作业模式的设计思想出发,基于VB．NET和数据库技术,研究设计了高精度地面边角网外业数据采集与处理系统,实现了边角数据的自动化采集和处理。     

混合LS-TLS的GM（1,1）模型在基坑水平位移监测中的应用

通过分析传统GM（1,1）模型的局限性,提出了混合整体最小二乘法（混合LS-TLS）的GM（1,1）模型,并将其应用于宁夏某深基坑水平位移的监测中。同时,将此模型与最小二乘法（LS）的GM（1,1）模型及整体最小二乘法（TLS）的GM（1,1）模型进行了对比,分析了3种模型所求水平位移的预测值。结果表明,混合LS-TLS的GM（1,1）模型更符合工程实际,预测精度更高,在深基坑水平位移监测中具有一定的实用性。     

基于比例整体最小二乘的GPS高程拟合

针对GPS高程拟合过程中GPS基线观测量和水准高程观测量含有误差且残差中误差不相同的情况,在整体最小二乘(TLS)基础上引入比例因子λ来确定残差中误差的大小,即比例整体最小二乘(STLS)。实例计算表明,STLS比TLS和LS能够得到更好的估计参数,高程异常值拟合精度也相应提高。     

基于验后方差估计的稳健整体最小二乘方法

根据整体最小二乘的验后方差估计,求出观测值的验后方差,通过方差检验可找出方差异常大的观测值。然后根据经典权与观测值方差成反比的定义赋予它一个相应小的权进行下一步迭代平差,逐步实现粗差定位。通过坐标转换实验,利用一般最小二乘法(LS)、加权整体最小二乘法(WTLS)以及文中提出的稳健整体最小二乘法(RTLS)分别对待估参数进行求解对比,解算结果表明文中提出的方法能对粗差进行有效的定位,且估计量受粗差影响较小,具有稳健性,估算效果优于其它两种方法。     

Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.