Temporal and spatial variations in the biogeochemical cycling of cobalt in two urban estuaries: Hudson River Estuary and San Francisco Bay

Despite the fact that Co is an essential trace element for the growth of marine phytoplankton, there is very limited information on the cycling of this trace metal in the marine environment. We report here the distribution of dissolved (<0.4 μm) and particulate (>0.4 μm) Co in surface waters of the Hudson River Estuary (HRE) and San Francisco Bay (SFB). Samples were collected during several cruises (from 1990 to 1995 in SFB and from 1995 to 1997 in the HRE) along the whole salinity gradient. Dissolved Co concentrations (mean±1 standard deviation) were nearly identical in magnitude in both estuaries despite differences in climate, hydrography, riverine-flow conditions and land-usage (HRE=0.91±0.61 nM; SFB=1.12±0.69 nM). Dissolved Co levels in each system showed non-conservative distributions when plotted as a function of salinity, with increasing concentrations downstream from the riverine end-members. Desorption from suspended particulates and sewage inputs, therefore, seems to be the major processes responsible for the non-conservative behavior of Co observed. Mass balance estimates also indicated that most of the estuarine Co is exported out of both estuaries, indicating that they and other estuarine systems are principal sources of this essential trace element to the open ocean.     

协方差阵二次型容许估计的一个必要条件

研究协方差阵Σ的二次型容许估计问题。设 y1,y2 ,… ,yniid,n≥ 2 ,y1与 p维正态分布N (β,Σ )有相同的前四阶矩。其中β =(β1,β2 ,… ,βp)′∈ Rp与Σ =(σij) p× p >0均未知。记 y =△ (y1,y2 ,… ,yn)′。在二次损失 L (d ,Σ ) =tr(d -Σ) 2下给出Σ的二次型估计 a S2 + nby-y-′是容许估计的必要条件为 :(n - 1) a + b + 2 max(a,b)≤ 1。此必要条件比张立振等协方差阵的二次型容许估计中的必要条件有了明显的加强     

北黄海盆地区域地质特征

北黄海盆地位于黄海的北部，由于勘探程度低，研究投入少，使得它成为我国迄今为止尚未发现油气的惟一海区。随着我国在南黄海盆地和朝鲜在北黄海盆地东部发现油气，如何实现北黄海盆地油气突破，成为我们研究的焦点。结合该区现有资料和前人研究成果，对北黄海盆地的地球物理场和地质构造特征进行了全面的论述，并在此基础上，对该区油气资源远景作了初步评价。     

Carbon stable isotopes in estuarine sediments and their utility as migration markers for nursery studies in the Firth of Forth and Forth Estuary, Scotland

The stable carbon isotope ratios (δ¹³C) of the organic fraction of intertidal sediments in the Forth Estuary and the Firth of Forth, Scotland, were measured to determine if terrestrially derived carbon was present in the estuarine sediments. It was hypothesised that differences in the inputs from marine vs. terrestrial sources to the organic carbon of estuarine and marine sediments, as well as differences in ambient seawater stable oxygen isotope (δ¹⁸O) ratios between the estuary and the Outer Firth, would allow the use of these two stable isotopes as habitat markers for juvenile plaice (Pleuronectes platessa), to allow determination of nursery habitats. Muddy and sandy sediments from the estuary and sandy sediments from the Outer Firth were sampled and δ¹³C measured. Juvenile plaice were caught at two estuarine sites and at two Outer Firth sites and otoliths were removed for δ¹³C and δ¹⁸O analysis. The sandy sediments in the estuary showed a strong gradient of δ¹³C enrichment with distance down the estuary, while the muddy sediments showed a much shallower gradient. δ¹³C and δ¹⁸O measured in the carbonate of juvenile plaice otoliths showed no clear difference between otoliths of fish caught at one of the estuarine sites and at the two Outer Firth sites. However, the isotope ratios of both carbon and oxygen in plaice otoliths from the other estuarine site showed the expected trend of depletion in the heavier isotopes. While the measurements recorded here did not conclusively distinguish between otoliths from juveniles caught in the estuarine site and those caught in the other three sites, they show that stable isotopes have potential to distinguish between estuarine habitats with terrestrial carbon inputs, and coastal marine habitats with predominantly marine carbon inputs.     

Experimental activities that intentionally perturb the marine environment: Implications for the marine environmental protection and marine scientific research provisions of the 1982 United Nations Convention on the Law of the Sea

The global community's ability to assess the environmental effects of marine scientific research (MSR) as required by the 1982 United Nations Convention on the Law of the Sea's (UNCLOS) marine environment provisions (MEP) is limited, as shown by experimental activities that intentionally manipulate the marine environment. Such work enhances knowledge of the ocean, but it may also have significant environmental effects. This growing use of the ocean as a laboratory has global scientific, environmental, legal and policy implications. Examined here is the relationship between the MSR and the MEP provisions of UNCLOS. International, science-driven guidelines are proposed.     

杭州湾乍浦断面潮流分布特征

根据2000年9月在杭州湾乍浦断面设置的8个潮流同步观测站的资料,对该断面潮流分布特征进行了分析和探讨,结果表明:该断面大潮涨急时呈现两个大流速核;断面南部的流速要比北部的大,涨潮流速大于落潮流速。这对了解杭州湾水文特征有着一定意义,同时为杭州湾跨海大桥的设计建设提供参考。     

化学生态调控对鳌山湾氮磷营养盐的影响

鳌山湾,是一个营养类型特殊的海湾,湾中基本无径流输入,呈“C”字形,封闭性较强,水较浅,湾内主要有筏式扇贝养殖和底播贝类养殖,沿岸有滩涂池塘养殖.根据1996年11月至1998年5月的调查结果得知,鳌山湾海域为贫营养海域[1,2].为探讨贫营养海域进行化学生态调控的可能性,利用鳌山湾的封闭性,根据其水交换规律[3],于1999年6月首次对鳌山湾进行了全湾规模较大的化学生态调控试验,旨在有效提高鳌山湾的营养水平,为今后在贫营养海域合理发展海水养殖业提供科学依据,获得了十分理想的效果.     

黄河三角洲河道沉积规律研究Ⅱ. 建林边滩沉积作用机理

通过对建林边滩沉积物粒度分布、粒度参数及水体流变性质的分析，阐述了黄河三角洲上河道水流属于牵引流范畴，与低含沙水流无本质上的差别，并探讨沉积物搬运和沉积的基本特征。     

北部湾三维风生流及密度流模拟

将Casulli差分格式引入三维物理海洋模型计算，模拟了北部湾风生流及密度流。模拟结果表明，夏季西南季风在北部湾导致一个顺时针环流，夏季海水密度梯度导致一个逆时针方向的环流，密度流明显强于风生流；冬季东北寒潮导致一个逆时针环流。模拟结果不支持北部湾夏季为一顺时针环流、冬季为逆时针环流的传统结论，而支持终年为逆时针环流的观点。     

福建闽江口外海岸植物生态

记录了福建闽江口266种海岸高等植物,其中草本占70.2%、灌木占21.4%、藤本和乔木占8.4%.喜盐种在河口的内侧、中区和外侧占总数的百分比分别为5.7%,6.8%和11.8%.二叶红薯、南方碱蓬和番杏是盐碱土的指示种.在内侧近淡水区有繁茂的咸水草、芦苇和芦竹