GPS测时在电力系统中的应用

介绍了利用GPS测时及时间传递的几种方式，详细地讨论了GPS用在电压相角测量，输电线路故障定位以及线路网损和电能结算系统几个方面的应用原理，设计出应用的方案，并得到部分结果。     

氢化物发生—原子荧光光谱法测定煤样中的硒

采用氢化物发生原子荧光光谱法测定了煤样中的总Se。煤样选用高压闷罐强酸消解的方法进行处理，所得消解液经6mol/L HCl将Se（Ⅵ）还原为Se（Ⅳ），然后进行测定。标准工作曲线的线性范围为0－400μg/L Se，检测限为0.4μg/L Se。用标准参考物质煤飞灰对方法进行了验证，所得总Se含量与标准值相符，对ω为10^-6级Se的4次测定，RSD≤4.5％。     

ARL 8680型X荧光光谱仪的非自动高压校正

通过实验，介绍如何设计X荧光光谱仪中测角仪检测器的非自动高压校正的方法。     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.     

Preliminary Study on the Chemical Mapping of Individual Fluid Inclusion by Synchrotron X-ray Fluorescence Microprobe

Abstract: Synchrotron X-ray fluorescence analyses on individual hypersaline fluid inclusions were tested to using synchrotron source at Tsukuba (KEK), Japan. The XRF instrumentation at KEK meets the purpose of fluid inclusion analysis, nondestructive, multi–element, ppm detection limits, with micro spatial resolution. In practice, however, the quantitative chemical analysis of fluid inclusion requires further considerable data accumulation. Semi-quantitative distribution of elements (mass number > 25) in single fluid inclusion was obtained.     

激光荧光遥感系统在地物识别上的应用研究

应用我国自行研制组装的激光荧光遥感系统,测试了包括岩石、土壤、植物、水体以及人工建筑材料在内的各种样品的激光诱导荧光光谱。研究结果表明,应用地物荧光峰的位置、强度及它们的组合指标,不仅能区分上述各基本类型的地物,而且还能往下级单元续分。还表明,激光荧光遥感系统具有相当广泛的应用前景,在某些方面可望超过当前常用的、以反射光谱为基础的被动式遥感。     

X射线荧光探矿技术在福建紫金山铜矿区的应用效果

应用放射性同位素x射线荧光分析仪测定各种元素含量在许多文献中均有报道。本文主要介绍84A86型轻便x射线荧光分析仪首次在福建省紫金山铜矿区测定粉末样、块状岩心、坑道壁中铜矿的含量及其所取得的经济效益。     

染料交换荧光分光光度法测定地球化学样品中痕量铊

研究表明，在Ｈ３ＰＯ４介质中，丁基罗丹明Ｂ可从乙酸异戊酯有机相中的［Ｔ１Ｂｒ４］＾－－结晶紫缔合物中置换结晶紫而形成新的离子缔合三元荧光络合物。详细考察了该络合物形成的最佳条件、荧光特征及萃取溶剂等，制定了地球化学样品中痕量Ｔ１的荧光光度测定新方法，其检出限０．００５μｇ／ｍｌ．Ｔ１量在０－０．５μｇ／ｍｌ范围与荧光强度呈正比。测定了含Ｔ１量０．６１－１．９μｇ／ｇ的８个一级地球化学标样，结果相符     

Distribution of ionospheric O<Superscript>+</Superscript> ion in synchronous altitude region

Based on satellite observation data, using dynamics equation, the ionospheric O⁺ ion’s distribution in the synchronous altitude region for different geomagnetic activity indexK _p is studied by theoretical modeling and numerical analyzing, and semi-empirical models for the O⁺ ion’s density and flux versus longitude in the synchronous altitude region for differentK _p are given. The main results show that in the synchronous altitude region: (i) The O⁺ ion’s density and flux in day-side are larger than those in nightside. (ii) With longitude changing, the higher the geomagnetic activity indexK _p is, the higher the O⁺ ion’s density and flux, and their variation amplitude will be. The O⁺ ion’s density and flux whenK _{p ≥} 6 will be about ten times as great as that whenK _p = 0. (iii) WhenK _p = 0 orK _{p ≥} 6, the O⁺ ion’s density reaches maximum at longitudes 120° and 240° respectively, and minimum in the magnetotail. WhenK _p = 3−5, the O⁺ ion’s density gets to maximum at longitude 0°, and minimum in the magnetotail. However, the O⁺ ion’s flux reaches maximum at longitude 120° and 240° respectively, and minimum in the magnetotail for anyK _p value.     

X射线荧光光谱分析检出限问题的探讨与建议

对有关X射线荧光光谱分析低含量元素的检出限问题进行了多方面的探讨。从检出限的定义及其定义下的相对标准偏差到各种不同测量、校准与校正方法的检出限及其相对应的相对标准偏差进行计算。提出了以定义检出限的相对标准偏差为基准,对各种测量方法计算出的检出限进行重新界定,从而确认一个具有可比性的、精度一致的检出限。同时还讨论了仪器与X光管固有杂质元素谱线对该元素检出限的影响;测量仪器、测量条件与测量时间对检出限的影响;不同岩性试样对检出限的影响;检出限与测定限等问题。