四川雪宝顶W-Sn-Be矿床中矿物化学组成及矿床成因

雪宝顶矿床位于四川省的松潘甘孜造山带中,以出产大颗粒含W-Sn-Be-F-P的矿物而闻名,前人对该矿床已经开展了大量的研究,但缺乏对粗粒矿物的主次痕量元素研究.本次研究采用X射线荧光光谱(XRF)、电子探针(EMPA)和电感耦合等离子体质谱(ICP-MS)技术对矿床中各矿物的主次痕量元素进行测试分析.结果显示,雪宝顶矿...     

Field experiments of multi-channel oceanographic fluorescence lidar for oil spill and chlorophyll-a detection

A Multi-channel Oceanographic Fluorescence Lidar (MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll-a (Chl-a), has been developed using the Laser-induced Fluorescence (LIF) technique. The sketch of the MOFL system equipped with a compact multi-channel photomultiplier tube (MPMT) is introduced in the paper. The methods of differentiating the oil fluorescence from the background water fluorescence and evaluating the Chl-a concentration are described. Two field experiments were carried out to investigate the field performance of the system, i.e., an experiment in coastal areas for oil pollution detection and an experiment over the Yellow Sea for Chl-a monitoring. In the coastal experiment, several oil samples and other fluorescence substances were used to analyze the fluorescence spectral characteristics for oil identification, and to estimate the thickness of oil films at the water surface. The experiment shows that both the spectral shape of fluorescence induced from surface water and the intensity ratio of two channels (I ₄₉₅/I ₄₀₅) are essential to determine oil-spill occurrence. In the airborne experiment, MOFL was applied to measure relative Chl-a concentrations in the upper layer of the ocean. A comparison of relative Chl-a concentration measurements by MOFL and the Moderate Resolution Imaging Spectroradiometer (MODIS) indicates that the two datasets are in good agreement. The results show that the MOFL system is capable of monitoring oil spills and Chl-a in the upper layer of ocean water.     

三种验潮方法水位观测性能比较与统计分析

水尺、压力式验潮仪与验潮井验潮仪是海道测量水位控制和水位观测的主要手段。通过6日6个时间段的同步比对试验,计算了三种方法获取水位观测数据之间的潮时差和潮高差,分析了三种观测手段的水位观测性能以及产生差值的可能原因,提出了使用方法的建议。     

红石泉铀矿床黑云母与晶质铀矿同步富集作用探讨

红石泉铀矿床是以岩浆气成热液成矿作用占主导地位的复成因型铀矿床。研究结果表明,黑云母的结晶时间明显晚于伟晶状白岗岩中的长石、石英等主要造岩矿物,这是由白岗质 岩浆本身的物质成分和物理化学条件所决定的。岩体边缘的黑云母与晶质铀矿同步富集作用是以元素地球化学和矿物热力学作用为主导的地质作用。黑云母与晶质铀矿结晶时间相近,具有一定的成因联系,并且,其组份具有明显的亲缘性是二者密切共生的原因。     

CHLOROPHYLL FLUORESCENCE RATIO F685/F735 IN BROWN ALGAE AND ITS VARIATION UNDER EXCITATION BY TWO TYPES OF LIGHT AND DEHYDRATION

Calculation and comparative study of the chlorophyll fluorescence ratio F685/F735 in brown algae (Laminaria japonica, Underia pinnatifida and Padina crassa) excited by blue and green light showed that the fluorescence ratios were higher when the algae were excited by blue light (440 nm), but reduced obviously under green light (540 nm) excitation. The values also reduced under dehydration but could recover during rehydration if the stress was not serious. The variation of the fluorescence ratio under dehydration was mainly because changes in fluorescence emission at 735 nm were always sharper than those at 685 nm. The ratio was sensitive to stress and has potential as a stress indicator in phycological research. Measurement of the fluorescence excitation spectra showed that the only peak at 540 hm changed apparently during dehydration. It meant that the function of the Chl a /Fucoxanthin protein complex for energy transfer was easily inhibited by water stress. However, no variation of the ratio was foun     

X射线荧光技术用于西秦岭地区金矿勘查

本文根据用轻便型X射线荧光仪在西秦岭数个金异常区测量金的伴生元素——砷的荧光强度,间接找寻金矿的实践,阐明用该仪器可快速圈定金矿远景区和揭示隐伏金矿体,提高找矿效果。并对使用X射线荧光技术进行现场测量及配合金异常查证工作,作了初步探讨。     

X射线荧光光谱仪的性能检验

本文介绍了理学3080E型X射线荧光光谱仪性能检验的主要项目,说明了测量方法和技术指标。     

吉林腰英台油田油水分布特征及成因探讨

腰英台油田是东北地区新发现的油田，目前刚开始勘探开发，在勘探开发初期遇到不少问题。其中之一是开采时高含水：就油田的实际油水分布特征进行了分析，分析油水同出的可能原因，认为这是受油藏储层物性及构造幅度和实际油柱高度的影响，由于储层低孔、特低渗。实际构造幅度低，实际油柱高度大多低于油藏产纯油所需的油柱高度，致使油藏大都处于油水过渡带。故开采时多含水，油水同出。根据这一分析，认为进一步的油气勘探重点考虑西部水下冲积扇的有利部位。此处储层物性好，有利于接受更多油源。     

A method to estimate hydraulic conductivity from bulk geochemical compositions

A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field. In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study.     

原子荧光光谱分析环境样品中砷锑铋汞易出现的问题及解决方法

针对原子荧光光谱法测试砷锑铋汞中易出现的仪器空白不稳定、样品制备及仪器污染等问题，总结出相应的解决方法。