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Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)63+ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation. 相似文献
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Stephanie de Villiers 《中国地球化学学报》2006,25(B08):146-146
Acidification is considered the most important one of the primary chemical stress factors that impact on freshwater ecosystems. In unpolluted freshwater systems, the primary controls on the degree of acidification are factors such as the geological substrate of the catchment area, the presence of organic acids secreted by vegetation in the river system, and equilibrium exchange of carbon dioxide with the atmosphere. Anthropogenic factors that can impact on the degree of acidification of freshwater systems include agricultural, mining and industrial activities, either through direct runoff into river systems or through deposition of atmospheric pollutants from these sources. The capacity factors alkalinity and acidity, which represent the acid- and base-neutralizing capacity (ANC and BCN) of an aqueous system, have been used as more reliable measures of the acidic character of freshwater systems than pH. Unlike pH, ANC and BNC are not affected by parameters such as temperature and pressure. Therefore, ANC has been employed as a predictor of biological status in critical load assessments. Freshwater systems with ANC's eq/L isμeq/L are considered sensitive to acidification, ANC=0 μbelow 150 commonly used as the predictor for fish species such as trout in lakes, and an eq/L as more realistic for streams. Acid-neutralizing capacity μANC value of 40 (ANC) can be determined by titration with a strong acid to a preselected equivalence point. Alternatively, it can be calculated as the difference between base cations ([BC]) and strong acid anions ([SAA]): ANC=[BC]- [SAA]=[Ca^2+]+[Mg^2+]+[Na^+]+[K^+]-[SO4^2-]-[NO3^-]-[Cl^-] To date, there has been no attempt to establish the ANC of South Africa's freshwater ecosystems or variability therein, despite the fact that long-term water quality monitoring data exist for all the parameters needed to calculate it according to the above equations. As a result, the relationship between the acid neutralizing capacity of freshwater ecosystems in South Africa and biodiversity factors, such as fish status, is unknown. Results of the first comprehensive (country-wide scale) evaluation of the acid neutralizing capacity of river systems in South Africa will be presented. Long-term monitoring data obtained from the Department of Water Affairs and Forestry (DWAF) from most of South Africa's river systems were used to establish geographic and temporal variabilities in ANC. The results show that the Berg and Breede River systems are most susceptible to acidification, and that geological substrate appears to explain most of the geographic variabilities observed. 相似文献
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Habib Ben Hassine 《Comptes Rendus Geoscience》2006,338(5):329-340
The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca++, Mg++ and K+ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006). 相似文献
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通过对邯郸市某车间地基的勘察.分析和探讨了新近沉积粉细砂地层的勘察手段、其物理力学性质,及其利用载荷试验确定承载力的标准取得了较为满意的结果,提出的一些分析方法,对新近沉积的粉细砂地层的勘察具有一定的借鉴作用。 相似文献
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历来对半胶结泥质岩风化等级划分都带有许多主观性,从而影响提承载力,有的规范要求可不对半胶结岩石进行风化程度划分,但有时要对这些岩石进行工程地质细分,从而准确确定各分层的承载力与摩阻力。统计了合肥、六安、淮南、安庆地区等大量实践资料,用标准贯入击数、重型圆锥触探实验击数等原位测试手段来划分泥质岩风化等级,并对泥质岩的承载力与摩阻力等工程地质性质做出了评价。 相似文献
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我国水资源承载力研究现状及展望 总被引:1,自引:0,他引:1
概要说明了我国水资源承载力的研究现状,阐述了水资源承载力的概念、内涵及影响因素,探讨了目前几种常用的水资源承载力评价方法,并对当前研究中存在的问题进行了初步分析,进而提出了我国水资源承载力的研究趋势。 相似文献