冀东平原土壤重金属元素的存在形态及有效性分析

通过对冀东平原根系土中8种重金属元素形态含量的统计与分析,总结出其形态组成特征,初步分析了各重金属元素在土壤中的地球化学行为。笔者运用相关性分析方法,对重金属元素有效态含量与全量及土壤pH、TOC的相关性进行分析,从而得出重金属元素有效态含量的高低不仅受其全量的影响,而且与土壤pH、TOC亦有密切关系,这为表层土壤重金属元素污染程度的科学合理评价提供了理论依据。     

金矿中的黄铁矿标型特征

黄铁矿是金矿中最常见的金属矿物,它不仅与金的矿化有着密切联系,而且还是主要的载金矿物.通过对黄铁矿的形态、物性、主成分及微量元素等标型特征的研究,可反映金矿床的不同成因,也是预测成矿远景地段、指导深部找矿的有效方法之一.文章对黄铁矿在金矿中的标型特征进行了归纳总结,以期对金矿床的勘探有一定的指导意义.     

扫描电镜-X射线能谱仪在丹巴地区铂族矿物物相特征分析中的应用

丹巴地区铜镍硫化物铂族矿床品位低、铂族矿物颗粒细、铂族元素间的类质同象普遍,此类铂族资源的赋存状态研究及矿石的选冶长期以来都是较为棘手的问题。本文采用扫描电镜-X射线能谱仪器组合,对丹巴铜镍硫化物铂族矿床中含量达到1‰的元素进行快速的定性/定量分析,研究了铂族矿物原位的赋存状态和形貌特征。通过扫描电镜观察到该矿床的铂族矿物主要为砷铂矿、锑钯矿、碲锑钯矿,其次以自然铂、硫砷铑矿、硫砷铱矿,呈椭圆状、纺锤状等形式赋存于黄铁矿、磁黄铁矿及蛇纹石中,部分以类质同象的形式存在,极少量的铂与钯元素呈固溶体形式存在。X射线能谱分析表明该矿床中主要的铂族元素为Pt、Pd,其次为Ru、Rh、Ir、Os; 点分析表明砷铂矿中Pt的含量为52.84%,锑钯矿中Pd的含量为45.15%; 线扫描和面扫描分析表明铂族元素主要分布在含铁的硫化物中,Pt、Pd等铂族元素的含量与铁、镍的含量成正相关关系,反映了丹巴地区铂族元素亲铁、亲镍、亲硫的地球化学特征。     

新月形沙丘迎风坡形态及沉积物对表面气流的响应

对孤立新月形沙丘迎风坡风速的野外实测和计算表明,沙丘迎风坡表面风速廓线呈非对数关系,近地面剪切风速和输沙强度由坡脚至丘顶总体呈递增趋势,但同时随断面坡度的增减而发生相应的变化;沿断面输沙率的变化导致蚀积强度的改变,表现为沙丘迎风坡坡度变缓的部位沉积大于侵蚀,其它部位侵蚀大于沉积,其中丘顶输沙率和侵蚀强度最大。在沙丘形态上,表现为坡度减缓的部位沉积变凸、其它部位因侵蚀变凹以及坡脚和丘顶的前移。变凸和变凹部位反过来又制约着表面剪切风速的相应变化。粒度分析也表明,沙丘迎风坡表面粒度特征主要取决于表面蚀积状况,同断面形态表现出密切的相关性。     

利用灰岩断层面形貌特征识别罗云山山前断裂古地震信息

以山西地堑系罗云山山前断裂的基岩断层面为例,用陆基Li DAR扫描获取了断层面形貌学数据,采用各向同性变差函数法计算了断层面形貌的分维值。结果显示,断层面形貌在高度上具有显著的分带性,每个分带的特征分维值随断层面高度的增加呈阶跃式变化。分析认为这种形貌特征可能反映了断层面与多次地震相关的间歇式出露方式。分带高度指示了约3m和1m的2组同震倾滑位移量,各分带之间的分维值过渡带是断层面缓慢剥露的结果。与片麻岩区的断层面形貌学研究结果相比,灰岩断层面形貌学分维值随着暴露时间的增加而减小,2种岩性区的断层面分维值D与断层面高度H呈现类似镜像的关系,在气候构造条件大致相同的情况下,考虑为岩性差异的影响。     

Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.     

Study on Effects of Building Morphology on Urban Boundary Layer Using an Urban Canopy Model

An urban canopy model is incorporated into the Nanjing University Regional Boundary Layer Model. Temperature simulated by the urban canopy model is in better agreement with the observation, especially in the night time, than that simulated by the traditional slab model. The coupled model is used to study the effects of building morphology on urban boundary layer and meteorological environment by changing urban area, building height, and building density.It is found that when the urban area is expanded, the urban boundary layer heat flux, thermal turbulence, and the turbulent momentum flux and kinetic energy all increase or enhance, causing the surface air temperature to rise up. The stability of urban atmospheric stratification is affected to different extent at different times of the day.When the building height goes up, the aerodynamic roughness height, zero plane displacement height of urban area, and ratio of building height to street width all increase. Therefore, the increase in building height results in the decrease of the surface heat flux, urban surface temperature, mean wind speed, and turbulent kinetic energy in daytime. While at night, as more heat storage is released by higher buildings, thermal turbulence is more active and surface heat flux increases, leading to a higher urban temperature.As the building density increases, the aerodynamic roughness height of urban area decreases, and the effect of urban canopy on radiation strengthens. The increase of building density results in the decrease in urban surface heat flux, momentum flux, and air temperature, the increase in mean wind speed, and the weakening of turbulence in the daytime. While at night, the urban temperature increases due to the release of more heat storage.     

片状微囊藻(Microcystis panniformis)——中国微囊藻属的一个新记录种

目前全球范围内先后有50多种微囊藻被描述记载,国内最新研究报道有12种.根据采自太湖的野外藻类样品,确定了中国微囊藻属的一个新记录种——片状微囊藻(Microcystis panniformis),对其分类学的形态特征进行详细的描述,并对其和分类学上相近的属种Pannus以及微囊藻属的鱼害微囊藻(M.ichthyoblabe)、铜绿微囊藻(M.aeruginosa)和水华微囊藻(M.flos-aquae)等的区分进行讨论.     

基于长时间序列(1975—2020年)生态耗水的岱海动态生态需水分析

生态需水是湖泊生态系统的重要指标,维持着湖泊生态系统的良性循环.以内蒙古中部半干旱湖泊岱海为研究对象,对湖泊动态生态需水进行分析.本研究在遥感和气象数据的基础上,获得1975-2020年长时间序列高精度水文要素数据,分析岱海水文要素时空演变规律;通过天然生态水深分析法、水深经验频率分析法和湖泊形态分析法分析岱海的水深随面积变化的关键水深;构建基于生态耗水规律的湖泊生态需水模型,计算自然状态下岱海生态需水动态变化范围.研究结果如下:岱海地区6-9月为丰水期,10月至次年5月为枯水期;45 a以来岱海水面面积呈显著下降趋势,近年来下降速率减缓;枯水期岱海适宜生态水深为8.72~9.92 m,丰水期为9.40~10.69 m,适宜生态需水量为5.62亿~7.71亿m³,适宜湖面面积为70.92~84.77 km².本文构建了长时间序列气候水文数据库,确定岱海动态生态需水范围可以实现对湖泊生态健康的实时监测,为相关规划与管理提供科学依据及可操作性指导,从而为岱海湖泊治理提供理论参考.     

外源氮磷负荷比增加对刺苦草（Vallisneria spinulosa）生长的影响

磷(P)是水生态系统生产力的限制因子,因此,在水体富营养化治理的过程中,许多地方采取了有效的措施控制流域P的排放;但氮(N)来源复杂,难以有效控制,导致湖泊外源的N∶P负荷比日益扩大.植物的生长需要合适的N∶P比,因此,外源N∶P负荷比的增加可能会对沉水植物的生长产生影响.采取控制实验,将刺苦草(Vallisneria spinulosa)栽种于塑料桶中,每隔3 d添加1次N、P营养盐,实验设置5个处理,P外源性负荷量固定为4 mg/(m~2·d),N外源性负荷量分别为0、40、80、120、160 mg/(m~2·d).实验周期为80 d.结果显示:随着N∶P负荷比的增加,刺苦草的叶干重、植株总干重、根干重、叶N及总N含量、叶片数、叶P及总P含量等指标基本保持不变或略有增加,单株总根长、根茎长度、块茎干重和无性系小株数目则呈现下降趋势.结果表明:随外源N∶P负荷比的增加,刺苦草个体生长指标总体呈现不变的趋势,但与种群扩张潜力相关的指标如根茎长度、块茎干重和无性系小株数目等则呈现下降趋势;刺苦草体内累积的N随外源N∶P负荷比的增加而增加,但P的累积保持不变.说明N∶P负荷比的增加对刺苦草个体生长影响不大,但对种群扩张不利;刺苦草对P的吸收也并不随N∶P比的增加而改变.