中国二氧化碳排放源现状分析

通过对20世纪90年代中国几个主要温室气体研究项目中关于二氧化碳(CO2)排放源研究结果的综合分析,结合最新资料,对1990年的中国CO2排放源进行了收集和完善,对1994年中国CO2排放源重新做了计算.其中,工业生产过程的CO2排放,在以前的研究中仅仅计算了水泥一项,本研究中我们增加了石灰、钢铁、电解铝三项,力求使结果更接近实际情况.结果表明,1990年和1994年中国CO2矿物燃料燃烧和工业过程总排放分别为2218.9×106t(合605.1×106t碳)和2787.8×106t(合760.3×106t碳),分别占当年全球CO2总排放的10.2%和12.7%.能源和工业生产活动的CO2排放均有不同程度的增长.矿物燃料燃烧是中国CO2的最大排放源,占总排放的90%以上.对CO2排放源的不确定性分析表明,中国CO2排放存在大于10%的减排潜力.     

二连盆地吉尔嘎朗图凹陷煤层气成因类型及勘探方向

低煤阶煤层气地球化学特征及成因判识是勘探选区重要基础。通过解剖煤层气井气、水组成及其碳、氢同位素特 征,探讨了二连盆地吉尔嘎朗图凹陷煤层气成因。结果表明：煤层气组分中甲烷占93.41%,重烃及二氧化碳含量低,为典 型干气;甲烷碳同位素(δ13C)值介于-62.5‰~-60.1‰之间、氢同位素(δD)值介于-275.1‰~-270.2‰之间、二氧化碳碳的同位 素(δ13C)值介于5.1‰~6.2‰之间,反映其为生物成因气。煤层水来源于大气降水,呈弱碱性、较低矿化度。煤层气井气、水 氢同位素特征表明研究区97%左右生物成因气形成于二氧化碳还原机制。生物气藏是吉尔嘎朗图凹陷重要煤层气勘探方 向,适宜地下水环境是勘探选区关键因素。     

Modeling vertical stratification of CO2 injected into a deep layered aquifer

The vertical stratification of carbon dioxide (CO₂) injected into a deep layered aquifer made up of high-permeability and low-permeability layers, such as Utsira aquifer at Sleipner site in Norway, is investigated with a Buckley–Leverett equation including gravity effects. In a first step, we study both by theory and simulation the application of this equation to the vertical migration of a light phase (CO₂), in a denser phase (water), in 1D vertical columns filled with different types of porous media: homogeneous, piecewise homogeneous, layered periodic and finally heterogeneous. For each case, we solve the associated Riemann problems and propose semi-analytical solutions describing the spatial and temporal evolution of the light phase saturation. These solutions agree well with simulation results. We show that the flux continuity condition at interfaces between high-permeability and low-permeability layers leads to CO₂ saturation discontinuities at these interfaces and, in particular, to a saturation increase beneath low-permeability layers. In a second step, we analyze the vertical migration of a CO₂ plume injected into a 2D layered aquifer. We show that the CO₂ vertical stratification under each low-permeability layer is induced, as in 1D columns, by the flux continuity condition at interfaces. As the injection takes place at the bottom of the aquifer the velocity and the flux function decrease with elevation and this phenomenon is proposed to explain the stratification under each mudstone layer as observed at Sleipner site.     

60年来大气中二氧化碳浓度数据的趋势方程研究

通过讨论已有的60年来大气中CO₂浓度数据的分布状态,采用趋势分析方法,给出了具体趋势方程形式.与冰芯分析或观测数据对比结果表明,趋势方程曲线与已有数据基本符合,随后初步给出了2010年至2016年间大气中CO₂浓度预测值.     

苏南地区温室气体CO2地质处置的探讨

化石能源是现代工业飞速发展的重要保障。但从工业革命以来,无节制的能源消耗导致越来越多的温室气体被排入大气,带来了一系列的环境问题,全球气候变暖就是其中最严重的问题。业已觉悟的国际社会,已经认识到问题的严重性,并开始行动起来,其中二氧化碳(CO₂)的回收及安全处置就是一项减缓大气变暖的重大工程。针对全球温室气体减排的压力,详细分析了CO₂的地质处置机制与措施,并探讨了工业发达的苏南地区进行CO₂地质处置的方式,认为存在苏北油田注CO₂增产、句容盆地深层盐水层或贫油气储层的CO₂地质处置和薄煤层CO₂吸附处置等3种方式,提出句容盆地将是未来苏南地区进行CO₂地质处置的重要场所,同时认为进行CO₂地质处置存在巨大的商机。     

一次能源消费导致的二氧化碳排放量变化

从不同燃料和不同地区入手,分析了我国1995~2006年间一次能源消费导致的二氧化碳排放量变化情况。结果表明:1995~2006年间,我国一次能源消费导致的二氧化碳年总排放量呈现"先减少后增加"的发展态势,其拐点出现在2000年,而且2001年后各个省(区、市)的二氧化碳年排放量较前期均有大幅度的增加,总排放量由1995年的78678万t碳增长到2006年的146919万t碳,年均增长率5.84％,人均二氧化碳年排放量也由0.62t碳/人增加到1.12t碳/人;煤炭消费导致的二氧化碳排放量占全国二氧化碳年总排放量的79%~85％;我国七大区和大部分省(区、市)二氧化碳年排放量与全国总排放量有类似的发展态势,其中华北、华东地区二氧化碳排放量居全国首位,山西省的二氧化碳排放量位居全国第一。     

地表CO2浓度分布模拟试验及分析

如何获取CO₂浓度时空分布特征,是气候变化研究中的一个关键问题。本文基于中国碳卫星在吉林航飞试验区的地面观测数据,分析地表CO₂浓度与环境变量的相关关系,运用多元线性回归与HASM高精度曲面建模相结合的方法,模拟航飞区地表CO₂浓度分布格局。结果表明：CO₂浓度空间分布受气象条件的影响较大,短波辐射是影响CO₂浓度的重要因素;第1时段整体浓度最高,特别是在西部区域;第2时段CO₂浓度高值区东移,呈现西低东高的分布特点;第3时段浓度空间分布与第2时段有类似的特征,但细节存在差异,且高值区缩小;精度对比显示在采样点较少及采样密度不大的情况下,HASM方法的模拟误差小于Kriging方法。因此,这种使用多元线性回归模型通过引入环境变量获得高分辨率趋势面,结合HASM模型进行修正残差提高模拟结果精度的手段,可作为模拟地表CO₂浓度时空分布的有效方法。     

BOOK REVIEWS

Book reviewed is the article: Small-State Security in the Balkans . Aurel Braun. South American Development: A Geographical Introduction . Rosemary D. F. Bromley and Ray Bromley. Interregional Migration, National Policy and Social Justice . Gordon L. Clark. Marketing Architectural and Engineering Services . Weld Coxe. A Geography of the Third World . J. P. Dickenson, C. G. Clarke, W. T. S. Gould, R. M. Prothero, D. J. Siddle, C. T. Smith, E. M. Thomas-Hope, and A. G. Hodgkiss. Wildlife and Man in Texas: Environmental Change and Conservation . Robin W. Doughty. At the Sea's Edge . William T. Fox. Englewood Cliffs Geography and Ecology . I. P. Gerasimov. Urbanization in Contemporary Latin America. Critical Approaches to the Analysis of Urban Issues . Alan Gilbert in association with Jorge E. Hardoy and Ronaldo Ramírez, eds. The Coming of the Transactional City . Jean Gottmann. College Park Visions of City and Country: Prints and Photographs of Nineteenth-Century France . Bonnie L. Grad and Timothy A. Riggs. Worcester Soviet Geography Today: Physical Geography . N. A. Gvozdetskiy, ed. Adaptive Responses of Native Amazonians . Raymond B. Hames and William T. Vickers, eds. Urban and Regional Industrial Research: The Changing UK Data Base . Michael Healey, ed. Cuando se Acaban los Montes . Stanley Heckadon Moreno. A Panama Forest and Shore: Natural History and Amerindian Culture in Bocas del Toro . Burton L. Gordon. Pacific Grove Mozambique: From Colonialism to Revolution, 1900–1982 . Allen Isaacman and Barbara Isaacman. Soviet Natural Resources in the World Economy . Robert G. Jensen, Theodore Shabad, and Arthur W. Wright, eds. The Changing Geography of the United Kingdom . R. J. Johnston and J. C. Doornkamp, eds. Pluralism and Political Geography—People, Territory and State . Nurit Kliot and Stanley Waterman, eds. Landmarks Preservation and the Property Tax . David Listokin. Irrigation Horticulture in Highland Guatemala: The Tablón System of Panajachel . Kent Mathewson. Her Space, Her Place: A Geography of Women . Mary Ellen Mazey and David R. Lee. Man, A Geomorphological Agent . Dov Nir. Dordrecht The Book of America: Inside the 50 States Today . Neal R. Peirce and Jerry Hagstrom. Rivers . Geoffrey E. Petts. Proceedings, United States/Australia Workshop on Design and Implementation of Computer-Based Geographic Information Systems . Donna Peuquet and John O'Callaghan, eds. Outdoor Recreational and Resource Management . John Pigram. Remaking the City: Social Science Perspectives on Urban Design . John S. Pipkin, Mark La Gory and Judith R. Blau, eds. The Crust of Our Earth: An Armchair Traveler's Guide to the New Geology . Chet Raymo. Englewood Cliffs Concepts and Themes in the Regional Geography of Canada J. Lewis Robinson. Vancouver Secondary Cities in Developing Countries: Policies for Diffusing Urbanization . Dennis A. Rondinelli. Beverly Hills Legal Foundations of Environmental Planning , Vol 1. J. G. Rose. Can We Delay a Greenhouse Warming? Stephen Seidel and Dale Keyes. Mobilizing Human Resources in the Arab World . R. Paul Shaw. Prairie Mosaic: An Ethnic Atlas of Rural North Dakota . William C. Sherman. The Future of Conflict in the 1980s . William J. Taylor, Jr. and Steven A. Maaranen, eds. The Visual Display of Quantitative Information . Edward R. Tufte. U.S. 40 Today: Thirty Years of landscape Change in America . Thomas R. Vale and Geraldine R. Vale. Madison Silent Violence: Food, Famine and Peasantry in Northern Nigeria . Michael Watts. Readings in Historic Preservation: Why? What? How? Norman Williams Jr., Edmund Kellogg and Frank Gilbert, eds.     

The Heterogeneous Reaction of NO<Subscript>2</Subscript> with NH<Subscript>4</Subscript>Cl: A Molecular Diffusion Tube Study

The heterogeneous interaction of nitrogen dioxide with ammonium chloride was investigated in a molecular diffusion tube experiment at 295–335 K and interpreted using Monte Carlo trajectory calculations. The surface residence time (τ_surf) of NO₂ on NH₄Cl is equal to 15 μs at 295 K, increases with temperature up to 323 K (τ_surf = 45 μs) and probably decreases beyond 323 K. The same experiment also yields uptake coefficients, γ, which are derived from the absolute number of surviving molecules effusing out of the diffusion tube. The rate of uptake of NO₂ on NH₄Cl followed a rate law first order in [NO₂] and the uptake coefficient γ is equal to 7 × 10⁻⁵ at 295 K, increases with temperature up to 323 K (γ = 2.1 × 10⁻⁴) and probably decreases beyond 323 K. Nitrous acid, water and nitrogen were detected as products. From these products, it is concluded that the reaction of NO₂ with NH₄Cl is a reverse disproportionation reaction where two moles of NO₂ result in ammonium nitrite, NH₄NO₂, as an intermediate, and nitryl chloride, NO₂Cl. NH₄NO₂ decomposes in two pathways, one to nitrous acid, HONO and NH₃, the other to nitrogen and water. The branching ratio for the production of HONO + NH₃ to that of N₂ + H₂O is approximately 20 at 298 K and increases with increasing temperature.